排序方式: 共有6条查询结果,搜索用时 125 毫秒
1
1.
Izyan Najwa Mohd Norsham Siti Nor Atika Baharin Muggundha Raoov Syed Shahabuddin Jaroon Jakmunee Kavirajaa Pandian Sambasevam 《Polymer Engineering and Science》2020,60(12):3170-3182
A simple, cost-effective, and novel chemical sensor for ammonia (NH3) gas detection was developed from polyaniline (PANI)/quail eggshell (QES) composites. QES is a natural waste enriched in calcium carbonate. In this work, pure PANI was synthesized from chemical oxidation method and PANI/QES composites were prepared from physical mixing of QES with the synthesized PANI at different mass ratio. A series of complementary techniques including Fourier transform infrared and ultraviolet-visible spectrometers, scanning electron microscope with energy dispersive detection coupled with mapping, thermogravimetric analysis, and X-ray diffractometer were used to characterize the physicochemical and textural properties of the biocomposites. From the results, PANI/QES composite with a mass ratio of 1 exhibited the lowest NH3 detection limit of 5.24 ppm with a linear correlation coefficient (R2) of close to unity (0.9932) between the signal and NH3 gas concentration. As a whole, the PANI/QES biocomposites synthesized from this work exhibited excellent selectivity toward NH3 gas even in the presence of other gas impurities, such as acetone, ethanol, and hexane. For the sensor reusability, the PANI/QES biocomposites can be reused in the application of NH3 gas detection for at least 4 cycles. 相似文献
2.
Mohamad S Surikumaran H Raoov M Marimuthu T Chandrasekaram K Subramaniam P 《International journal of molecular sciences》2011,12(9):6329-6345
This study focuses on the synthesis and characterization of the inclusion complex of β-Cyclodextrin (β-CD) with dicationic ionic liquid, 3,3'-(1,4-Phenylenebis [methylene]) bis(1-methyl-1H-imidazol-3-ium) di(bromide) (PhenmimBr). The inclusion complex was prepared at room temperature utilizing conventional kneading technique. Proton ((1)H) NMR and 2D ((1)H-(1)H) COSY NMR were the primary characterization tools employed to verify the formation of the inclusion complex. COSY spectra showed strong correlations between protons of imidazolium and protons of β-CD which indicates that the imidazolium ring of PhenmimBr has entered the cavity of β-CD. UV absorption indicated that β-CD reacts with PhenmimBr to form a 2:1 β-CD-PhenmimBr complex with an apparent formation constant of 2.61 × 10(5) mol&(-2) L(2). Other characterization studies such as UV, FT-IR, XRD, TGA, DSC and SEM studies were also used to further support the formation of the β-CD-PhenmimBr inclusion complex. 相似文献
3.
Md Saleh Noorashikin Muggundha Raoov Sharifah Mohamad Mhd Radzi Abas 《International journal of molecular sciences》2013,14(12):24531-24548
A cloud point extraction (CPE) process using non-ionic surfactant (DC193C) to extract selected paraben compounds from water samples was investigated using reversed phase high performance liquid chromatography (RP-HPLC). The CPE process with the presence of β-cyclodextrin (βCD) functionalized ionic liquid as a modifier (CPE-DC193C-βCD-IL) is a new extraction technique that has been applied on the optimization of parameters, i.e., pH, βCD-IL concentration and phase volume ratio. This CPE-DC193C-βCD-IL method is facilitated at 30 °C, showing great losses of water content in the surfactant-rich phase, resulting in a high pre-concentration factor and high distribution coefficient. The developed method CPE-DC193C-βCD-IL did show enhanced properties compared to the CPE method without the modifier (CPE-DC193C). The developed method of CPE-DC193C-βCD-IL gives an excellent performance on the detection of parabens from water samples with the limit of detection falling in the range of 0.013–0.038 μg mL−1. Finally, the inclusion complex formation, hydrogen bonding, and π–π interaction between the βCD-IL, benzyl paraben (ArP), and DC 193C were proven using 1H NMR and 2D NOESY spectroscopy. 相似文献
4.
Md Saleh Noorashikin Muggundha Raoov Sharifah Mohamad Mhd Radzi Abas 《Journal of surfactants and detergents》2014,17(4):747-758
A cloud point extraction process using a silicone non-ionic surfactant to extract selected parabens compounds from water samples was investigated using reversed phase high performance liquid chromatography. The cloud point extraction process, in the presence of β-cyclodextrin (β-CD) as a modifier, is a new extraction process which was optimized with five parameters, i.e. salt concentration, pH of the solution, temperature, surfactant concentration and β-CD concentration. The developed method with the β-CD modifier results in an excellent performance on detection of parabens from water samples with limits of detection in the range of 0.017–0.043 μg/L and percentage recoveries from 90.5 to 98.9 %. 相似文献
5.
Muggundha Raoov Sharifah Mohamad Mhd Radzi Abas 《International journal of molecular sciences》2014,15(1):100-119
β-Cyclodextrin-ionic liquid polymer (CD-ILP) was first synthesized by functionalized β-cyclodextrin (CD) with 1-benzylimidazole (BIM) to form monofunctionalized CD (βCD-BIMOTs) and was further polymerized using a toluene diisocyanate (TDI) linker to form insoluble CD-ILP (βCD-BIMOTs-TDI). The βCD-BIMOTs-TDI polymer was characterized using various tools and the results obtained were compared with those derived from the native β-cyclodextrin polymer (βCD-TDI). The SEM result shows that the presence of ionic liquid (IL) increases the pore size, while the thermo gravimetric analysis (TGA) result shows that the presence of IL increases the stability of the polymer. Meanwhile, Brunauer-Emmett-Teller (BET) results show that βCD-BIMOTs-TDI polymer has 1.254 m2/g surface areas and the Barret-Joyner-Halenda (BJH) pore size distribution result reveals that the polymer exhibits macropores with a pore size of 77.66 nm. Preliminary sorption experiments were carried out and the βCD-BIMOTs-TDI polymer shows enhanced sorption capacity and high removal towards phenols and As(V). 相似文献
6.
Syed Fariq Fathullah Syed Yaacob Mamman Suwaibatu Raja Zalinda Raja Jamil Nur Nadhirah Mohamed Zain Muggundha Raoov Faiz Bukhari Mohd Suah 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2023,98(2):312-330
Cyclodextrins (CDs) are formed of starch molecules that are linked together in a cyclic ring. They are composed of five or more (1, 4) connected D-glucopyranoside units. CDs have toroidal, hollow truncated cone structures with exterior hydrophilic edges and internal hydrophobic cavities. The numerous hydroxyl groups available in cyclodextrins are active sites capable of forming various sorts of connections. They can be cross-linked or derived to generate monomers able to form branching or linear networks. Furthermore, they can form inclusion complexes with a variety of guest molecules, including organic and inorganic molecules, thus changing their physicochemical properties, The modification of the imprinting method could produce molecularly imprinted polymers that are stable, dependable, long-lasting, selective, and cost-effective. As a result, molecularly imprinted polymers are becoming increasingly popular in chemical separation and analysis. As found in previous studies, the monomers of cyclodextrins used in molecular imprinting have a higher binding impact on target molecules. The purpose of this study is to highlight the application of imprinting technology utilizing cyclodextrins as a valuable functional monomer in the remediation of phenolic compounds by examining and assessing relevant works published in the literature. © 2022 Society of Chemical Industry (SCI). 相似文献
1