Novel electrospun polymer electrolytes incorporated with Keggin‐type hetero polyoxometalate fillers as solvent‐free electrolytes for lithium ion batteries

In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm^?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry     

Algebraic theory of optimal filterbanks

We introduce an optimality theory for finite impulse response (FIR) filterbanks using a general algebraic point of view. We consider an admissible set /spl Lscr/ of FIR filterbanks and use scalability as the main notion based on which performance of the elements in /spl Lscr/are compared. We show that quantification of scalability leads naturally to a partial ordering on the set /spl Lscr/. An optimal solution is, therefore, represented by the greatest element in /spl Lscr/. It turns out that a greatest element does not necessarily exist in /spl Lscr/. Hence, one has to settle with one of the maximal elements that exist in /spl Lscr/. We provide a systematic way of finding a maximal element by embedding the partial ordering at hand in a total ordering. This is done by using a special class of order-preserving functions known as Schur-convex. There is, however, a price to pay for achieving a total ordering: there are infinitely many possible choices for Schur-convex functions, and the optimal solution specified in /spl Lscr/ depends on this (subjective) choice. An interesting aspect of the presented algebraic theory is that the connection between several concepts, namely, principal component filterbanks (PCFBs), filterbanks with maximum coding gain, and filterbanks with good scalability, is clearly revealed. We show that these are simply associated with different extremal elements of the partial ordering induced on /spl Lscr/ by scalability.     

Antihyperglycemic activity of phenolics from Pterocarpus marsupium

Glucose levels in rats with hyperglycemia induced by streptozotocin were determined after i.p. administration of marsupsin (1), pterosupin (2), and pterostilbene (3), three important phenolic constituents of the heartwood of Pterocarpus marsupium. Marsupsin and pterostilbene significantly lowered the blood glucose level of hyperglycemic rats, and the effect was comparable to that of 1,1-dimethylbiguanide (metformin).     

Design and energy absorption enhancement of vehicle hull under high dynamic loads

V-shape hulls are widely used in peacekeeping efforts such as demining vehicles in order to deflect the blast energy and reduce the effects of mine blast. Blast resistant design and energy absorption enhancement of V-shape plates were carried out using finite element analysis package ABAQUS. Various geometries of V-shape plates with and without interlayer of materials like Al-foams and honeycomb were employed to analyze their effects on the deformation of the plate and applied stresses and strains. The results obtained show that application of metallic foams leads to better response of the plate and consequently results in more energy dissipation, less dame to vehicle and enhances crew survivability.     

Maternal Regulation of Infant Reactivity From 2 to 6 Months.

Previous research has investigated the effect of maternal soothing behaviors on reducing infant reactivity but not the differential effects of specific maternal behaviors on infant stress responses. The present study investigated maternal regulation of 2- and 6-month-olds' responses to an inoculation and found a significant decline with age in both the intensity and duration of infants' crying. Maternal affection and touching decreased from 2 to 6 months, whereas maternal vocalizing and distraction behaviors increased. At both ages, the combination of maternal holding/rocking and vocalizing was associated with decreases in all levels of infant reactivity. Neither strategy alone, however, was found to be effective. Feeding/ pacifying behaviors were effective only when initial distress was at a low or moderate level, which suggests that the effectiveness of maternal regulatory behaviors may depend on the intensity of infants' crying. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Axial offset control of PWR nuclear reactor core using intelligent techniques

Improved load following capability is one of the main technical performances of advanced PWR (APWR). Controlling the nuclear reactor core during load following operation encounters some difficulties. These difficulties mainly arise from nuclear reactor core limitations in local power peaking, while the core is subject to large and sharp variation of local power density during transients. Axial offset (AO) is the parameter usually used to represent of core power peaking, in form of a practical parameter. This paper, proposes a new intelligent approach to AO control of PWR nuclear reactors core during load following operation. This method uses a neural network model of the core to predict the dynamic behavior of the core and a fuzzy critic based on the operator knowledge and experience for the purpose of decision-making during load following operations. Simulation results show that this method can use optimum control rod groups maneuver with variable overlapping and may improve the reactor load following capability.     

