Evaluation of the Growth of Dislocations Density in Fatigue Loading Process via Electrical Resistivity Measurements

The paper focuses on quantitative evaluation of the microstructural changes - growth of the dislocation density - in stainless steel specimens subjected to fatigue loading. We propose to use electrical resistivity measurements for this goal. Change in electrical resistance of the specimens has been monitored in dependence on the number of fatigue cycles and the relative growth of the dislocation density was calculated from these data and known values of the specific resistivity of dislocations for iron. We also estimated the growth of dislocation density using analysis of Scanning Electron Microscopy (SEM) images of etched specimens. This estimate however appears to be unreasonably low, so that SEM may be used for qualitative analysis only.     

Magnetotransport Properties and Electronic Structure of Ni 8 1 Fe 1 9 /W 9 0 Ti 1 0 Multilayers

The magnetotransport properties of Ni₈₁Fe₁₉/W₉₀Ti₁₀ multilayers are investigated. The effect of the thicknesses of magnetic (Ni₈₁Fe₁₉) and nonmagnetic (WTi) layers on the magnetoresistance (MR) is theoretically discussed in the framework of the Johnson–Camley semiclassical approach based on the Boltzmann transport equation. A comparison between the calculated and measured MR ratios is obtained. The observed MR ratio oscillates for WTi layer thickness with an average period of 10 Å. A weak MR(t_NiFe) ratio for a fixed t_WTi is obtained, and it presents a maximum peak of the MR with a value of 0.8 % located at t_NiFe = 50 Å. In addition, electronic and magnetic properties of multilayers are investigated by self-consistent ab initio calculations based on the Korringa–Kohn–Rostocker (KKR) approximation. Spin polarized within the framework of the coherent potential approximation (CPA) is considered for calculations.     

鄂尔多斯盆地上古生界低压气藏成因

鄂尔多斯盆地上古生界气藏具有明显的低压特征,其流体压力梯度东高西低,与现今构造形态基本一致。研究表明,剥蚀期间的温度下降和后期埋深的增加是造成上古生界气藏低压形成的主要原因。对苏里格气田的实例研究表明,在150℃成藏时,流体压力梯度约为1.22MPa/100m;温度下降时,压力梯度下降14.9%,到白垩纪末压力梯度约为1.06MPa/100m。在新生代,随着埋深增加,压力梯度再下降21.4%,从而形成典型的低压气藏。     

空间激光通信精跟踪单元的高精度快速PZT驱动技术研究

为保证空间激光通信的顺利进行,精跟踪系统执行机构驱动器设计至关重要.在分析压电陶瓷自身特性的基础上,研制一种基于PA93的高压、大电流、高速率的新型压电陶瓷驱动电源,并对所设计的驱动电源的输出电压稳定性、范围、线性度、静态纹波,带宽等各项性能指标进行测试,得以验证该驱动电源的性能满足了整个精跟踪系统的跟踪精度保持在3μrad左右的前提条件.     

Biosynthesis of the Myxobacterial Antibiotic Corallopyronin A

Corallopyronin A is a myxobacterial compound with potent antibacterial activity. Feeding experiments with labelled precursors resulted in the deduction of all biosynthetic building blocks for corallopyronin A and revealed an unusual feature of this metabolite: its biosynthesis from two chains, one solely PKS‐derived and the other NRPS/PKS‐derived. The starter molecule is believed to be carbonic acid or its monomethyl ester. The putative corallopyronin A biosynthetic gene cluster is a trans‐AT‐type mixed PKS/NRPS gene cluster, containing a β‐branching cassette. Striking features of this gene cluster are a NRPS‐like adenylation domain that is part of a PKS‐type module and is believed to be responsible for glycine incorporation, as well as split modules with individual domains occurring on different genes. It is suggested that CorB is a trans‐acting ketosynthase and it is proposed that it catalyses the Claisen condensation responsible for the interconnection of the two chains. Additionally, the stereochemistry of corallopyronin A was deduced by a combination of a modified Mosher's method and ozonolysis with subsequent chiral GC analyses.     

Tunnel diode oscillator circuit for surface impedance measurement of thin films near 20 MHz

We describe and analyse a simple method for the measurement of thin film surface impedance in the frequency range 10–20 MHz. This method is based on the analysis of both the frequency shift and the amplitude variation of the signal in a tunnel diode oscillator circuit inductively coupled to the sample. The sensitivity of the method to the conducting properties of the thin films is a function which is greatly dependent on geometrical parameters and which can be easily optimized and included in the response calculation. The analysis is illustrated by examples with superconducting and normal metal films. The resolution of the measurements is also discussed.     

Synthesis of thermoreactive polysiloxanes with cyclic fragments in the side chain

The synthesis of polysiloxanes with pendant unsaturated cyclic fragments have been successfully performed by hydrosilylation reactions of polymethylhydrosiloxane with 4‐vinyl‐1‐cyclohexene in the presence of platinum hydrochloric acid (0.1 M solution in THF), Karstedt's catalyst (Pt₂[(VinSiMe₂)₂O]₃) and platinum on the charcoal (5%). Reactions were carried out at various temperatures with different ratios of initial compounds. It was shown, that not all active ≡Si? H groups take part in the hydrosilylation reaction. Some kinetic parameters of reactions were studied. The synthesized oligomers were characterized by FTIR, ¹H, ¹³C, H,H‐COSY, and C,H‐correlation NMR spectroscopy. Calculations using the quantum‐chemical semi empirical AM1 method for modeling reactions between methyldimethoxysilane [Me(MeO)₂SiH] and 4‐vinyl‐1‐cyclohexene were performed to evaluate possible reaction paths. Synthesized oligomers were characterized by gel‐permeation chromatography, differential scanning calorimetric, thermogravimetric, and wide‐angle X‐ray analyses. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Accelerant‐promoted free radical polymerization of methacrylates by stabilized nitroxide unimolecular initiators: synthesis and characterization

BACKGROUND: This investigation evaluates the effectiveness of initiator adducts for living and controlled polymerization of methacrylates, crosslinking of dimethacrylates and thermal stabilities of the resulting polymers. Adducts of 2,2,6,6‐tetramethyl‐1‐piperidinyloxy with benzoyl peroxide and with azobisisobutyronitrile were prepared and evaluated as stabilized unimolecular initiators for the free radical polymerization of methacrylate monomers using sulfuric acid as catalyst. The monomers used were methyl methacrylate, triethylene glycol dimethacrylate (TEGDMA) and ethoxylated bisphenol A dimethacrylate (EBPADMA). RESULTS: Successful polymerization was achieved at 70 and 130 °C with reaction times ranging from 45 min to 120 h. The dispersity (D) of poly(methyl methacrylate) (PMMA) was 1.09–1.28. The livingness and extent of control over polymerization were confirmed with plots of M_n evolution as a function of monomer conversion and of the first‐order kinetics. The glass transition temperature (T_g) for PMMA was 123–128 °C. The degradation temperature (T_d) for PMMA was 350–410 °C. T_d for poly(TEGMA) was 250–310 °C and for poly(EBPADMA) was 320–390 °C. CONCLUSION: The initiators are suitable for free radical living and controlled polymerization of methacrylates and dimethacrylates under mild thermal and acid‐catalyzed conditions, yielding medium to high molecular weight polymers with low dispersity, high crosslinking and good thermal stability. Copyright © 2008 Society of Chemical Industry