Synthesis of a novel sulfonated poly(amide‐imide) and its application in preparation of ultrafiltration PES membranes as a modifier

Sulfonated poly(amide‐imide) (SPAI) copolymer was synthesized, characterized, and blended into poly(ether sulfone) (PES)/dimethylacetamide casting solutions to prepare ultrafiltration membranes. Different weight ratios of the copolymer (0–10 wt %) were mixed in the PES casting solution. The analyses of contact angle and attenuated total reflection‐Fourier transform infrared spectra were used to study hydrophilicity and physicochemical properties of the membrane surface, respectively. The membranes were further characterized by scanning electron microscopy images, ultrafiltration performance, and fouling analyses. The outcomes showed that addition of the SPAI in the PES matrix improved considerably the membranes hydrophilicity. Moreover, with increasing SPAI concentration, the porosity, flux recovery ratio, and pure water permeability of the modified membranes were improved. The pure water flux was increased from 3.6 to 12.4 kg/m² h by increasing 2 wt % SPAI. The antifouling property of the modified PES membranes against bovine serum albumin, tested by a dead‐end filtration setup revealed that bovine serum albumin rejection of the obtained membrane was also enhanced and the antifouling properties of the blending membranes were improved. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46477.     

Microstructural study of synthesized polyethylenes by homogeneous and heterogeneous nickel α-diimine catalysts

In this work, ethylene polymerization was investigated by using homogeneous and heterogenouse nickel α-diimine catalysts [1,4-bis(2,6-diisopropylphenyl) acenaphthene diimine nickel(II) dibromide]. Methyl aluminoxane (MAO) and triethyl aluminum (TEA) were used as cocatalysts in homogenous and heterogeneous polymerizations, respectively. The heterogeneous catalyst showed lower activity than its homogeneous equivalent. The influence of polymerization temperature and heterogenization conditions was studied on the microstructure properties of the prepared polymers. Increasing polymerization temperature (T _P) up to 50 °C decreased the activity of both homogenous (LN) and heterogeneous (LNS) nickel α-diimine catalysts. The highest activities were 1286 and 982 kg PE (mol Ni bar h)^?1 obtained at T _P = 30 °C for LN and LNS catalysts, respectively. The polymer samples obtained by supported catalyst (LNS) showed lower unsaturation contents. Moreover, DSC analysis did not show any melting peaks for polymers obtained by LN catalyst due to their amorphous structure, which was confirmed by XRD analysis. The microstructure of the prepared polymers was completed by successive self-nucleation annealing (SSA) and was investigated by ¹³C NMR studies. The SSA thermogram of samples made by LNS catalyst exhibited several crystal types with different lamella thicknesses. The branches in polyethylene samples produced by homogenous catalyst were higher and showed more diversity. The total methyl branch percentages for both LN and LNS catalysts were 13.1 and 3.4%, respectively.     

Effect of different additives and their mixtures on thermal stability of polyethylene synthesized using iron and titanocene hybrid catalysts

Traditionally, additives are introduced into a polymer matrix via extrusion process which consumes a high amount of energy. In this study, the use of different additives including antioxidants for the in‐reactor stabilization of polyethylene has been investigated in order to provide an energy saving system. Particular attention was dedicated to the efficiency of antioxidant influencing the catalysts activity and properties of polymers. The effect of the addition of Irganox 1330 and Irgafos 168 antioxidants and zinc stearate on the activities of metallocene, post‐metallocene, and their supported hybrid were studied. In addition, the effect of different additives on the thermal characteristics of the synthesized polymers and oxidative induction time (OIT) was evaluated. Our polymerization results exhibited that the factors such as chemical structure of antioxidant and its steric hindrance, type of catalysts, and their hybrid could affect the catalyst performance and OIT contents. The use of antioxidants mixture and hybrid of catalysts is a way that can increase oxidation resistance of polymers considerably. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 45482.     

Structural,Half-Metallic,Optical, and Thermoelectric Study on the Zr2TiX (X = Al,Ga, Ge,Si) Heuslers: by DFT

Silicon - Based on the density functional theory (DFT) framework, the mechanical, half-metallic (HF), optical and thermoelectric properties of Zr2TiX (X = Al, Ga, Ge, Si) Heusler compounds are...