Shear mode coupling and tilted grain growth of A1N thin films in BAW resonators.

Polycrystalline A1N thin films were deposited by RF reactive magnetron sputtering on Pt(111)/Ti electrode films. The substrates were tilted by an angle ranging from 40 degrees to 70 degrees with respect to the target normal. A low deposition temperature and a high sputter gas pressure were found ideal for tilted growth. The resulting grain tilt angle amounts to about half the substrate tilt angle. For coupling evaluation, 5 GHz solidly mounted resonator structures have been realized. The tilted grain A1N films exhibited a permittivity in the 9.5-10.5 range and loss tangent of 0.3%. Two shear modes as well as the longitudinal mode could be clearly identified. The coupling coefficient k2(eff) of the fundamental thickness shear mode (TS0) was found to be about 0.5%, which is compatible with a c-axis tilt of about 6 degrees.     

Rheological behaviour of polysaccharide aqueous solutions

Several data relative to the viscosity of water-soluble polysaccharide solutions were collected from the literature and processed by different rheological models. Some relationships between the viscosity of these polymer solutions, their molecular weight and their solution concentrations, were established and their validity checked. Thus, an accurate equation correlating the viscosity and both the shear rate and the solution concentration of different water soluble polysaccharides (xanthan, hyaluronan, carboxymethylcellulose) was deduced on the basis of Cross' model which suggests two domains in which the viscosity is constant, i.e. very low and very high shear rate ranges. Then, an expression relating the zero-shear viscosity (A) and the concentration of their solutions was proposed. Finally, an alternative equation to that of Mark–Houwink correlating the molecular weight and the intrinsic viscosity of the water-soluble polysaccharides studied in this paper was found.     

Local Convergence of the Lavrentiev Method for the Cauchy Problem via a Carleman Inequality

The purpose is to perform a sharp analysis of the Lavrentiev method applied to the regularization of the ill-posed Cauchy problem, set in the Steklov-Poincaré variational framework. Global approximation results have been stated earlier that demonstrate that the Lavrentiev procedure yields a convergent strategy. However, no convergence rates are available unless a source condition is assumed on the exact Cauchy solution. We pursue here bounds on the approximation (bias) and the noise propagation (variance) errors away from the incomplete boundary where instabilities are located. The investigation relies on a Carleman inequality that enables enhanced local convergence rates for both bias and variance errors without any particular smoothness assumption on the exact solution. These improved results allows a new insight on the behavior of the Lavrentiev solution, look similar to those established for the Quasi-Reversibility method in [Inverse Problems 25, 035005, 2009]. There is a case for saying that this sort of ??super-convergence?? is rather inherent to the nature of the Cauchy problem and any reasonable regularization procedure would enjoy the same locally super-convergent behavior.     

Structured estimation of tire forces and the ground slope using SM observers

In agricultural context, the principal cause of serious accidents for all-terrain vehicles(ATVs) is rollover. The most important parameters related to this risk is the ground slope. In this paper, we propose a structured observer to estimate the system states and the longitudinal tire forces using only wheel angular velocities measurement. The robust estimation is based on a second order sliding mode observer. This estimation is then used to build up a ground slope estimation. The algorithm is composed by two cascaded estimators. This structured estimation is then applied to the model of an agricultural vehicle G7(GregoireTM) integrated in the driving simulation environment SCANeRTM-Studio.     

Real-time performance models for photovoltaic water pumping systems

This purpose of this paper is to develop and validate a model to accurately predict the cell temperature of a photovoltaic (PV) module that adapts to various mounting configurations, mounting locations, and climates while only requiring readily available data from the module manufacturer. Results from this model are also compared with results from published cell temperature models. The models were used to predict real-time performance from a PV water pumping systems in the desert of Medenine, south of Tunisia using 60-min intervals of measured performance data during one complete year. Statistical analysis of the predicted results and measured data highlights possible sources of errors and the limitations and/or adequacy of existing models, to describe the temperature and efficiency of PV-cells and consequently, the accuracy of performance of PV water pumping systems’ prediction models.     

Nanocomposites of PBAT and cellulose nanocrystals modified by in situ polymerization and melt extrusion

Cellulose nanocrystals (CNC) were successfully grafted with a low molecular weight poly(butylene glutarate) through an in situ polymerization procedure. The grafting treatment decreased the CNC hydrophilic character and increased the onset of their thermal degradation by approximately 20°C, thus increasing the possibilities of CNC application. Composites of grafted and nongrafted CNC with a poly(butylene‐adipate‐co‐terephthalate) (PBAT) matrix were prepared by melt extrusion. The CNC addition led to an increase of 50% of the tensile elastic modulus of the PBAT. In addition, dynamic mechanical thermal analysis showed that the composite with CNC retained its high modulus even at temperatures far above the glass transition temperature of PBAT. At 60°C the storage modulus of the composite with CNC was approximately 200% higher than that of the pure PBAT. Thus, in this work, nanocomposites of improved properties were obtained through a combination of in situ polymerization and melt extrusion. POLYM. ENG. SCI., 56:1339–1348, 2016. © 2016 Society of Plastics Engineers     

2-furyloxirane: II. Reduction,hydrolysis, alcoholsis and the uncatalysed polymerization induced by OH groups

The reduction of furyloxirane (FO) with different reducing agents was conducted under various experimental conditions and occurred essentially by the α-opening of the oxirane ring. It was also shown that the presence of Lewis acids favoured this mode of ring opening. The hydrolysis of furanic oxiranes was accompanied by oligomerization even in the absence of a catalyst. Moreover, very small quantities of water induced the oligomerization of FO giving degrees of polymerization of 40–50. This behaviour is unique since aliphatic and aromatic oxiranes are not activated by water alone. The alcoholysis of FO catalysed by metal alkoxides showed variable extents of α- and β-opening of the oxirane ring, depending on the steric hindrance of the alkoxide used.     

Urethanes and polyurethanes based on oxypropylated cork: 1. Appraisal and reactivity of products

The reaction of various polyols derived from the oxypropylation of cork with aliphatic and aromatic mono‐ and diisocyanates was studied in solution at room temperature. In all instances, good second‐order kinetics were observed and the corresponding rate constant determined. The reactivity of the aromatic isocyanate was found to be much higher than that of aliphatic counterparts. The ensuing urethanes and polyurethanes were characterised by FTIR and ¹H NMR spectroscopy, DSC and sol/gel distribution. © 2001 Society of Chemical Industry