Nuclear numerical range and quantum error correction codes for non-unitary noise models

Quantum Information Processing - We present an efficient protocol to rapidly generate a three-dimensional entangled state for two atoms trapped in a cavity with quantum Zeno dynamics and...     

Impact of Ozonation Process on the Microbiological Contamination and Antioxidant Capacity of Highbush Blueberry (Vaccinum corymbosum L.) Fruit during Cold Storage

In the studies conducted, the impact of the innovative ozonation procedure on the microbial state and antioxidant potential of highbush blueberry (Vaccinum corymbosum L.) stored under cold storage conditions was assessed. Microbiological analysis was carried out to determine the total number of mesophilic aerobic bacteria and the total number of fungi during the storage experiment. In addition, changes in the flavonoid, anthocyanins, and vitamin C content and the total antioxidant capacity were monitored during the storage. The degree of fruit infection with gray mold and anthracnose was determined. It was found that daily ozonation of fruits with a dose of 15 ppm for 30 min, every 12 h, for 28 days effectively reduced the development of aerobic mesophilic bacteria and fungi. On the last day of storage, symptoms of the infection by gray mold were observed in 27.5% of the control fruit, while the absence of symptoms was observed in case of the ozonated fruit. On the other hand, ozone was ineffective in case of inhibiting the infection by anthracnose. Nevertheless, the ozonation process allowed maintaining a high antioxidant potential of the fruit and substantially reduced losses of flavonoids, anthocyanins, and vitamin C. The utilized procedure has proved to be effective, providing the possibility of extensive use of ozone as a factor allowing sustaining a high commercial and consumption value of the fruit over extended time.     

A Critical Role for the Presence of Lignocellulosic Material in the Determination of Wood Buffering Capacity

The currently used determinations of wood buffering capacity, which are based on pH-metric titrations of aqueous wood extracts, neglect the effect of lignocellulosic material and the role of its insoluble constituents. This study examined the influence of the presence of wood in a system subjected to titration. A comparison of the results obtained from pine chip extracts and chip suspensions showed that the presence of wood and the wood-to-water ratio were critical factors that affected the measurement of the wood buffering capacity. The evidence showed that the resulting determination may vary by up to six times (0.28–1.99 ml/g), depending upon the conditions of the titration. In addition, it was found that the presence of wood had a neutralizing effect over the course of prolonged pH observations.     

The comparison of low‐velocity impact resistance of aluminum/carbon and glass fiber metal laminates

This article presents the low‐velocity impact response of fiber metal laminates, based on aluminum with a polymer composite, reinforced with carbon and glass fibers. The influence of fiber orientations as well as analysis of load‐time history, damage area and damage depth in relation to different energy levels is presented and discussed. The obtained results made it possible to determine characteristic points, which may be responsible for particular stages of the laminate structure degradation process: local microcracks and delaminations, leading to a decrease in the stiffness of the laminate, as well as further damage represented by laminate cracks and its perforation. The damage mechanism of fiber metal laminates is rather complex. In case of carbon fiber laminates, a higher tendency to perforation was observed in comparison to laminates containing glass fibers. Delaminations in composite interlayers and at the metal/composite interface constitute a significant damage form of fiber metal laminates resulting from dynamic loads. Fiber metal laminates with glass fibers absorb energy mainly through plastic deformation as well as through delamination initiation and propagation, whereas laminates containing carbon fibers absorb energy for penetration and perforation of the laminate. POLYM. COMPOS. 37:1056–1063, 2016. © 2014 Society of Plastics Engineers     

KINETICS OF PAHS LOSSES AND RELATIONSHIPS BETWEEN PAHS PROPERTIES AND PROPERTIES OF SOIL IN SEWAGE SLUDGE-AMENDED SOIL

Abstract

The properties of soil determine the activity of its microflora which is responsible for the degradation of polycyclic aromatic hydrocarbons (PAHs). Moreover, soil properties influence the strength of the interactions between the PAHs and individual soil components. The introduction of sewage sludge into the soil changes these properties which, in turn, changes environmental conditions. In the present studies, relationships between the PAH content and changes in selected soil properties (pH, CEC, TEB, BS, N _t ) have been evaluated. The present experiment was carried out in two blocks of experimental plots divided according to the type of plants grown. In the first block, the following field plants were grown in specific sequence, (maize, spring barley, winter rape, potatoes and cereal mixture) while in the other block a perennial, i.e. willow, was grown. Plant cultivation was carried out for 54 months, whereas the cultivation of the willow was conducted over 42 months. Each block consisted of 6 plots with a surface area of 15 m² into which sewage sludge had been introduced in the following doses: soil without fertilization – control, sludge 30, 75, 150, 300, 600 t/ha. Both the disappearance rate and the scope of the individual polycyclic aromatic hydrocarbons as determined by their respective half-lives showed that losses of these compounds depended on the sewage sludge properties (among other things, the pollutant content) as well as the sludge dose and the type of area used. The correlation coefficients determined depended on the sludge dose and the experimental variant. The highest frequency of their occurrence was found in the case of the total sum of nitrogen and cation exchange capacity for the highest sludge doses (in the experimental with willow).     

