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1.
Anacardic acids, 6-pentadec(en)ylsalicylic acids isolated from the cashew Anacardium occidentale L. (Anacardiaceae) nut and apple, were found to possess preventive antioxidant activity while salicylic acid did not show this activity. These anacardic acids prevent generation of superoxide radicals by inhibiting xanthine oxidase (EC 1.1.3.22, Grade IV) without radical-scavenging activity. Notably, the inhibition kinetics of anacardic acids do not follow hyperbolic dependence of enzyme inhibition on inhibitor contents (Michaelis–Menten equation) but follow the Hill equation instead. Anacardic acid (C15:1) inhibited the soybean lipoxygenase-1 (EC 1.13.11.12, Type 1) catalyzed oxidation of linoleic acid with an IC50 of 6.8 μM. The inhibition is a slow and reversible reaction without residual enzyme activity. The inhibition kinetics indicate that anacardic acid (C15:1) is a competitive inhibitor and the inhibition constant, KI, was 2.8 μM. Anacardic acids act as antioxidants in a variety ways, including inhibition of various prooxidant enzymes involved in the production of the reactive oxygen species and chelate divalent metal ions such as Fe2+ or Cu2+, but do not quench reactive oxygen species. The C15-alkenyl side chain is largely associated with the activity. 相似文献
2.
Jagadeeswari Sivanadanam Ramesh Mukkamala Sudip Mandal Raman Vedarajan Noriyoshi Matsumi Indrapal Singh Aidhen Kothandaraman Ramanujam 《International Journal of Hydrogen Energy》2018,43(9):4691-4705
Six triphenylamine-based dyes were explored for their application in dye-sensitized solar cells (DSSCs). Dyes 1–3 and dyes 4–6 possess cyanoacrylic acid (C-acceptor) and rhodanine-3-acetic acid (R-acceptor), respectively. Stilbene (in dyes 2 and 5) and bis(styryl)benzene (in dyes 3 and 6) were used as π-spacers. There is no π-spacer in the dye 1 and 4. To elucidate the role of π-spacers, optical, electrochemical, and photovoltaic properties of the dyes were studied. Among C-acceptor dyes, dye 2 exhibits the highest light-to-electricity conversion efficiency of 4.45%, followed by dye 3 (4.16%). Similarly, among R-acceptor dyes, dye 5 is the best. These results indicate that stilbene is a better π-spacer over bis(styryl)benzene. Although bis(styryl)benzene could extend the light absorption range (in dye-adsorbed TiO2 film), its tendency to promote intermolecular π-π stacking is possibly the reason for its poor performance in DSSCs. Furthermore, the conjugation break in the R-acceptor moiety attached to the TiO2 surface limits the electron injection of R-acceptor dyes poorer than C-acceptor dyes. Density functional theory calculations were performed for the dye-(TiO2)8 cluster, assuming a bidentate chelation of a carboxylic acid group with Ti4+ of TiO2 anatase. The natural bond orbital (NBO) analysis indicated relatively more electron-accepting ability of cyanoacrylic acid over rhodanine-3-acetic acid. 相似文献
3.
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5.
Koizumi H Yamamoto T Maki A Yamashita Y Sato H Kawaguchi H Ichikawa N 《Applied optics》2003,42(16):3054-3062
We will briefly review the present status of optical topography and then discuss the method of improving practicality, i.e., the signal-to-noise (S/N) ratio and the spatial resolution in observations of higher-order brain functions. The optimum wavelength pair improved the S/N ratio sixfold for deoxyhemoglobin, and new configurations of light irradiation and detection positions doubled the spatial resolution. We also report on developing application fields of optical topography. This modality will bridge the gap between natural sciences, neuroscience, and pedagogy, and show actual real-time brain activity. 相似文献
6.
Yasuyoshi Fukui Hiroshi Okada Noriyoshi Kumazawa Yashimi Watanabe 《Metallurgical and Materials Transactions A》2000,31(10):2627-2636
A possibility to make near-net-shape functionally graded material (FGM) products has been examined. The FGM billets having
a graded volume fraction of Al3Ni in thickness direction were machined from an Al-Al3Ni FGM thick-walled tube manufactured by a vacuum centrifugal method. Billets, which were set in the container for the backward
extruding, were heated to 650 °C to 680 °C, at which temperature the FGM becomes a mixture of molten aluminum eutectic and
solid intermetallics. Then, billets were extruded successfully to FGM cups by a semisolid forming, except at 650 °C. Residual
bulky Al3Ni particles are found at higher temperature. Thus, an optimum operation temperature is found to be around 660 °C, because
bulky Al3Ni particles transform to fine spheroidal or fibrous shape after the forming. The volume fraction of intermetallics at the
bottom region of the cup was condensed more than 60 vol pct in a proper billet setting. 相似文献
7.
