Effect of 100 KeV Ar+ ion beam irradiation on ZnO thin films – Influence of morphology vis-a-vis electrode/electrolyte interface and its impact on photoelectrochemical water splitting

The present study attempts quantitative determination of changes in the morphological surface features viz. fractal dimension, lower and upper cut off length scale through Power Spectral Density analysis prior to and after irradiation of 100 KeV Ar⁺ ion beam at incidence angles of 0°, 40° and 60° on ZnO thin films. All the unirradiated and irradiated samples are subjected to photoelectrochemical characterization and a correlation between photoelectrochemical performance and morphological parameters is established. Sample irradiated at 40° angle at the fluence of 5 × 10¹⁶ ions/cm² is found to possess maximum fractal dimension of 2.72, lower and upper cut off length scale of 3.16 nm and 63.00 nm respectively. This sample exhibits maximum photocurrent density of 3.19 mA/cm² and applied bias photon-to-current efficiency of 1.12% at 1.23 V/RHE. Hydrogen gas collected for duration of 1 h for the same sample was ~4.83 mLcm^?2.     

Investigation on sulphonated zinc oxide nanorod incorporated sulphonated poly (1,4-phenylene ether ether sulfone) nanocomposite membranes for improved performance of microbial fuel cell

Hydrothermally prepared zinc oxide nanorods are sulphonated (S–ZnO NR) and incorporated into 15% Sulphonated Poly (1,4-Phenylene Ether Ether Sulfone) (SPEES) to improve the hydrophilicity, water uptake and ion transfer capacity. Water uptake and ion transfer capacity increased to 34.6 ± 0.6% and 2.0 ± 0.05 meq g^?1 from 29.8 ± 0.3% and 1.4 ± 0.04 meq g^?1 by adding 7.5 wt% S–ZnO NR to SPEES. Morphological studies show the prepared S–ZnO NR is well dispersed in the polymer matrix. SPEES +7.5 wt% S–ZnO NR membrane exhibits optimum performance after three-weeks of continual operation in a fabricated microbial fuel cell (MFC) to produce a maximum power density of 142 ± 1.2 mW m^?2 with a reduced biofilm compared to plain SPEES (59 ± 0.8 mW m^?2), unsulphonated filler incorporated SPEES (SPEES + 7.5 wt% ZnO, 68 ± 1.1 mW m^?2) and Nafion (130 ± 1.5 mW m^?2) thereby suggesting its suitability as a sustainable and improved cation exchange membrane (CEM) for MFCs.     

Deep autoencoders for feature learning with embeddings for recommendations: a novel recommender system solution

Neural Computing and Applications - We propose “Deep Autoencoders for Feature Learning in Recommender Systems,” a novel discriminative model based on the incorporation of features from...     

Face verification across age progression.

Human faces undergo considerable amounts of varialions with aging. While face recognition systems have been proven to be sensitive to factors such as illumination and pose, their sensitivity to facial aging effects is yet to be studied. How does age progression affect the similarity between a pair of face images of an individual? What is the confidence associated with establishing the identity between a pair of age separated face images? In this paper, we develop a Bayesian age difference classifier that classifies face images of individuals based on age differences and performs face verification across age progression. Further, we study the similarity of faces across age progression. Since age separated face images invariably differ in illumination and pose, we propose preprocessing methods for minimizing such variations. Experimental results using a database comprising of pairs of face images that were retrieved from the passports of 465 individuals are presented. The verification system for faces separated by as many as nine years, attains an equal error rate of 8.5%.     

An integrated approach to the optimum utilization of national tungsten resources: Technology gaps

A critical review of the current status of tungsten resources, of state-of-the-art processing technology and of product development in India vis-a-vis the world scenario is presented. An attempt has been made to identify technology gap areas requiring attention.     

Failure analysis of a hot extrusion die used for Al-Li alloy processing

Al-Li alloys being developed as lighter, substitutes for conventional high strength Al alloys are to be processed by routine methods. During extrusion of a 8090 Al-Li alloy, the extrusion die container failed causing some alarm. This failed die container was analysed to examine if the failure was caused by interaction of Li diffusing out of Al-Li alloy with the carbides of die steel. The evidence, although not conclusive, is sufficient to exercise caution during such processing.     

Impact of power-supply noise on timing in high-frequency microprocessors

This paper analyzes the impact of power-supply noise on the performance of high-frequency microprocessors. First, delay models that take this noise into account are proposed for device-dominated and interconnect-dominated timing paths. For typical circuits, it is shown that the peak of the noise is largely irrelevant and that the average supply voltage during switching is more important. It is then argued that global differential noise can potentially have a greater timing impact than common-mode noise. Finally, realistic values for the model parameters are measured on a 2.53-GHz Pentium4 microprocessor using a 130-nm technology. These values imply that the power-supply noise present on the system board reduces clock frequency by 6.7%. The model suggests that the frequency penalty associated with this power-supply noise will steadily increase and reach 7.6% for the 90-nm technology generation.     

Mixed convection boundary layer flow of a micropolar fluid along vertical cylinders and needles

An analysis is presented to investigate the effects of buoyancy and curvature on convection along vertical cylinders and needles placed in a micropolar fluid. The governing equations for momentum, angular momentum and energy are solved numerically by finite difference scheme. The heat transfer results are presented for a range of values of the buoyancy parameters, the curvature parameter and the material parameters of the fluid. The effect of the microrotation boundary conditions on heat transfer is discussed.     

Bayesian algorithms for simultaneous structure from motion estimation of multiple independently moving objects.

In this paper, the problem of simultaneous structure from motion estimation for multiple independently moving objects from a monocular image sequence is addressed. Two Bayesian algorithms are presented for solving this problem using the sequential importance sampling (SIS) technique. The empirical posterior distribution of object motion and feature separation parameters is approximated by weighted samples. The first algorithm addresses the problem when only two moving objects are present. A singular value decomposition (SVD)-based sample clustering algorithm is shown to be capable of separating samples related to different objects. A pair of SIS procedures is used to track the posterior distribution of the motion parameters. In the second algorithm, a balancing step is added into the SIS procedure to preserve samples of low weights so that all objects have enough samples to propagate empirical motion distributions. By using the proposed algorithms, the relative motions of all the moving objects with respect to the camera can be simultaneously estimated. Both algorithms have been tested on synthetic and real-image sequences. Improved results have been achieved.