Reichweite und Umfang der Belehrungspflicht des Treuhänders nach der BTVG-Novelle 2008

Die BTVG-Novelle 2008 führte auch zu Anpassungen bei den dem Treuh?nder gegenüber dem Erwerber bestehenden Belehrungspflichten. Der folgende Beitrag besch?ftigt sich mit dem Inhalt dieser Pflichten und geht der Frage nach, ob die Novelle zu einer Erweiterung der Treuh?nderpflichten geführt hat und welche Rechtsfolgen mit der Verletzung dieser Pflichten gegenüber dem Erwerber verbunden sind.     

Photo-vulcanization using thiol-ene chemistry: Film formation,morphology and network characteristics of UV crosslinked rubber latices

The photo-vulcanization with versatile thiol-ene chemistry represents an innovative approach to crosslink diene-rubber materials both in latex and in solid film state. In this work, the structure of elastomer-based thiol-ene networks and the morphology after film formation are studied in detail using electron microscopic techniques, atomic force microscopy and multiple-quantum solid-state NMR spectroscopy. Additionally, film formation properties and corresponding macroscopic properties of photo-vulcanized natural rubber (NR) latex and its synthetic counterpart, isoprene rubber (IR) latex, are determined in dependence on the curing procedure (pre- and post-vulcanization). The results reveal that thiol-ene cured elastomers comprise homogenously distributed crosslinks with a low amount of short chain defects. Whilst photochemically pre-cured NR latex particles provide coherent films, the film formation and mechanical properties of IR are strongly governed by the crosslink density of the latex particles. In film state, photo-vulcanization promotes narrow crosslink distributions and excellent tensile properties of both NR and IR.     

A simulation model for settling tanks with varying cross-sectional area

A quasi-one-dimensional model of the process of continuous sedimentation in clarifier-thickeners (settlers) with variable cross-sectional area is presented. The partial differential equation (PDE) model extends the settler model advanced by Bürger et al. (2013 Bürger, R., Diehl, S., Farås, S., Nopens, I., and Torfs, E. (2013). A consistent modelling methodology for secondary settling tanks: A reliable numerical method, Water Sci. Technol. 68(1), 192–208.[Crossref], [PubMed], [Web of Science ®] , [Google Scholar]), which assumes a constant cross section. A reliable numerical method that handles the special features of the nonlinear PDE is presented along with an advantageous time-step condition for continuous and batch sedimentation under the condition of a variable cross-sectional area. Simulations of continuous sedimentation show the effect of change of cross-sectional area in the concentration inside the vessel and in the underflow. Simulations of batch settling in cones illustrate the versatility of the numerical scheme to include a vertex, where the area shrinks to zero.     

Amino Acid Transporter LAT1 (SLC7A5) Mediates MeHg-Induced Oxidative Stress Defense in the Human Placental Cell Line HTR-8/SVneo

The placental barrier can protect the fetus from contact with harmful substances. The potent neurotoxin methylmercury (MeHg), however, is very efficiently transported across the placenta. Our previous data suggested that L-type amino acid transporter (LAT)1 is involved in placental MeHg uptake, accepting MeHg-L-cysteine conjugates as substrate due to structural similarity to methionine. The aim of the present study was to investigate the antioxidant defense of placental cells to MeHg exposure and the role of LAT1 in this response. When trophoblast-derived HTR-8/SVneo cells were LAT1 depleted by siRNA-mediated knockdown, they accumulated less MeHg. However, they were more susceptible to MeHg-induced toxicity. This was evidenced in decreased cell viability at a usually noncytotoxic concentration of 0.03 µM MeHg (~6 µg/L). Treatment with ≥0.3 µM MeHg increased cytotoxicity, apoptosis rate, and oxidative stress of HTR-8/SVneo cells. These effects were enhanced under LAT1 knockdown. Reduced cell number was seen when MeHg-exposed cells were cultured in medium low in cysteine, a constituent of the tripeptide glutathione (GSH). Because LAT1-deficient HTR-8/SVneo cells have lower GSH levels than control cells (independent of MeHg treatment), we conclude that LAT1 is essential for de novo synthesis of GSH, required to counteract oxidative stress. Genetic predisposition to decreased LAT1 function combined with MeHg exposure could increase the risk of placental damage.     

LED-Informationstafeln mit hoher Leuchtstärke

Firmen&;ProdukteModeller-Systeml?sung

Sichere Energieversorgung in der Fertigungsindustrie     

Simultaneous Detection of Positive and Negative Ions From Single Airborne Particles by Real-time Laser Mass Spectrometry

ABSTRACT

The instrumental setup used for simultaneous bipolar ion detection in on-line single-particle analysis by laser mass spectrometry is described. Particle size calibration has been performed using aerodynamic time-of-flight techniques. Mass spectra of several hundred ambient particles with aerodynamic diameters of 0.8 μm have been evaluated for statistical classification (Principal Components Analysis [PCA]) in order to identify main chemical components of the prominent particle classes.     

Formation of internal cracks in steel billets during soft reduction

To investigate the formation of internal cracks in steel billets during soft reduction, fully coupled thermo-mechanical finite element models were developed using the commercial software ABAQUS, also casting and soft reduction tests were carried out in a laboratory strand casting machine. With the finite element models, the temperature distribution, the stress and strain states in the bil-let were calculated. The relation between internal cracks and equivalent plastic strain, as well as maximal principal stress was ana-lyzed. The results indicate that tensile stresses can develop in the mushy zone during soft reduction and the equivalent strain nearby the zero ductility temperature (ZDT) increases with decreasing solid fraction. Internal cracks can be initiated when the accumulated strain exceeds the critical strain or the applied tensile stress exceeds the critical fracture stress during solidification.     

A consistent modelling methodology for secondary settling tanks in wastewater treatment

The aim of this contribution is partly to build consensus on a consistent modelling methodology (CMM) of complex real processes in wastewater treatment by combining classical concepts with results from applied mathematics, and partly to apply it to the clarification-thickening process in the secondary settling tank. In the CMM, the real process should be approximated by a mathematical model (process model; ordinary or partial differential equation (ODE or PDE)), which in turn is approximated by a simulation model (numerical method) implemented on a computer. These steps have often not been carried out in a correct way. The secondary settling tank was chosen as a case since this is one of the most complex processes in a wastewater treatment plant and simulation models developed decades ago have no guarantee of satisfying fundamental mathematical and physical properties. Nevertheless, such methods are still used in commercial tools to date. This particularly becomes of interest as the state-of-the-art practice is moving towards plant-wide modelling. Then all submodels interact and errors propagate through the model and severely hamper any calibration effort and, hence, the predictive purpose of the model. The CMM is described by applying it first to a simple conversion process in the biological reactor yielding an ODE solver, and then to the solid-liquid separation in the secondary settling tank, yielding a PDE solver. Time has come to incorporate established mathematical techniques into environmental engineering, and wastewater treatment modelling in particular, and to use proven reliable and consistent simulation models.