全文获取类型
收费全文 | 2340篇 |
免费 | 171篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 29篇 |
综合类 | 5篇 |
化学工业 | 482篇 |
金属工艺 | 37篇 |
机械仪表 | 38篇 |
建筑科学 | 91篇 |
矿业工程 | 10篇 |
能源动力 | 49篇 |
轻工业 | 253篇 |
水利工程 | 16篇 |
石油天然气 | 3篇 |
无线电 | 274篇 |
一般工业技术 | 444篇 |
冶金工业 | 430篇 |
原子能技术 | 28篇 |
自动化技术 | 324篇 |
出版年
2023年 | 40篇 |
2022年 | 54篇 |
2021年 | 95篇 |
2020年 | 56篇 |
2019年 | 79篇 |
2018年 | 88篇 |
2017年 | 80篇 |
2016年 | 84篇 |
2015年 | 67篇 |
2014年 | 89篇 |
2013年 | 121篇 |
2012年 | 107篇 |
2011年 | 126篇 |
2010年 | 71篇 |
2009年 | 79篇 |
2008年 | 89篇 |
2007年 | 76篇 |
2006年 | 73篇 |
2005年 | 56篇 |
2004年 | 49篇 |
2003年 | 36篇 |
2002年 | 41篇 |
2001年 | 44篇 |
2000年 | 28篇 |
1999年 | 48篇 |
1998年 | 139篇 |
1997年 | 82篇 |
1996年 | 69篇 |
1995年 | 28篇 |
1994年 | 39篇 |
1993年 | 25篇 |
1992年 | 16篇 |
1991年 | 13篇 |
1990年 | 20篇 |
1989年 | 23篇 |
1988年 | 18篇 |
1987年 | 15篇 |
1986年 | 12篇 |
1985年 | 15篇 |
1984年 | 19篇 |
1983年 | 15篇 |
1982年 | 9篇 |
1980年 | 17篇 |
1978年 | 8篇 |
1977年 | 19篇 |
1976年 | 21篇 |
1975年 | 9篇 |
1974年 | 10篇 |
1972年 | 9篇 |
1969年 | 12篇 |
排序方式: 共有2513条查询结果,搜索用时 15 毫秒
1.
Liangtao Yang Liang-Yin Kuo Juan Miguel López del Amo Prasant Kumar Nayak Katherine A. Mazzio Sebastian Maletti Daria Mikhailova Lars Giebeler Payam Kaghazchi Teófilo Rojo Philipp Adelhelm 《Advanced functional materials》2021,31(38):2102939
A known strategy for improving the properties of layered oxide electrodes in sodium-ion batteries is the partial substitution of transition metals by Li. Herein, the role of Li as a defect and its impact on sodium storage in P2-Na0.67Mn0.6Ni0.2Li0.2O2 is discussed. In tandem with electrochemical studies, the electronic and atomic structure are studied using solid-state NMR, operando XRD, and density functional theory (DFT). For the as-synthesized material, Li is located in comparable amounts within the sodium and the transition metal oxide (TMO) layers. Desodiation leads to a redistribution of Li ions within the crystal lattice. During charging, Li ions from the Na layer first migrate to the TMO layer before reversing their course at low Na contents. There is little change in the lattice parameters during charging/discharging, indicating stabilization of the P2 structure. This leads to a solid-solution type storage mechanism (sloping voltage profile) and hence excellent cycle life with a capacity of 110 mAh g-1 after 100 cycles. In contrast, the Li-free compositions Na0.67Mn0.6Ni0.4O2 and Na0.67Mn0.8Ni0.2O2 show phase transitions and a stair-case voltage profile. The capacity is found to originate from mainly Ni3+/Ni4+ and O2-/O2-δ redox processes by DFT, although a small contribution from Mn4+/Mn5+ to the capacity cannot be excluded. 相似文献
2.
Dr. Adarshi P. Welegedara Dr. Ansis Maleckis Ruchira Bandara Dr. Mithun C. Mahawaththa Iresha Dilhani Herath Yi Jiun Tan Dr. Angeliki Giannoulis Prof. Daniella Goldfarb Prof. Gottfried Otting Prof. Thomas Huber 《Chembiochem : a European journal of chemical biology》2021,22(8):1480-1486
The selenol group of selenocysteine is much more nucleophilic than the thiol group of cysteine. Selenocysteine residues in proteins thus offer reactive points for rapid post-translational modification. Herein, we show that selenoproteins can be expressed in high yield and purity by cell-free protein synthesis by global substitution of cysteine by selenocysteine. Complete alkylation of solvent-exposed selenocysteine residues was achieved in 10 minutes with 4-chloromethylene dipicolinic acid (4Cl-MDPA) under conditions that left cysteine residues unchanged even after overnight incubation. GdIII−GdIII distances measured by double electron–electron resonance (DEER) experiments of maltose binding protein (MBP) containing two selenocysteine residues tagged with 4Cl-MDPA-GdIII were indistinguishable from GdIII−GdIII distances measured of MBP containing cysteine reacted with 4Br-MDPA tags. 相似文献
3.