Hot Corrosion Behavior and Microstructural Change of Al-Gradient CoNiCrAlYSi Coatings, Produced by LVPS and Diffusional Processes

Conventional and gradient CoNiCrAlYSi coatings were produced by using low vacuum plasma spray and an additional step of diffusional over aluminizing (pack cementation) techniques on an Inconel-738 substrate. Hot corrosion of these coatings was investigated using Na₂SO₄–20wt%NaVO₃ molten salt at 880?°C for 800?h. Hot corrosion rate was determined by measuring the weight gain of the specimens at regular intervals for a duration of 20?h. X-ray diffraction, field emission scanning electron microscopy and electron probe micro analysis techniques were used to determine the nature of phases, investigation of the thermally grown oxide, examination of the surface attack and determination of the elemental distribution. The gradient coating showed better performance by re-healing alumina scale due to its possession of more β phase as Al reservoir. Results indicated that pack cementation process caused an increase in amount of aluminum-rich β phase and better hot corrosion properties of gradient coatings owing to the Al enrichment in the outer layer and rapid formation of protective oxide on the surface.     

Modeling and Control of Linear Two-time Scale Systems: Applied to Single-Link Flexible Manipulator

This paper deals with the problem of H _∞ control of linear two-time scale systems. The authors’ attention is focused on the robust regulation of the system based on a new modeling approach under the assumption of norm-boundedness of the fast dynamics. In the proposed approach, the fast dynamics are treated as a norm-bounded disturbance (dynamic uncertainty). In this view, the synthesis is performed only for the certain dynamics of the two-time scale system, whose order is less than that of the original system. It should be noted, however, that this scheme is significantly different from the conventional approaches of order reduction for linear two-time scale systems. Specifically, in the present work, explicitly or implicitly, all the dynamics of the system are taken into consideration. In other words, the portion that is treated as a perturbation is incorporated in the design by its maximum possible gain – in the L ₂ sense – over different values of the inputs. One of the advantagesof this approach is that – unlike in the conventional approaches of the order reduction – the reduced-order system still keeps some information of the ‘deleted’ subsystem. Also, we consider the robust stability analysis and stability bound improvement of perturbed parameter (ɛ) in the two-time scale systems by using linear fractional transformations and structured singular values (μ) approach. In this direction, by introducing the parametric uncertainty and dynamic uncertainty in the two-time scale systems, we represent the system as a standard μ-interconnection framework by using linear fractional transformations, and derive a set of new stability conditions for the system in the frequency domain. The exact solution of ɛ-bound is characterized. It is shown that, in spite of the coupling between the dynamic uncertainties and certain dynamics, the designed H _∞ controller stabilizes the overall closed-loop system, in the presence of norm-bounded disturbances. To show the effectiveness of the approach, the modeling of the single-link flexible manipulator and control of the Tip-position of the manipulator by utilizing the mentioned method are presented in the case study.     

Warranty servicing for discretely degrading items with non-zero repair time under renewing warranty

This paper considers a repair-replacement strategy for a special class of discretely degrading and repairable products under renewing free replacement warranty. Each product may experience N different working states with different exponential hazard functions, before the warranty contract expires. Once the item enters working state i (i = 1, 2, … , N), it can either fail or move to any of the subsequent working states with different probabilities, given that a transition has been made. In the former case, the best rectification action, replacement or minimal repair, regarding the failure status, i.e., the product degradation level at the failure time and the remaining warranty time, should be conducted to put the item into operation. It is assumed that replacement of the faulty item occurs instantly and the product warranty is renewed, but non-zero repair time has been included in the model. We derive the optimal replacement-repair policy to minimize the manufacturer’s expected warranty servicing cost per item sold. The Adomian decomposition method is used to find an analytic approximate solution for a special case with two working states. For N > 2, a simulation based optimization method has been developed to analyze the expected warranty cost. Some numerical examples in each section are given to clearly demonstrate the application of this model.