Fabrication of Ni-shims using UV-moulding as an intermediate step

We fabricated nickel-shims including various types of structures with dimensions from hundreds of nanometers to several microns. The mastering process was made by electron-beam lithography, lift-off and reactive ion etching techniques. Then the structures were copied into a UV-curable ORMOCER-material and the Ni-shims were fabricated by electroforming using UV-copies as masters. The experiments showed that the use of UV-copying evades typical quartz master sticking and cracking problems. Furthermore, all features were replicated in the final Ni-shim as they existed in the quartz master proving the method suitable for the fabrication of the Ni-shims from the quartz masters with high precision.     

Wet Chemical Treatment and Mg Doping of p-InP Surfaces for Ohmic Low-Resistive Metal Contacts

Manufacturing a low-resistive Ohmic metal contact on p-type InP crystals for various applications is a challenge because of the Fermi-level pinning via surface defects and the diffusion of p-type doping atoms in InP. Development of wet-chemistry treatments and nanoscale control of p-doping for InP surfaces is crucial for decreasing the device resistivity losses and durability problems. Herein, a proper combination of HCl-based solution immersion, which directly provides an unusual wet chemical-induced InP(100)c(2 × 2) atomic structure, and low-temperature Mg-surface doping of the cleaned InP before Ni-film deposition is demonstrated to decrease the contact resistivity of Ni/p-InP by the factor of 10 approximately as compared to the lowest reference value without Mg. Deposition of the Mg intermediate layer on p-InP and postheating of Mg/p-InP at 350 °C, both performed in ultrahigh-vacuum (UHV) chamber, lead to intermixing of Mg and InP elements according to X-ray photoelectron spectroscopy. Introducing a small oxygen gas background (O₂ ≈ 10⁻⁶ mbar) in UHV chamber during the postheating of Mg/p-InP enhances the indium outdiffusion and provides the lowest contact resistivity. Quantum mechanical simulations indicate that the presence of InP native oxide or/and metal indium alloy at the interface increases In diffusion.     

Stimulation of Bone Healing by Sustained Bone Morphogenetic Protein 2 (BMP-2) Delivery

The aim of the study was to investigate the effect of a sustained release of bone morphogenetic protein2 (BMP-2) incorporated in a polymeric implant coating on bone healing. In vitro analysis revealed a sustained, but incomplete BMP-2 release until Day 42. For the in vivo study, the rat tibia osteotomy was stabilized either with control or BMP-2 coated wires, and the healing progress was followed by micro computed tomography (μCT), biomechanical testing and histology at Days 10, 28, 42 and 84. MicroCT showed an accelerated formation of mineralized callus, as well as remodeling and an increase of mineralized/total callus volume (p = 0.021) at Day 42 in the BMP-2 group compared to the control. Histology revealed an increased callus mineralization at Days 42 and 84 (p = 0.006) with reduced cartilage at Day 84 (p = 0.004) in the BMP-2 group. Biomechanical stiffness was significantly higher in the BMP-2 group (p = 0.045) at Day 42. In summary, bone healing was enhanced after sustained BMP-2 application compared to the control. Using the same drug delivery system, but a burst release of BMP-2, a previous published study showed a similar positive effect on bone healing. Distinct differences in the healing outcome might be explained due to the different BMP release kinetics and dosages. However, further studies are necessary to adapt the optimal release profiles to physiological mechanisms.     

Titania and titania-silver nanoparticle deposits made by Liquid Flame Spray and their functionality as photocatalyst for organic- and biofilm removal

Titania and titania-silver nanoparticle deposits were made by Liquid Flame Spray technique, in which the liquid precursor is injected into a high temperature flame, where it will evaporate and nucleate to nanosize particles. One-step and two-step methods were used for preparation of titania-silver deposits. The amount of silver added was 1 wt%. The deposits were collected in the flame zone on steel and glass surfaces and were analyzed by TEM, EDS, XPS and SAXS. The titania deposits consisted of porous nanosized titania agglomerates of primary particles (~10 nm). With silver addition, small spherical silver metal particles (~2 nm) were detected on the agglomerates. An increase in the photocatalytic activity was verified by stearic acid decomposition and biofilm removal using Deinococcus geothermalis as the model organism.     