Solvent Screening for Solubility Enhancement of Theophylline in Neat,Binary and Ternary NADES Solvents: New Measurements and Ensemble Machine Learning

Theophylline, a typical representative of active pharmaceutical ingredients, was selected to study the characteristics of experimental and theoretical solubility measured at 25 °C in a broad range of solvents, including neat, binary mixtures and ternary natural deep eutectics (NADES) prepared with choline chloride, polyols and water. There was a strong synergistic effect of organic solvents mixed with water, and among the experimentally studied binary systems, the one containing DMSO with water in unimolar proportions was found to be the most effective in theophylline dissolution. Likewise, for NADES, the addition of water (0.2 molar fraction) resulted in increased solubility compared to pure eutectics, with the highest solubilisation potential offered by the composition of choline chloride with glycerol. The ensemble of Statistica Automated Neural Networks (SANNs) developed using intermolecular interactions in pure systems has been found to be a very accurate model for solubility computations. This machine learning protocol was also applied as an extensive screening for potential solvents with higher solubility of theophylline. Such solvents were identified in all three subgroups, including neat solvents, binary mixtures and ternary NADES systems. Some methodological considerations of SANNs applications for future modelling were also provided. Although the developed protocol is focused exclusively on theophylline solubility, it also has general importance and can be used for the development of predictive models adequate for solvent screening of other compounds in a variety of systems. Formulation of such a model offers rational guidance for the selection of proper candidates as solubilisers in the designed solvents screening.     

Vortex Dynamics in hcp Solid 4He

The peculiar features noted in (Penzev et al. in Phys. Rev. Lett. 101: 065301, 2008) we conjecture are evidence of a vortex fluid state in solid He. We suggest to analyze this state by means of the dynamics of quantized vortices, as used for the tangle of vortices in superfluid turbulence. We introduce parameters of the vortex tangle dynamics, e.g., relaxation time for the drift of lines in parallel to the torsional oscillation axis. We briefly discuss the transition from the supposed vortex fluid state into the supposed supersolid state (Shimizu et al. in Phys. Rev. Lett., arXiv:0903.1326).     

Multirepresentation,Multiheuristic A* search‐based motion planning for a free‐floating underwater vehicle‐manipulator system in unknown environment

A key challenge in autonomous mobile manipulation is the ability to determine, in real time, how to safely execute complex tasks when placed in unknown or changing world. Addressing this issue for Intervention Autonomous Underwater Vehicles (I‐AUVs), operating in potentially unstructured environment is becoming essential. Our research focuses on using motion planning to increase the I‐AUVs autonomy, and on addressing three major challenges: (a) producing consistent deterministic trajectories, (b) addressing the high dimensionality of the system and its impact on the real‐time response, and (c) coordinating the motion between the floating vehicle and the arm. The latter challenge is of high importance to achieve the accuracy required for manipulation, especially considering the floating nature of the AUV and the control challenges that come with it. In this study, for the first time, we demonstrate experimental results performing manipulation in unknown environment. The Multirepresentation, Multiheuristic A* (MR‐MHA*) search‐based planner, previously tested only in simulation and in a known a priori environment, is now extended to control Girona500 I‐AUV performing a Valve‐Turning intervention in a water tank. To this aim, the AUV was upgraded with an in‐house‐developed laser scanner to gather three‐dimensional (3D) point clouds for building, in real time, an occupancy grid map (octomap) of the environment. The MR‐MHA* motion planner used this octomap to plan, in real time, collision‐free trajectories. To achieve the accuracy required to complete the task, a vision‐based navigation method was employed. In addition, to reinforce the safety, accounting for the localization uncertainty, a cost function was introduced to keep minimum clearance in the planning. Moreover a visual‐servoing method had to be implemented to complete the last step of the manipulation with the desired accuracy. Lastly, we further analyzed the approach performance from both loose‐coupling and clearance perspectives. Our results show the success and efficiency of the approach to meet the desired behavior, as well as the ability to adapt to unknown environments.     

Influence of Alkyl Chain Length on Thermal Properties,Structure, and Self-Diffusion Coefficients of Alkyltriethylammonium-Based Ionic Liquids

The application of ionic liquids (ILs) has grown enormously, from their use as simple solvents, catalysts, media in separation science, or electrolytes to that as task-specific, tunable molecular machines with appropriate properties. A thorough understanding of these properties and structure–property relationships is needed to fully exploit their potential, open new directions in IL-based research and, finally, properly implement the appropriate applications. In this work, we investigated the structure–properties relationships of a series of alkyltriethylammonium bis(trifluoromethanesulfonyl)imide [TEA-R][TFSI] ionic liquids in relation to their thermal behavior, structure organization, and self-diffusion coefficients in the bulk state using DSC, FT-IR, SAXS, and NMR diffusometry techniques. The phase transition temperatures were determined, indicating alkyl chain dependency. Fourier-transformed infrared spectroscopy studies revealed the structuration of the ionic liquids along with alkyl chain elongation. SAXS experiments clearly demonstrated the existence of polar/non-polar domains. The alkyl chain length influenced the expansion of the non-polar domains, leading to the expansion between cation heads in polar regions of the structured IL. ¹H NMR self-diffusion coefficients indicated that alkyl chain elongation generally caused the lowering of the self-diffusion coefficients. Moreover, we show that the diffusion of anions and cations of ILs is similar, even though they vary in their size.