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排序方式: 共有1829条查询结果,搜索用时 31 毫秒
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Mani Balamurugan Hui‐Yun Jeong Venkata Surya Kumar Choutipalli Jung Sug Hong Hongmin Seo Natarajan Saravanan Jun Ho Jang Kang‐Gyu Lee Yoon Ho Lee Sang Won Im Venkatesan Subramanian Sun Hee Kim Ki Tae Nam 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(25)
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO2 to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO2 to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO2 in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions. 相似文献
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Soumya Ghosh Chowdhury Jagannath Chanda Sreedip Ghosh Koushik Banerjee Shib Shankar Banerjee Amit Das Prasenjit Ghosh Sanjay Kr. Bhattacharyya Rabindra Mukhopadhyay 《Polymer Engineering and Science》2020,60(8):1973-1983
Proficiency on underlying mechanism of rubber-metal adhesion has been increased significantly in the last few decades. Researchers have investigated the effect of various ingredients, such as hexamethoxymethyl melamine, resorcinol, cobalt stearate, and silica, on rubber-metal interface. The role of each ingredient on rubber-metal interfacial adhesion is still a subject of scrutiny. In this article, a typical belt skim compound of truck radial tire is selected and the effect of each adhesive ingredient on adhesion strength is explored. Out of these ingredients, the effect of cobalt stearate is found noteworthy. It has improved adhesion strength by 12% (without aging) and by 11% (humid-aged), respectively, over control compound. For detailed understanding of the effect of cobalt stearate on adhesion, scanning electron microscopy and energy dispersive spectroscopy are utilized to ascertain the rubber coverage and distribution of elements. X-ray photoelectron spectroscopy results helped us to understand the impact of CuXS layer depth on rubber-metal adhesion. The depth profile of the CuXS layer was found to be one of the dominant factors of rubber-metal adhesion retention. Thus, this study has made an attempt to find the impact of different adhesive ingredients on the formation of CuXS layer depth at rubber-metal interface and establish a correlation with adhesion strength simultaneously. 相似文献
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V. Vassilev S. Thijs P. L. Segura P. Wambacq P. Leroux G. Groeseneken M. I. Natarajan H. E. Maes M. Steyaert 《Microelectronics Reliability》2005,45(2):255-268
This paper describes an approach to design ESD protection for integrated low noise amplifier (LNA) circuits used in narrowband transceiver front-ends. The RF constraints on the implementation of ESD protection devices are relaxed by co-designing the RF and the ESD blocks, considering them as one single circuit to optimise. The method is applied for the design of 0.25 μm CMOS LNA. Circuit protection levels higher than 3 kV HBM stress are achieved using conventional highly capacitive ggNMOS snapback devices. The methodology can be extended to other RF-CMOS circuits requiring ESD protection by merging the ESD devices in the functionality of the corresponding matching blocks. 相似文献
7.
Lean philosophy: implementation in a forging company 总被引:2,自引:2,他引:0
Ajit Kumar Sahoo N. K. Singh Ravi Shankar M. K. Tiwari 《The International Journal of Advanced Manufacturing Technology》2008,36(5-6):451-462
This research addresses the implementation of lean philosophy in a forging company with a focus on radial forging production
flow lines. Here, the prime motive is to evolve and test several strategies to eliminate waste on the shop floor. In this
research, a systematic approach is suggested for the implementation of lean principles. This paper describes an application
of value stream mapping (VSM). Consequently, the present and future states of value stream maps are constructed to improve
the production process by identifying waste and its sources. Furthermore, Taguchi’s method of design of experiments is pursued
here to minimize the forging defects produced due to imperfect operating conditions. A noticeable reduction in set-up time
and work-in-process (WIP) inventory level is substantiated. Finally, we conclude with a discussion of managerial implications
and the future scope of research. 相似文献
8.
The Design of Discrimination Experiments 总被引:1,自引:0,他引:1
Experimentation plays a fundamental role in scientific discovery. Scientists experiment to gather data, investigate phenomena, measure quantities, and test theories. In this article, we address the problem of designing experiments to discriminate between two completing theories. Given an initial situation for which the two theories make the same prediction, the experiment design problem is to determine how to modify the situation such that the two theories make different predictions for the modified situation. The modified situation is called a discrimination experiment. We present a knowledge-intensive method called DEED for designing discrimination experiments. The method analyzes the differences in the two theories' explanations of the prediction for the initial situation. Based on this analysis, it determines modifications to the initial situation that will result in a discrimination experiment. We illustrate the method with the design of experiments to discriminate between several pairs of qualitative theories in the fluids domain. 相似文献
9.
Hongxuan Zhang Venkatesha S. Minahan R. Sherman D. Oweis Y. Natarajan A. Thakor N.V. 《IEEE engineering in medicine and biology magazine》2006,25(4):39-45
Intraoperative neurological monitoring (INM) is the evaluation of the nervous system within the operating room (OR) environment. In this paper, the INM system is tested in a clinical setting in comparison with conventional somatosensory evoked potential (SEP) monitoring. The study results demonstrate the capability of the INM system in extracting clearer and more stable SEP signals. The high SNR of SEP signals collected in various clinical environments, including the OR, makes the INM system a robust platform for continuous monitoring. While the current use of EP monitoring is limited to intermittent analysis by a highly trained clinical neurophysiologist, the authors believe in changing this paradigm by developing continuous monitoring systems, such as the INM system, capable of automated quantitative EP analysis. This noninvasive monitoring modality will allow for a wider range of use in clinical practice. Based on volunteer and clinical patient studies, the INM monitoring system demonstrates much greater reliability and accuracy via the artifact rejection and denoising strategies. It provides more strategic filtering options for different situations under which the clinical SEP response signal could be greatly contaminated and distorted. Furthermore, the INM system offers a promising approach to signal extraction in real-time monitoring during SEP research. 相似文献
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