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1.
In the presence of modified methylaluminoxane as cocatalyst, the behavior of a binary catalytic system based on pyridine-imine nickel ( N ) and iron ( F ) catalysts was evaluated in order to reach a proper mixture of polyethylene (PE). A computational study along with kinetic profile suggested that the catalyst F with higher electron affinity (A) and electrophilicity (ω) in the methyl cationic active center and stronger interaction with the monomer led to high integrated monomer consumption and higher activity. In addition, the samples produced by the mixture of catalysts showed a higher value of [19.4 × 104 g (PE) mol (Fe+Ni)−1 h−1)], melting point (127.8 °C), and crystallinity extent (41.29%) than the samples produced by the single catalysts. The addition of multiwalled carbon nanotubes (MWCNT) into the polymerization media reduced the activity of catalysts [from 7.50 × 104 to 0.66 × 104 g (PE) mol (Fe+Ni)−1 h−1] and the thermal properties of the low-density polyethylene nanocomposite samples. However, the sample containing 2.33% MWCNT20-30 improved the total thermal stability of the neat polyethylene blend up to 400 °C. Scanning electron microscope images of the samples demonstrated irregular to virtually uniform morphologies were obtained through the in situ and solution-mixing techniques. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47376. 相似文献
2.
Amini Amir Jafari Azin Vafaei Mostafa Mahmoodian Mehrnoosh 《Journal of Materials Science: Materials in Electronics》2022,33(3):1293-1306
Journal of Materials Science: Materials in Electronics - The main weakness of polymer gas sensors is its stability. Here, we report stability enhancement of a 100 nm polypyrrole (PPy) thin... 相似文献
3.
SPEEK/cSMM membrane for simultaneous electricity generation and wastewater treatment in microbial fuel cell
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4.
Mostafa Dellahi Hattab Maker Guillermo Botella Enrique Alameda-Hernandez Azeddine Mouhsen 《International Journal of Circuit Theory and Applications》2020,48(6):887-905
The three-phase four-wire shunt active power filter (SAPF) was developed to suppress the harmonic currents generated by nonlinear loads, and for the compensation of unbalanced nonlinear load currents, reactive power, and the harmonic neutral current. In this work, we consider instantaneous reactive power theory (PQ theory) for reference current identification based on the following two algorithms: the classic low-pass filter (LPF) and the second-order generalized integrator (SOGI) filter. Furthermore, since an important process in SAPF control is the regulation of the DC bus voltage at the capacitor, a new controller based on the Lyapunov function is also proposed. A complete simulation of the resultant active filtering system confirms its validity, which uses the SOGI filter to extract the reference currents from the distorted line currents, compared with the traditional PQ theory based on LPF. In addition, the simulation performed also demonstrates the superiority of the proposed approach, for DC bus voltage control based on the Lyapunov function, compared with the traditional proportional-integral (PI) controller. Both novel approaches contribute towards an improvement in the overall performance of the system, which consists of a small rise and settling time, a very low or nonexistent overshoot, and the minimization of the total harmonic distortion (THD). 相似文献
5.
6.
An agriglass composition containing different oxides acts as a slow release for macro and micro nutrients and was chosen to improve maize yield under most important abiotic stresses which affecting agriculture development; salinity and drought. A field experiment was performed in salt affected soil (EC =?7.5 dSm??1) by using different water deficit rates (I1 = 100, I2 = 85 and I3 = 70% of maize water requirements). Irrigation levels were located in main plots. Every main-plot divided into six sub-plots contained glassy fertilizer treatments [F1 = 55 kg fed?1 with 1/2 mm diameter of agriglass (fed. =?4200 m2), F2 = 55 kg fed?1 with 1 mm diameter, F3 = 80 kg fed?1 with 1/2 mm diameter, F4 = 80 kg fed?1 with 1 mm diameter, F5 = Recommendations of Ministry of Agriculture and F6 = control]. The experimental results demonstrated that, ears, straw, grains and biological yields increased with increasing both water and agriglass rates. Application of agriglass as a slow release fertilizer improved yield more than mineral fertilizer. Some growth parameters, water use efficiency (IWUE), macronutrients concentration and their relations were included. Other studies on residual effect of agriglass and the annual application rates to withstand salinity and drought stress by strategic crops are required. 相似文献
7.
Mostafa A. G. Sanad A. M. Kashif I. El-Saghier A. A. 《Journal of Materials Science Letters》1985,4(5):571-574
Journal of Materials Science Letters - 相似文献
8.
The molecular weight of polyacrylic acid (PAA) was determined by a viscometric method using NaNO3 as solvent at 30°C. The specific electric conductivities (σ) of PAA as well as PAA doped with carbon black (CB), chromium oxide (Cr2O3), and cupferron with different concentrations (from 0.25 to 1 wt %) were measured at a temperature range 360–400 K. IR spectra of some polymers were determined and it was shown that when PAA was doped with 0.5 wt % CB, a C? O? C band appeared at 775–875 cm?1. The positron annihilation lifetime (PAL) spectra in PAA doped with the above‐mentioned dopants were measured as a function of their concentrations. It was observed that the short lifetime intensity I1 decreased, whereas the intermediate lifetime intensity I2, which is related to the conductivity of the material, increased with increasing the wt % of Cr2O3 and cupferron as well as at low concentrations of CB. These results are discussed in terms of the conducting island model. It was found that there were distinct positive relationships between σ and I2. © 2002 John Wiley & Sons, Inc. J Appl Polym Sci 84: 877–883, 2002; DOI 10.1002/app.10381 相似文献
9.
Mostafa Moussaid Stphane Caillet Josphine Nketsia‐Tabiri Cheikh Boubekri Monique Lacroix 《Journal of the science of food and agriculture》2004,84(13):1657-1662
The study evaluated the effects of waxing, irradiation dose and post‐irradiation storage time on the essential oils in orange peel. Mature oranges (Maroc late) waxed or unwaxed were treated with 1 or 2 kGy radiation and stored for 9 weeks at 20 °C and 40–50% RH. Essential oils from the peel were extracted and analysed by GC. Results showed that D ‐limonene was significantly lower in waxed oranges; levels in samples treated with 2 kGy were higher than those in non‐irradiated or treated with 1 kGy. Linalool, methyl anthranilate and 3,7‐dimethyl‐2,6‐octadienal decreased as the dose increased. Levels of linalool increased with storage time but D ‐limonene was unaffected. These results may aid in guaranteeing the quality of orange essential oils during storage time. Copyright © 2004 Society of Chemical Industry 相似文献
10.
The influences of wall-slip/jump conditions on the fluid flow and heat transfer for hydrodynamically and thermally fully developed electrically conducting gaseous flow subject to an electromagnetic field inside a parallel plate microchannel with constant heat flux at walls are studied under the assumptions of a low-magnetic Reynolds number. The governing equations are non-dimensionalized and then analytical solutions are derived for the friction and the heat transfer coefficients. The fluid flow and the heat transfer characteristics obtained in the analytical solutions are discussed in detail for different parameters such as the Knudsen, Hartmann, and Brinkman numbers. The velocity profiles verify that even with a constant Knudsen number, applying a stronger electromagnetic field gives rise to an increase in the slip velocity. The results also reveal that on increasing the Hartmann number, the heat transfer rate as well as the friction factor is enhanced, whereas it tends to suppress the movement of the fluid. Further, it is found that the Nusselt and the Poiseuille numbers are less sensitive to the electromagnetic field effects with increase in rarefaction. 相似文献