Dr. Raysa Khan Tareque Dr. Storm Hassell-Hart Dr. Tobias Krojer Dr. Anthony Bradley Dr. Srikannathasan Velupillai Dr. Romain Talon Dr. Michael Fairhead Dr. Iain J. Day Kamlesh Bala Dr. Robert Felix Dr. Paul D. Kemmitt Prof. Paul Brennan Prof. Frank von Delft Dr. Laura Díaz Sáez Prof. Kilian Huber Prof. John Spencer 《ChemMedChem》2020,15(24):2513-2520
Combined photochemical arylation, “nuisance effect” (SNAr) reaction sequences have been employed in the design of small arrays for immediate deployment in medium-throughput X-ray protein–ligand structure determination. Reactions were deliberately allowed to run “out of control” in terms of selectivity; for example the ortho-arylation of 2-phenylpyridine gave five products resulting from mono- and bisarylations combined with SNAr processes. As a result, a number of crystallographic hits against NUDT7, a key peroxisomal CoA ester hydrolase, have been identified. 相似文献
4.
Forschung im Ingenieurwesen - Lkw-Überholmanöver auf Autobahnen können Konfliktsituationen provozieren. Das lange Blockieren der Überholspur und plötzliche Ausscheren kann... 相似文献
5.
Jasmin Kuhn Philipp M. Klein Nader Al Danaf Joel Z. Nordin Sren Reinhard Dominik M. Loy Miriam Hhn Samir El Andaloussi Don C. Lamb Ernst Wagner Yoshitsugu Aoki Taavi Lehto Ulrich Lchelt 《Advanced functional materials》2019,29(48)
Phosphorodiamidate morpholino oligomers (PMOs) are oligonucleotide analogs that can be used for therapeutic modulation of pre‐mRNA splicing. Similar to other classes of nucleic acid‐based therapeutics, PMOs require delivery systems for efficient transport to the intracellular target sites. Here, artificial peptides based on the oligo(ethylenamino) acid succinyl‐tetraethylenpentamine (Stp), hydrophobic modifications, and an azide group are presented, which are used for strain‐promoted azide‐alkyne cycloaddition conjugation with splice‐switching PMOs. By systematically varying the lead structure and formulation, it is determined that the type of contained fatty acid and supramolecular assembly have a critical impact on the delivery efficacy. A compound containing linolenic acid with three cis double bonds exhibits the highest splice‐switching activity and significantly increases functional protein expression in pLuc/705 reporter cells in vitro and after local administration in vivo. Structural and mechanistic studies reveal that the lipopeptide PMO conjugates form nanoparticles, which accelerate cellular uptake and that the content of unsaturated fatty acids enhances endosomal escape. In an in vitro Duchenne muscular dystrophy exon skipping model using H2K‐mdx52 dystrophic skeletal myotubes, the highly potent PMO conjugates mediate significant splice‐switching at very low nanomolar concentrations. The presented aminoethylene‐lipopeptides are thus a promising platform for the generation of PMO‐therapeutics with a favorable activity/toxicity profile. 相似文献
6.
Hal Philipp 《今日电子》2006,(9):60-61
好像在突然之间,电容式传感器就无处不在了。它被安装在汽车座位里以控制气囊配置和安全带预紧装置,在洗碗机和干燥机中以校正旋转桶的状态,甚至冰箱也使用其来控制自动去冰过程。但是直到现在,它最大的潜在应用领域还是触摸开关,触摸开关已越来越多地出现在消费电子产品中。 相似文献
7.
8.
9.
10.
Continuous simulation is performed using the US Environmental Protection Agency (USEPA) Storm Water Management Model (SWMM) to evaluate regional differences around the United States in hydrologic and water quality performance of wet-weather controls. Controls are characterised as being limited by peak inflow rate (i.e. any device with little or no storage, such as screens, filters and some proprietary devices) or by storage capacity (e.g., ponds, tanks). For flow-limited devices, results are presented in the form of percentage of annual runoff volume captured (passing through the device) for a given inflow capacity. For storage-limited devices, results are presented in two forms: percentage of annual runoff volume captured as a function of unit basin size and drawdown (drain) time, and as a percentage of total suspended solids captured, for the same two variables. Regional differences are apparent, driven mainly by variations in rainfall patterns around the country. 相似文献