PVP-assisted Sn-Ti microspheres for the efficient B–V oxidation of cyclohexanone

Journal of Porous Materials - New Sn-Ti microspheres were first successfully synthesized by a PVP-assisted sol-gel method in this paper, and their performance in the B–V oxidation of...     

Mn/Ti-Zr复合氧化物催化苯甲酸甲酯选择性加氢

以硝酸锆和钛酸四丁酯为原料,采用共沉淀法制备Ti-Zr-O氧化物载体,采用浸渍法制备了Mn/Ti-Zr催化剂;采用XRD、N2物理吸附、H2-TPR、NH3-TPD和TG-DTA对Mn/Ti-Zr催化剂进行了表征,并考察了催化剂组成、结构和反应条件对苯甲酸甲酯（MB）加氢性能的影响,以及催化剂的长周期稳定性、失活和再生行为。结果表明：TiO2含量和Mn负载量分别为12% 和8% （二者均以Ti-Zr-O氧化物的质量为基准,下同）时制备的Mn/Ti-Zr催化剂性能最优,该催化剂在θ = 390 ℃, p = 1.0 MPa,n(H2)∶n(MB) = 9∶1和重时空速（WHSV）= 0.5 h-1的优化条件能够实现98.0% 的苯甲酸甲酯转化率和89.7%的苯甲醛和苯甲醇选择性;苯甲酸甲酯加氢反应的活性和选择性分别与Mn/Ti-Zr表面MnOx物种的氧化还原性和催化剂的酸性密切相关。此外,Mn/Ti-Zr催化剂具有良好的结构稳定性,在反应1000 h后仅因积碳而丧失11% 的活性,且轻微失活的催化剂可以通过焙烧恢复其初始活性和选择性。     

橡胶件在燃油中腐蚀溶胀性的对比

将丁腈、氢化丁腈、氟橡胶分别浸泡在乙醇、柴油、生物柴油中,测量每组样件的直径、质量和硬度值,计算其变化率,并采用扫描电镜对腐蚀溶胀后的橡胶件进行微观形貌结构分析。结合测量数据与扫描分析结果,分析材料间极性的差异对橡胶腐蚀溶胀的影响。结果表明,样件上述各参数变化率与微观形貌变化一致,氟橡胶在柴油中变化率最低,抗腐蚀溶胀效果最佳。     

Si-Al电子封装材料粉末冶金制备工艺研究

采用粉末冶金液相烧结工艺制备了Si-50％Al（质量分数)电子封装材料。研究了压制压力、烧结工艺对材料微观组织及性能的影响。结果发现：低温烧结时，随压制压力增大，材料密度呈上升趋势，而高温烧结时，材料密度较高且变化不大；增大压制压力不仅提高了材料的致密度，而且改善了界面接触方式，在一定范围内使得材料热导率提高，但压制压力过大时，则会导致Si粉出现大量的微裂纹等缺陷，界面热阻急剧上升，从而降低热导性能；适当提高烧结温度和延长烧结时间可以提高材料的热导率。     

Isotope Drift Characteristics in Ordovician Limestone Karst Water Caused by Coal Mining in Northern China

Mine Water and the Environment - Samples from different areas near the Fengfeng Mine in northern China were analyzed for 2H and 18O isotopes. In the southern areas, the 2H and 18O isotopes...     

A polyvinyl alcohol-based mixed matrix membrane with uniformly distributed Schiff base network-1 for ethanol dehydration

In this study, Schiff base network (SNW)-1 nanoparticles with high hydrophilicity and large specific surface area were used to prepare polyvinyl alcohol (PVA)-based mixed matrix membranes (MMMs), which were evaluated for ethanol dehydration. Because of the low difference of density between SNW-1 and PVA, the as-prepared nanoparticles can be uniformly distributed into the PVA active layer. The effects of SNW-1 loading, feed temperature, and water concentration on pervaporation (PV) performance were further studied. The results showed the MMM with 10 wt% of SNW-1 loading exhibited a separation factor of 1,501 and a permeation flux of 187 g m⁻² h⁻¹ for feeding 95 wt% ethanol/water binary solution at 75°C. Overall, the SNW-1/PVA MMMs showed great prospect in ethanol dehydration via PV.     

低温烘焙下城市生活垃圾与烟煤的混燃特性

为了探讨垃圾与煤的混燃特性,选取城市生活垃圾(MSW)和烟煤(BC)为研究对象,通过热重分析法研究烘焙温度、掺混比例、升温速率对样品燃烧特性的影响,并采用Kissinger-Akahira-Sunose(KAS)法计算样品的活化能.结果表明:MSW经220℃,260℃和300℃低温烘焙后,热值都有所提升,随着烘焙温度上...     

西南三线工业建筑遗产价值的保护与再利用研究

西南三线建设进程中出现了大量的旧工业建筑,不仅具有物质功能,也承载着历史和文化。分析攀枝花三线工业建筑遗产的价值,提出保护与再利用构想,并指出延续工业建筑遗产价值是西南三线工业城市文脉发展的思路。     

Experimental Study on Surface Deterioration of Hot RollingMill Rolls under Near Service Conditions

ＥｘｐｅｒｉｍｅｎｔａｌＳｔｕｄｙｏｎＳｕｒｆａｃｅＤｅｔｅｒｉｏｒａｔｉｏｎｏｆＨｏｔＲｏｌｌｉｎｇＭｉｌｌＲｏｌｌｓｕｎｄｅｒＮｅａｒＳｅｒｖｉｃｅＣｏｎｄｉｔｉｏｎｓＣｕｉＰｅｉｙｏｎｇＡｂｓｔｒａｃｔ：Ｗｉｔｈｓｐｅｃｉａｌｌｙｄｅｓｉｇｎｅ...     

气体流量现场校准装置不确定度评定

介绍了一种气体流量现场校准装置工作原理,针对装置的标准流量计系统和被动活塞气体流量校准系统的不确定度进行了评定,验证了装置设计方案的可行性。