全文获取类型
收费全文 | 520篇 |
免费 | 28篇 |
专业分类
电工技术 | 19篇 |
综合类 | 1篇 |
化学工业 | 163篇 |
金属工艺 | 20篇 |
机械仪表 | 11篇 |
建筑科学 | 6篇 |
能源动力 | 20篇 |
轻工业 | 33篇 |
水利工程 | 1篇 |
石油天然气 | 2篇 |
无线电 | 60篇 |
一般工业技术 | 107篇 |
冶金工业 | 64篇 |
原子能技术 | 13篇 |
自动化技术 | 28篇 |
出版年
2023年 | 8篇 |
2022年 | 11篇 |
2021年 | 20篇 |
2020年 | 7篇 |
2019年 | 11篇 |
2018年 | 18篇 |
2017年 | 12篇 |
2016年 | 17篇 |
2015年 | 6篇 |
2014年 | 22篇 |
2013年 | 29篇 |
2012年 | 29篇 |
2011年 | 35篇 |
2010年 | 20篇 |
2009年 | 23篇 |
2008年 | 23篇 |
2007年 | 25篇 |
2006年 | 31篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 14篇 |
2002年 | 5篇 |
2001年 | 7篇 |
2000年 | 6篇 |
1999年 | 2篇 |
1998年 | 7篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 7篇 |
1994年 | 11篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 11篇 |
1989年 | 7篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 2篇 |
1981年 | 5篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有548条查询结果,搜索用时 695 毫秒
1.
Atsushi Narumi Kosei Kawasaki Harumi Kaga Toshifumi Satoh Naoya Sugimoto Toyoji Kakuchi 《Polymer Bulletin》2003,49(6):405-410
Summary
The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]0 and [maltohexaose]0 of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and
showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit
(n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively.
Received: 29 November 2002/Accepted: 22 December 2002
Correspondence to Toyoji Kakuchi 相似文献
2.
Critical heat fluxes (CHFs) were measured for two types of rectangular ducts containing horizontal flat plate heaters. One has the flat plate heater of 6 mm wide and 20 mm long located on the inner lower wall at 50 mm from the inlet. The other duct has two horizontal flat plates of 6 mm wide and 20 mm long on inner upper and lower walls at 50 mm from the inlet. The equation of CHF for the forced convection containing a new nondimensional-parameter m introduced in order to calculate cross-sectionally averaged liquid temperature at the center of the duct was derived based on two fluid model, ordinary convection theorem and experimental results. It was confirmed that this correlation can describe not only the author's data on the duct but also other worker's data for channels with different shapes and sizes. 相似文献
3.
M Tanaka T Hakuto M Akatsuka E Morimoto T Hama M Morimoto Y Hiraga M Hyodo 《Canadian Metallurgical Quarterly》1993,42(6):883-887
We injected botulinum toxin to treat hemifacial spasm, and investigated the effects and the patient's impression of this treatment. Average duration of improvement lasted about 3.5 months in both the initial treatment group and the recurrent group. However the patients in the recurrent group received fewer units of botulinum toxin than those in the initial treatment group. Except for local paralysis that disappeared within a month, there were very few complications. Most patient were satisfied with this treatment. We conclude that the treatment of hemifacial spasm with botulinum toxin is both simple and useful. 相似文献
4.
The esters of dichloropropanols from the byproduct of hydrolysates during food processing were degraded by the cell-free extracts of a dichloropropanol-assimilating bacterium of Pseudomonas sp. OS-K-29. 1-Acyloxy-2,3-dichloropropane was hydrolysed into the corresponding carbonic acid and 2,3-dichloropropanol, and then the dichloropropanol was dechlorinated. The esterase activity of the cell-free extracts was effective for the esters of the dichloropropanols and monoacylglycerides, but not for hydrolysing the lipase substrates such as triacylglycerides and Tween 60. A comparative study using a series of octanoyl glycerides and the esters of the dichlopropanols showed that the substrate specificities of the cell-free extracts were similar to the monoacylglyceride lipase from Penicillium camembertii. 相似文献
5.
Ten-user truly asynchronous gigabit OCDMA transmission experiment with a 511-chip SSFBG en/decoder 总被引:8,自引:0,他引:8
Hamanaka T. Xu Wang Naoya Wada Nishiki A. Kitayama K. 《Lightwave Technology, Journal of》2006,24(1):95-102
A ten-user truly asynchronous gigabit coherent-optical-code-division-multiple-access (OCDMA) transmission was experimentally demonstrated without using any timing coordination. The enabling technologies are a record-length 511-chip superstructured-fiber-Bragg-grating (SSFBG) en/decoder and a supercontinuum (SC)-based optical-thresholding technique to significantly suppress the signal interference beat noise as well as the multiple-access-interference (MAI) noise. 相似文献
6.