Simultaneous heat exchanger network synthesis for direct and indirect heat transfer inside and between processes

Process plants are typically divided into different process parts having specific processing tasks with possibly different ownership. Heat integration between these processes can increase the energy- and economic efficiency for both the overall plant and the individual processes. In this paper we present a heat exchanger network synthesis MINLP-model that allows simultaneous heat integration directly between streams in the same process and both directly and indirectly between streams in different processes. The indirect heat transfer is accomplished by using intermediate streams. Two examples, one small explanatory one and one from the literature, are optimized. The results verify that the model works logically.     

Selection of NF membrane to improve quality of chemically treated surface water

The requirement for higher quality drinking water necessitates the application of more efficient water treatment techniques. Nanofiltration is one promising option for enhanced water treatment, for example, in enhanced organic matter removal. The characteristics of different nanofiltration membranes vary remarkably, and the selection of a membrane has to be made according to the requirements of an application. In this study six nanofiltration membranes (NF70, NF255, NTR-7450, NTR-7410, Desal-5 and TFC-S) were evaluated in improving the quality of chemically pre-treated surface water in a pilot-scale process. The results indicate that the membrane with high organics removal and slightly reduced ion removal characteristics (NF255) performed best in terms of product water quality as well as membrane productivity and fouling. The most permeable membrane (NTR-7410) suffered intensive fouling and insufficient product water quality. An interesting finding was that the permeates of all the tested membranes possessed a significant potential for microbial growth, despite the low nutrient contents.     

Airborne Microbes and Endotoxins in the Work Environment of Two Sanitary Landfills in Finland

The Andersen sampler was used to study the occurrence of bacteria and fungi in the working air of two large, intensively used landfills in Finland. Endotoxins were also determined. The concentrations of airborne microbes were high in summer in warm windy weather. Mesophilic bacteria exceeded 10⁵ colony-forming units (cfu)/m³ and mesophilic fungi 10⁴ cfu/m³. In 67% of the samples, the concentrations of gram-negative bacteria exceeded 10³/m³, which has been suggested to be the threshold limit value (TLV). The endotoxin levels were all below 0.1 μg/m³. A large part of the colony-forming particles were within the respirable size range, about 40% of the bacteria and about 80% of the fungi. The commonly isolated airborne bacteria were Pseudomonas, Enterobacter, and Bacillus spp. The landfill workers should try to work upwind. There are also grounds for using a mask and irrigating the refuse terrace with leachate in dry weather. It is suggested that the traffic on the refuse terrace be decreased by arranging for the private cars to be emptied in the reception area.     

The effect of anisotropicity of Norway spruce (Picea abies) during two-body abrasion

The effect of anisotropicity of Norway spruce (Picea abies) during two-body abrasive wear was investigated by rubbing the wood with five different orientations while using constant surface pressure and a sanding belt with very fine abrasive grits. The anisotropic nature was found to affect the microstructure of the worn surface and the breakage mechanism of the surface. The properties of the particles that were released from the surface during abrasion were dependent on the grinding orientation and if the particle originated from early- or latewood. The wear process was influenced by the anisotropic nature of wood.     

Analysis of experimental factors in elastic–plastic small specimen mixed-mode I-II fracture mechanical testing

The quality of experimental fracture resistance testing results in mixed-mode I-II loading is more than questionable in several cases. This study describes efforts to gain consistent results with respect to mixed-mode I-II fracture resistance curve determination when working with elastic–plastic materials. The entire mixed-mode I-II field is evaluated, i.e. both numerical and experimental factors are considered the focus being on the asymmetric four-point bend set-up. Several error prone features are presented, and minimization of their effects on quantitative fracture resistance assessment considered. The results indicate that through a careful evaluation of the stages in experimental testing and numerical analysis valid, material characterizing, fracture toughness results can be obtained.