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排序方式: 共有292条查询结果,搜索用时 15 毫秒
1.
Maheshwari Rashmi Kumar Naveen Shadi Monal Tiwari Shailesh 《The Journal of supercomputing》2021,77(8):8653-8673
The Journal of Supercomputing - Data availability ensures efficient data accessibility by the readers anytime and from anywhere. It can be addressed by creating multiple copies of each data file... 相似文献
2.
Iodine-loaded poly(silicic acid) gellan nanocomposite film was fabricated and evaluated for antibacterial properties. Poly(silicic acid) nanoparticles were synthesized by condensation of silicic acid under alkaline conditions in the presence of polyvinyl pyrrolidone, phosphate ions, and molecular iodine. The nanoparticles were incorporated into gellan dispersion to prepare gellan nanocomposite film using the solvent casting method. The nanocomposite films were characterized by Fourier transformed infrared spectroscopy, thermogravimetric analysis, and X-ray diffraction studies. The results of characterization studies indicated improved thermal stability and an increase in the degree of crystallinity. The scanning electron micrographs and energy dispersive X-ray spectrum confirmed the uniform dispersion of silica and iodine in the nanocomposite films. The analysis of physical and mechanical properties revealed the enhanced tensile strength, moisture resistance, and higher folding endurance of poly(silicic acid) gellan nanocomposite films as compared to gellan film. Further, the iodine-loaded poly(silicic acid) gellan nanocomposite films showed good antibacterial activity against Staphylococcus aureus and Escherichia coli and effective mucoadhesive strength. The results indicate that iodine-loaded poly(silicic acid) gellan nanocomposite mucoadhesive film can be used for potential antibacterial applications in pharmaceuticals. 相似文献
3.
Coating gold nanorods (GNRs) with polyelectrolytes is an effective approach to make them biocompatible for potential use in photothermal treatment (PTT) of cancer. The authors report the effect of coating of the GNRs with polystyrene sulphonate (PSS‐GNRs) and PSS plus poly di‐allyl di‐methyl ammonium chloride (PDDAC‐GNRs) on its photothermal conversion efficiency (PTE), cellular uptake and subsequently the photothermal induced cytotoxicity in human oral cancer cells (NT8e). Coating of GNRs with PSS led to decrease in PTE by ∼30% and further coating it with PDDAC led to its increase to similar level, with respect to as‐ prepared GNRs. The cellular uptake of PDDAC‐GNRs in cancer cells was double than that for PSS‐GNRs. PTT of cancer cells after treatment with 60 pM of either PDDAC‐GNRs or PSS‐GNRs resulted in cytotoxicty of ∼90%. At higher concentration of 120 pM, while PSS‐GNRs showed no further change, for PDDAC‐GNR the photothermal induced cytotoxicity decreased to ∼50%. The broadening of longitudinal surface plasmon peak of PDDAC‐GNRs and appearance of dark clusters in cells under bright‐field microscope suggested intracellular clustering of PDDAC‐GNRs. In conclusion, despite high PTE and cellular uptake of PDDAC‐GNRs, its intracellular clustering (due to acidic pH) adversely affect the PTT of cancer cells.Inspec keywords: polymer electrolytes, gold, nanorods, cancer, nanomedicine, cellular biophysics, toxicology, radiation therapy, polymer filmsOther keywords: polyelectrolyte coating, photothermal efficiency, gold nanorods, photothermal induced cancer cell damage, cancer photothermal treatment, polystyrene sulphonate, poly di‐allyl di‐methyl ammonium chloride, photothermal conversion efficiency, cellular uptake, photothermal‐induced cytotoxicity, human oral cancer cells, dark clusters, bright‐field microscope, PDDAC‐GNR intracellular clustering, acidic pH, intracellular compartment, Au 相似文献
4.
