Bibliometric analysis of publications in experimental particle physics on cosmic rays and with accelerators

In the first part, the present paper presents a quantitative analysis of physics publications in the domain of experimental particle physics, before the Second World War in the field of cosmic rays physics and for the modern times in the field of accelerator and collision rings experiments. In the second part, a more general study is made on publications in the various fields of physics separating contributions from experiment, theory and techniques. Three aspects of physics are enlightened: physics of exploration, physics of applications, and forefront physics.     

Traumatic myocardial infarction caused by lead shot

The authors report the case of a 32 year old woman who was shot with a shotgun. Acute inferior wall infarction was detected fortuitously on electrocardiography and coronary angiography showed occlusion of the right coronary artery with lead shot. The single coronary lesion, absence, of other cardiac complications (haemopericardium, cardiac perforation, ...) and the favourable outcome with conservative medical treatment has not been previously reported to the authors' knowledge.     

Partial or total silylation of dextran with hexamethyldisilazane

The silylation reaction of dextran with 1,1,1,3,3,3-hexamethyldisilazane (HMDS) in DMSO was studied as the first step of the synthesis of new amphiphilic polyester-grafted dextrans. According to the experimental conditions, i.e. dextran molar weight, medium temperature and reaction time, HMDS/OH ratio, addition of a catalyst and co-solvent, partially or totally silylated dextrans were recovered. The highest silylation yields were obtained with the lowest molecular weight dextrans. The increase in temperature medium and/or reaction time, the presence of catalyst or co-solvent favored the protection yield. Whatever the dextran used, complete silylation of the polysaccharide chain could be achieved by adequate selection of the experimental conditions. The thermal properties of resulting silylated polysaccharides were investigated by temperature modulated DSC. It was observed that T_g values of partially silylated dextran were maintained between 120 and 140 °C, independently of the dextran molecular weight. Interestingly, DMSO proved to behave as an efficient plasticizer of (partially) silylated dextrans. The partially silylated dextrans were efficiently used as multifunctional macroinitiators for the controlled ring-opening polymerization (ROP) of lactone. The ROP was then promoted from the remaining hydroxyl groups in the presence of tin or aluminium activator. After polymerization and ultimate deprotection of the silylated dextran backbone, amphiphilic polyester-grafted dextrans were readily recovered.     

Object-based crop identification using multiple vegetation indices, textural features and crop phenology

Crop identification on specific parcels and the assessment of soil management practices are important for agro-ecological studies, greenhouse gas modeling, and agrarian policy development. Traditional pixel-based analysis of remotely sensed data results in inaccurate identification of some crops due to pixel heterogeneity, mixed pixels, spectral similarity, and crop pattern variability. These problems can be overcome using object-based image analysis (OBIA) techniques, which incorporate new spectral, textural and hierarchical features after segmentation of imagery. We combined OBIA and decision tree (DT) algorithms to develop a methodology, named Object-based Crop Identification and Mapping (OCIM), for a multi-seasonal assessment of a large number of crop types and field status.In our approach, we explored several vegetation indices (VIs) and textural features derived from visible, near-infrared and short-wave infrared (SWIR) bands of ASTER satellite scenes collected during three distinct growing-season periods (mid-spring, early-summer and late-summer). OCIM was developed for 13 major crops cultivated in the agricultural area of Yolo County in California, USA. The model design was built in four different scenarios (combinations of three or two periods) by using two independent training and validation datasets and the best DTs resulted in an error rate of 9% for the three-period model and between 12 and 16% for the two-period models. Next, the selected DT was used for the thematic classification of the entire cropland area and mapping was then evaluated applying the confusion matrix method to the independent testing dataset that reported 79% overall accuracy. OCIM detected intra-class variations in most crops attributed to variability from local crop calendars, tree-orchard structures and land management operations. Spectral variables (based on VIs) contributed around 90% to the models, although textural variables were necessary to discriminate between most of the permanent crop-fields (orchards, vineyard, alfalfa and meadow). Features extracted from late-summer imagery contributed around 60% in classification model development, whereas mid-spring and early-summer imagery contributed around 30 and 10%, respectively. The Normalized Difference Vegetation Index (NDVI) was used to identify the main groups of crops based on the presence and vigor of green vegetation within the fields, contributing around 50% to the models. In addition, other VIs based on SWIR bands were also crucial to crop identification because of their potential to detect field properties like moisture, vegetation vigor, non-photosynthetic vegetation and bare soil. The OCIM method was built using interpretable rules based on physical properties of the crops studied and it was successful for object-based feature selection and crop identification.     

DOPO‐Based Phosphorus‐Containing Methacrylic (Co)Polymers: Glass Transition Temperature Investigation

A two‐step synthetic procedure is designed for preparing new flame‐retardant methacrylic monomers containing 9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide (DOPO) as a substituent side group. DOPO and methacrylate moieties are linked by linear aliphatic hydrocarbon spacers (3 to 11 carbon atoms). Copolymerization with methyl methacrylate is carried out leading to copolymers containing between 2 and 10 wt% phosphorus. All homo‐ and copolymers exhibit a unique glass transition temperature (T_g ). A new group contribution for DOPO‐based substituent is extracted that leads to reasonable estimations of T_g s of other published polymers. The Fox equation provides a good estimation of T_g s for most copolymers and for physical blends of poly(methyl methacrylate) (PMMA) and DOPO. When using monomers having three and four carbon atoms in the hydrocarbon spacer, the T_g of copolymers remains close to that of PMMA over a wide range of composition.     

NMR imaging of low pressure,gas‐phase transport in packed beds using hyperpolarized xenon‐129

Gas‐phase magnetic resonance imaging (MRI) has been used to investigate heterogeneity in mass transport in a packed bed of commercial, alumina, catalyst supports. Hyperpolarized ¹²⁹Xe MRI enables study of transient diffusion for microscopic porous systems using xenon chemical shift to selectively image gas within the pores, and, thence, permits study of low‐density, gas‐phase mass‐transport, such that diffusion can be studied in the Knudsen regime, and not just the molecular regime, which is the limitation with other current techniques. Knudsen‐regime diffusion is common in many industrial, catalytic processes. Significantly, larger spatial variability in mass transport rates across the packed bed was found compared to techniques using only molecular diffusion. It has thus been found that that these heterogeneities arise over length‐scales much larger than ～100 µm. © 2015 American Institute of Chemical Engineers AIChE J, 61: 4013–4019, 2015     

The implementation of insertion and deletion algorithms for 1–2 brother trees

We derive an implementation in PASCAL of the insertion and deletion algorithms for 1–2 brother trees. The implementation is of interest not only in its own right but also in that it has given rise to an improved deletion algorithm.     

From relative to absolute quantification of tryptic peptides with tandem mass tags: application to cerebrospinal fluid

Quantification is a major task in proteomics. Among the different analytical strategies to enable peptide and protein quantification, tagging with isotopic labels has emerged as a practical, versatile, and efficient alternative. In particular, isobaric labels, such as TMT or iTRAQ, are now widely employed to make relative comparison of the protein amounts in separate biological samples with tandem mass spectrometry (MS/MS). We used herein a shotgun proteomic approach based on labelling with tandem mass tags (TMTs) for the relative quantification of proteins, and the absolute quantification of their tryptic peptides in human cerebrospinal fluid (CSF). First, the comparison of ante- and post-mortem CSF samples was carried out for the discovery of protein marker candidates of brain-damage disorders. Second, tryptic peptides representative of these candidates were measured in CSF using reporter-ion calibration curves. These works highlighted the advantages and limitations of such strategies for quantification purposes in proteomics.