F Deák á Horváth á Kiss Z Seres A Galonsky CK Gelbke H Hama L Heilbronn D Krofcheck WG Lynch DW Sackett HR Schelin MB Tsang J Kasagi T Murakami 《Canadian Metallurgical Quarterly》1995,52(1):219-227
An extruding wire knife was used to give adult male CFHB rats a minimally traumatic unilateral mechanical lesion of the medial forebrain bundle. In addition, some rats received bilateral intrastriatal injections of one of three fluorescent retrograde tracers either eight days before or eight days after the lesion. Injections made after the lesion revealed that about half of the animals had complete lesions of the nigrostriatal tract, while the other half were incompletely lesioned, the mean proportion of non-axotomized neurons being 23%. Over the 10 weeks following the lesions, the number of tyrosine hydroxylase-immunoreactive cells in the lesioned substantia nigra fell linearly, reaching a mean of 29% of that of the control substantia nigra. In the animals which were completely lesioned, neuronal survival at 10 weeks varied between 6 and 12%. That the disappearance of tyrosine hydroxylase-immunoreactive neurons was due to cell death rather than the loss of tyrosine hydroxylase itself was confirmed by labelling the cells with Fluoro Gold before axotomy; the tracer was seen in survival neurons, microglia and in a few involuted neurons which continued to be tyrosine hydroxylase-immunoreactive. This percentage of neurons surviving axotomy corresponds to the proportion of substantia nigra neurons which project to the contralateral striatum, and these neurons were in the region of the substantia nigra from which the contralateral projection originated. It is concluded that following mechanical transection of the nigrostriatal tract, all truly axotomized substantia nigra neurons die over a period of about 10 weeks. 相似文献
7.
Details of the vorticity field structure associated with the 3D Tollmien-Schlichting waves have been examined based upon the
recent numerical studies of the subject. First, a single obliquet-s wave has been found to have the velocity component parallel to the wave front playing an overall dominant role, in particular,
to create the longitudinal vorticity. The so-called Benney-Lin longitudinal vortices are then demonstrated to be, in fact,
a minor consequence compared with the localized longitudinal vorticity field and its periodic pumping. Finally, the formation
of the longitudinal vorticity field in the fundamental- and subharmonic-mode interactions is explained.
The research reported in this paper has been supported in part by Bundesministerium für Forschung und Technologie and by Deutsche
Forschungsgemeinschaft. The major part of the paper has been presented at the Third Asian Congress of Fluid Mechanics, 1–5
September 1986, in Tokyo, as a General Lecture by the senior author, FRH. 相似文献
8.
I. Hama T. Okamoto E. Hidai K. Yamada 《Journal of the American Oil Chemists' Society》1997,74(1):19-24
For the purpose of estimating the reaction mechanism of the direct ethoxylation of a fatty ester in the presence of an Al-Mg
composite oxide catalyst, a labeled fatty methyl ester C11H23CO18OCH3 containing 18O isotope was synthesized and directly ethoxylated. The product was evaluated by gas chromatography-mass spectrometry (GC-MS).
The GC-MS spectra showed that the 18O isotope label was present only in the methoxy group at the molecular end of the ethoxylated fatty methyl ester. This supports
the reaction mechanism of coordination anionic polymerization where the bond between the acyl and methoxy groups of the fatty
methyl ester molecule was broken, caused by the bifunctional effect of the acid-base active sites; an intermediate chemisorption
species was formed; and then ethylene oxide was addition-polymerized sequentially, in parallel. 相似文献
9.
Yoichi Shindo Naoya Katagiri Toichi Ebisuno Masatoshi Hasegawa Miyuki Mitsuda 《大分子材料与工程》1996,240(1):231-239
Poly (vinyl alcohol) with pendent styrylpyridinium groups (SbQ) is insolubilized by photoirradiation. An association takes place in SbQ groups. The association of polymer chains becomes marked with increasing the number of SbQ groups. Mainly intermolecular crosslinks were formed. Transparent and homogeneous macrogels consisting of several intermolecular crosslinks are obtained. The proportion of the free water to the bound water in PVA-SbQ gels was 3.3?2.9 despite of the large change in conversion of photodimerization of SbQ groups, x=0.27?0.58. The water uptake after swelling of the gels in water increased 6–27 times compared to the original weight at pH=7. The higher the degree of photocrosslinking, the lower was the degree of swelling. The water diffusion coefficients, D, were (2.2?5.8) × 10?5 cm2 S?1 for a 88% saponified PVA with 1 . 3 mol% SbQ groups. The volume of the gel increased discontinuously about 10-fold for the 99% saponified PVA with 0 . 096 mol% SbQ and 51% water (49% acetone). The acetone concentration at the transition decreased with increasing the degree of saponification of the PVA. 相似文献
10.
An investigation was undertaken on the application of dilute chitosan solutions gelled by tyrosinase‐catalyzed reaction with 3,4‐dihydroxyphenethylamine (dopamine). The tyrosinase‐catalyzed reaction with dopamine conferred water‐resistant adhesive properties to the semidilute chitosan solutions. The viscosity of the chitosan solutions increased highly by the tyrosinase‐catalyzed reaction and the subsequent reactions between o‐quinone compounds and chitosan. These highly viscous, gel‐like modified chitosan materials were allowed to spread onto the surfaces of the glass slides, which were tightly lapped together and held them in water. Tensile shear adhesive strength of over 400 kPa was observed for the modified chitosan samples. The increase in the amino group concentration of the chitosan solutions and the molecular mass of the chitosan used effectively led to the increase in adhesive strength of the glass slides. In addition, in the case where the chitosan solution was gelled by the enzymatic reaction with dopamine in the presence of poly(ethylene glycol), adhesive strength sharply increased at shorter reaction times concomitantly with the increase in the viscosity of the chitosan solutions because the tyrosinase activity effectively was retained by poly(ethylene glycol). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1818–1827, 2007 相似文献