Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.     

Rheological behaviour of polysaccharide aqueous solutions

Several data relative to the viscosity of water-soluble polysaccharide solutions were collected from the literature and processed by different rheological models. Some relationships between the viscosity of these polymer solutions, their molecular weight and their solution concentrations, were established and their validity checked. Thus, an accurate equation correlating the viscosity and both the shear rate and the solution concentration of different water soluble polysaccharides (xanthan, hyaluronan, carboxymethylcellulose) was deduced on the basis of Cross' model which suggests two domains in which the viscosity is constant, i.e. very low and very high shear rate ranges. Then, an expression relating the zero-shear viscosity (A) and the concentration of their solutions was proposed. Finally, an alternative equation to that of Mark–Houwink correlating the molecular weight and the intrinsic viscosity of the water-soluble polysaccharides studied in this paper was found.     

A new fast motion estimation algorithm using fast mode decision for high-efficiency video coding standard

High-efficiency video coding is the latest standardization effort of the International Organization for Standardization and the International Telecommunication Union. This new standard adopts an exhaustive algorithm of decision based on a recursive quad-tree structured coding unit, prediction unit, and transform unit. Consequently, an important coding efficiency may be achieved. However, a significant computational complexity is resulted. To speed up the encoding process, efficient algorithms based on fast mode decision and optimized motion estimation were adopted in this paper. The aim was to reduce the complexity of the motion estimation algorithm by modifying its search pattern. Then, it was combined with a new fast mode decision algorithm to further improve the coding efficiency. Experimental results show a significant speedup in terms of encoding time and bit-rate saving with tolerable quality degradation. In fact, the proposed algorithm permits a main reduction that can reach up to 75 % in encoding time. This improvement is accompanied with an average PSNR loss of 0.12 dB and a decrease by 0.5 % in terms of bit-rate.     

Real-time quality authentication of honey using atmospheric pressure chemical ionisation mass spectrometry (APCI-MS)

The aim of this study was to use gas chromatography-mass spectrometry (GC-MS) and APCI-MS techniques to detect adulteration in honey. The key volatile compounds in the headspace of the adulterated honey were marked by GC-MS and their representative fragment ions were utilised in scanning honey samples using the real-time APCI-MS system. The PLS models validated using independent data sets resulted in coefficient of the determination () of 0.97 and 0.96 and root mean square error in prediction (RMSEP) of 2.62 and 2.45 for the GC-MS and APCI-MS data sets respectively. The most efficient volatiles from GC-MS analysis and their corresponding fragment ions m/z from APCI-MS data analysis were then identified and used to develop new PLS models to predict the level of adulteration. The best PLS model gave of 0.95 and RMEP of 2.60% in the independent validation set indicating that the model was very accurate in predicting the level of adulteration.     

A 2D finite element analysis of the effect of numerical parameters on the reliability of Ti6Al4V machining modeling

Abstract

The numerical analysis, based on the finite element modeling (FEM), presents nowadays an efficient computational tool. It allows a better understanding of several thermo-mechanical phenomena involved during the machining process. However, its reliability heavily depends on the accurate definition of the numerical model. In this regard, a FE analysis focused on the 2D modeling of the Ti6Al4V dry orthogonal machining was carried out in this study. The relevance of different numerical meshing approaches and finite elements topologies was studied. The effect of the friction coefficient on the numerical chip morphology, its geometry, the cutting and the feed forces was investigated. The adequacy of several compared adaptive meshing approaches, in terms of the modeling of severe contact conditions taking place around the cutting-edge radius, was underlined in the current study. However, numerical serrated chips, closer to the experimental ones, were only predicted when the pure Lagrangian formulation was adopted and a proper determination of the failure energy was carried out. The definition of different mesh topologies highlighted the efficiency of the 4-node quadrangular mesh, with a suitable edge length, in increasing the agreement with the experimental data, while reducing the computing times.     

Urethanes and polyurethanes based on oxypropylated cork: 1. Appraisal and reactivity of products

The reaction of various polyols derived from the oxypropylation of cork with aliphatic and aromatic mono‐ and diisocyanates was studied in solution at room temperature. In all instances, good second‐order kinetics were observed and the corresponding rate constant determined. The reactivity of the aromatic isocyanate was found to be much higher than that of aliphatic counterparts. The ensuing urethanes and polyurethanes were characterised by FTIR and ¹H NMR spectroscopy, DSC and sol/gel distribution. © 2001 Society of Chemical Industry     

Preparation of nanocomposite dispersions based on cellulose whiskers and acrylic copolymer by miniemulsion polymerization: Effect of the silane content

A one‐step method was used to prepare stable aqueous nanocomposite dispersions based on cellulose whiskers extracted from the rachis of the date palm tree and a poly(styrene‐co‐2‐ethyl hexylacrylate) copolymer via miniemulsion polymerization. A reactive silane, i.e., methacryloxypropyl triethoxysilane was added to stabilize the dispersion and favor the anchoring of the whiskers on polymer particles. Dynamic light scattering was used to study the effect of the silane and whiskers contents on the average particle size of the polymer. Nanocomposites materials were prepared from these dispersions using a casting/evaporation method. The effect of the silane and whiskers contents on the thermal and mechanical properties were studied using differential scanning calorimetry and dynamic mechanical analysis. POLYM. ENG. SCI., 2011. © 2010 Society of Plastics Engineers     

A discounted integrated inspection-maintenance model for a single deteriorating production facility

In this paper, we address the problem of determining optimum inspection schedules for a single deteriorating production system with a predetermined replacement cycle. It is assumed that, at different discrete points in time over the fixed planning horizon, the facility is inspected to detect its operating state and then it goes over an imperfect preventive maintenance routine to enhance its operating performance. Moreover, the facility undergoes minimal repair once detected in an “out‐of‐control” state. We also adopt the concept of discounted cash flow analysis to account properly for the effect of time value of money on the inspection policies. Under these settings, we formulate the discounted integrated inspection‐maintenance problem as a dynamic programming model with general time to failure distribution. After illustrating the model with a numerical example, we perform sensitivity analysis to investigate the effects of some input parameters on the expected present worth and the number of inspections.     

Build-Operate-Transfer in Infrastructure Projects in the United States

While the infrastructure in the United States is in need of large and immediate investment, the funds provided by public agencies are not nearly sufficient to face such a challenge. Build-operate-transfer (BOT) is a delivery/financing system that can be a solution to this problem. In this system, a private sponsor finances the design, construction, maintenance, and operation of a public project for a specified concession period, at the end of which it transfers ownership to the government agency, hopefully after recouping its costs and achieving profits. A questionnaire survey of large municipalities and state departments of transportation was conducted to determine the extent to which they are using BOT in their large projects, to investigate the implementation of BOT, and the reasons why some government agencies avoid using BOT. The findings indicate that very few agencies use BOT. The reasons why most do not use BOT were reported by the respondents to be the availability of proven alternatives and enough funds, the existence of political barriers, and resistance to change both on the part of government agencies and private sponsors. When government agencies and private sponsors explore the use of BOT, they should avoid the pitfalls perceived by the respondents in this study.