Rashmi Mahajan Akhshay Singh Bhadwal Nishant Kumar Mukil Madhusudanan Ramesh Namdeo Pudake Ravi Mani Tripathi 《IET nanobiotechnology / IET》2017,11(4):360
The present study reports a novel, facile, biosynthesis route for the synthesis of carbon nanodots (CDs) with an approximate quantum yield of 38.5%, using Musk melon extract as a naturally derived‐precursor material. The synthesis of CDs was established by using ultraviolet–visible (UV–vis) spectroscopy, Dynamic light scattering, photoluminescence spectroscopy, X‐ray diffraction, transmission electron microscopy and Fourier transform infrared (FTIR) spectroscopy. The as‐prepared CDs possess an eminent fluorescence under UV–light (λ ex = 365 nm). The size range of CDs was found to be in the range of 5–10 nm. The authors further explored the use of such biosynthesised CDs as a photocatalyst material for removal of industrial dye. Degradation of methylene blue dye was performed in a photocatalytic reactor and monitored using UV–vis spectroscopy. The CDs show excellent dye degradation capability of 37.08% in 60 min and reaction rate of 0.0032 min−1. This study shows that synthesised CDs are highly stable in nature, and possess potential application in wastewater treatment.Inspec keywords: carbon, nanostructured materials, nanofabrication, catalysis, photochemistry, ultraviolet spectra, visible spectra, photoluminescence, X‐ray diffraction, transmission electron microscopy, Fourier transform infrared spectra, fluorescence, dyesOther keywords: green synthesis, highly stable CD, photocatalytic performance, biosynthesis route, carbon nanodots, quantum yield, Musk melon extract, naturally derived‐precursor material, ultraviolet‐visible spectroscopy, dynamic light scattering, photoluminescence spectroscopy, X‐ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, FTIR spectroscopy, fluorescence, biosynthesised CD, photocatalyst material, industrial dye, methylene blue dye degradation, photocatalytic reactor, UV‐vis spectroscopy, wastewater treatment, size 5 nm to 10 nm, time 60 min 相似文献
5.
Bhim Bali Prasad Deepak Kumar Rashmi Madhuri Mahavir Prasad TiwariAuthor vitae 《Sensors and actuators. B, Chemical》2011,160(1):418
A new kind of molecularly imprinted polymer-modified graphite electrode was fabricated by “grafting-to” approach, incorporating sol–gel technique, for the detection of acute deficiency in serum ascorbic acid level (SAAL), manifesting hypovitaminosis C. The modified electrode exhibited ascorbic acid (AA) oxidation at less positive potential (0.0 V) than the earlier reported methods, resulting in a limit of detection as low as 6.13 ng mL−1 (RSD = 1.2%, S/N = 3). The diffusion coefficient (1.096 × 10−5 cm2 s−1), rate constant (7.308 s−1), and Gibb's free energy change (−12.59 kJ mol−1) due to analyte adsorption, were also calculated to explore the kinetics of AA oxidation. The proposed sensor was found to enhance sensitivity substantially so as to detect ultra trace level of AA in the presence of other biologically important compounds (dopamine, uric acid, etc.), without any cross interference and matrix complications from biological fluids and pharmaceutical samples. 相似文献
6.
Impurities in industrial synthetic diamond powder samples were analyzed by X-ray diffraction (XRD) and Flame Atomic Absorption Spectrometry (FAAS). Specimen for FAAS is required in solution form. Diamonds are chemically inert to most acids and alkalies. Carbon was removed as CO2 on heating and estimated gravimetrically. The remaining residue was fused with di-lithium tetraborate and dissolved in nitric acid. Impurities such as Si, Al, Fe, Ca, Mg, W, Na, Co and Ni were then determined by FAAS. Crystalline phases of major impurities were identified by XRD. 相似文献
7.
Ranjan Prakash Mahto Santosh Kumar Choubey Arvind Sinha Rashmi Peraza-Vázquez Hernán Barde Chetan Peña-Delgado Adrián Roy Komal 《Microsystem Technologies》2022,28(11):2467-2485
Microsystem Technologies - In this paper synthesis of two wideband Metamaterial Cross Polarizer (MCPs) is proposed. The synthesis of proposed MCPs is done by using Binary Wind Driven Optimization... 相似文献
8.
The copper(II)‐catalyzed decarboxylative coupling reactions of arylglyoxylic acids with isatins afford 4H‐benzo[d][1,3]oxazin‐4‐ones via decarbonylation and concurrent C–N, C–O bond formation.
9.
10.
Prashant Singh Pradeep Kumar Anju Katyal Rashmi Kalra Sujata K. Dass Satya Prakash Ramesh Chandra 《Catalysis Letters》2010,134(3-4):303-308
In this present work, we report that phosphotungstic acid provides a simple, efficient and environmentally benign route is a two-component one-pot domino Knoevenagel-type condensation/Michael reaction between 4-coumarin derivative and an aldehyde in water as a solvent in shorter duration with high yields. 相似文献