Summary
Novel poly(ethynylene-phenylene-ethynylene-borane)s were prepared by polycondensation between bifunctional lithium acetylide
and aryldimethoxyborane. The polymers obtained are expected as a novel type of organoboron π-conjugated polymers via vacant
p-orbital of boron atom. The polymerization between dilithium 2,5-didodecyloxybenzene- 1,4-diethynilide and tripyldimethoxyborane
[tripyl=2,4,6-triisopropylphenyl] gave the corresponding polymer in 67% yield. From gel permeation chromatographic analysis
(THF, PSt standards), the number-average molecular weight of the polymer was found to be 2700. In the UV-vis spectrum of the
polymer (in chloroform at room temperature), an absorption maximum was observed at 397 nm. The fluorescence emission spectrum
(in chloroform, room temperature, excitation wavelength at 400 nm) showed its λmax at 456 nm in the visible blue region. The polymers obtained were very soluble in common organic solvents such as THF, chloroform
and benzene.
Received: 11 April 2000/Accepted: 22 April 2000 相似文献
8.
Summary
Alternating boration copolymerization between 1,4-diallenylbenzene (2) and 2,7-diethynylfluorene (3) was examined using diphenylbromoborane (1) to give the corresponding copolymer (4). The organoboron copolymer obtained was characterized by 1H-, 11B-NMR, IR, and UV-vis absorption spectra.
Received: 5 August 1999/Accepted: 31 August 1999 相似文献
9.
Ohgi Takahashi Ryota Kirikoshi Noriyoshi Manabe 《International journal of molecular sciences》2015,16(6):12174-12184
In glacial acetic acid, phthalanilic acid and its monosubstituents are known to be converted to the corresponding phthalimides in relatively good yields. In this study, we computationally investigated the experimentally proposed two-step (addition-elimination or cyclization-dehydration) mechanism at the second-order Møller-Plesset perturbation (MP2) level of theory for the unsubstituted phthalanilic acid, with an explicit acetic acid molecule included in the calculations. In the first step, a gem-diol tetrahedral intermediate is formed by the nucleophilic attack of the amide nitrogen. The second step is dehydration of the intermediate to give N-phenylphthalimide. In agreement with experimental findings, the second step has been shown to be rate-determining. Most importantly, both of the steps are catalyzed by an acetic acid molecule, which acts both as proton donor and acceptor. The present findings, along with those from our previous studies, suggest that acetic acid and other carboxylic acids (in their undissociated forms) can catalyze intramolecular nucleophilic attacks by amide nitrogens and breakdown of the resulting tetrahedral intermediates, acting simultaneously as proton donor and acceptor. In other words, double proton transfers involving a carboxylic acid molecule can be part of an extensive bond reorganization process from cyclic hydrogen-bonded complexes. 相似文献
10.
Qing-qing LU Takuto KANETSUKI Shin-ichi YAMASAKI Ryoichi YAMADA Takahiro WATANABE Noriyoshi TSUCHIYA 《中国有色金属学会会刊》2014,24(6):1880-1889
Focusing on the origin of the heavy metal, this study aims to build an imputed method to estimate the heavy metal content in river water by making a distinction between the heavy metal of natural origins and that caused by human activities. Supported by GIS, Kosaka watershed within the Hokuroku basin was divided into several sub-watershed polygons and the outflows of water and Cu were calculated for each polygon. Compared with the natural origin, the dominant Cu emissions affected the river water more significantly in local. Based on the mass balance closure, the heavy metal content of Cu in the Kosaka River was estimated by the conflux accumulation of tributaries and mine drainages. The estimated Cu concentrations were checked by comparing with the actually measured values at monitoring points along the Kosaka River and the results are coincidence with each other in general. It is revealed that the mainstream water quality could be estimated by seizing the water quality of upstream tributaries and human drainages. 相似文献