Thermally stimulated shrinkage forces in oriented polymers: 1. Temperature dependence

Temperature dependences of shrinkage forces appearing in oriented polymer samples when heated at constant length were recorded for polycarbonate, polyethylene terephthalate, polyethylene and polypropylene. The influence of various processing conditions on thermally stimulated shrinkage forces is demonstrated. A four-state model is proposed which qualitatively describes the temperature dependences of shrinkage forces in amorphous polymers.     

Silicon‐containing heterocyclic polymers and thin films made therefrom

Thin films, in the range of tens of micrometers thickness, have been prepared by casting onto glass plates the chloroform or N‐methylpyrrolidone solutions of polyimides or poly(imide‐amide)s containing silicon and phenylquinoxaline units in the main chain. The polymers have been synthesized by solution polycondensation reaction of aromatic diamines having preformed phenylquinoxaline rings with bis(3,4‐dicarboxyphenyl)dimethylsilane dianhydride or with a diacid chloride resulting from the reaction of this dianhydride with p‐aminobenzoic acid. The polymers were easily soluble in polar aprotic solvents and showed high thermal stability. The free‐standing films exhibited good mechanical properties with tensile strengths in the range of 48–86 MPa, tensile modulus in the range of 1.25–2.22 GPa and elongation at break in the range of 3–37%. Electrical insulating properties of some polymer films were evaluated on the basis of dielectric constant and dielectric loss and their variation with frequency and temperature. The values of the dielectric constant at 10 kHz were in the range of 2.94–3.08 for polyimides and 3.89–4.49 for poly(imide‐amide)s. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 3062–3068, 2006     

Synthesis and characterization of poly(urethane‐ester)s based on calcium salt of mono(hydroxybutyl)phthalate

Calcium‐containing poly(urethane‐ester)s (PUEs) were prepared by reacting diisocyanate (HMDI or TDI) with a mixture of calcium salt of mono(hydroxybutyl)phthalate [Ca(HBP)₂] and hydroxyl‐terminated poly(1,4‐butylene glutarate) [HTPBG₁₀₀₀], using di‐n‐butyltin‐dilaurate as catalyst. About six calcium‐containing PUEs having different composition were synthesized by taking the mole ratio of Ca(HBP)₂:HTPBG₁₀₀₀:diisocyanate (HMDI or TDI) as 3:1:4, 2:2:4, and 1:3:4. Two blank PUEs were synthesized by the reaction of HTPBG₁₀₀₀ with diisocyanate (HMDI or TDI). The polymers were characterized by IR, ¹H NMR, Solid state ¹³C‐CP‐MAS NMR, TGA, DSC, XRD, solubility, and viscosity studies. The T_g value of PUEs increases with increase in the calcium content and decreases with increase in soft segment content. The viscosity of the calcium‐containing PUEs increases with increase in the soft segment content and decreases with increase in the calcium content. X‐ray diffraction patterns of the polymers show that the HMDI‐based polymers are partially crystalline and TDI‐based polymers are amorphous in nature. The dynamic mechanical analysis of the calcium‐containing PUEs based on HMDI shows that with increase in the calcium content of polymer, modulus (g′ and g″) increases at any given temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1720–1727, 2006     

Action diversity in a simulation of the Israeli-Palestinian conflict

This article explores the strategies used by Israeli students to resolve the Israeli-Palestinian conflict in the interactive computer game, PeaceMaker. Students played PeaceMaker in the roles of both the Israeli Prime Minister and the Palestinian President in random order. Students must take actions satisfying constituents on both sides of the conflict in order to win the game. The diversity of actions taken in each role was measured. Several hypotheses test the degree to which Israeli students, depending on which role they played and their own demographic variables, exploited a consistent set of actions or explored a more diverse range of actions across three main types: construction, political, and security. The results show that (1) greater action diversity increases success in both roles, (2) Israeli students engaged in less diverse actions when playing the Israeli role than when playing the Palestinian role, (3) students’ religiosity and political Hawkishness negatively predicted action diversity when playing the Palestinian role, and (4) action diversity mediates the relationship between a student’s background knowledge about the conflict and success in the Israeli role. The significance of these findings for understanding attitudes about the Israeli-Palestinian conflict are discussed, including implications for conflict resolution more generally.     

Cognitive-Behavioral and Humanistic Group Treatment for Children With Learning Disabilities: A Comparison of Outcomes and Process.

The authors of this study examined the outcomes and processes of 2 types of group treatment--cognitive-behavioral treatment groups (CBTG) and humanistic group therapy (HGT)--offered to 200 elementary schoolchildren in a center for students with learning disabilities in Israel. Results indicated that the addition of either type of group treatment to individual academic assistance was more effective than the latter alone on most measures. In fact, on the majority of measures, group treatment without academic assistance was more effective than just individual assistance. Finally, HGT was more effective than CBTG on most measures. Most of the outcomes were sustained at follow-up, and some even increased from termination to follow-up, although effect sizes were quite low. Process measures included the Client Behavior System and the therapist Helping Skills System, which were measured at 5 points in time. Differences between the 2 treatment types were revealed on both process measures, including differences in the growth curve of these behaviors. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Electrostatic Control of Structure in Self‐Assembled Membranes

Self‐assembling peptide amphiphiles (PAs) can form hierarchically ordered membranes when brought in contact with aqueous polyelectrolytes of the opposite charge by rapidly creating a diffusion barrier composed of filamentous nanostructures parallel to the plane of the incipient membrane. Following this event, osmotic forces and charge complexation template nanofiber growth perpendicular to the plane of the membrane in a dynamic self‐assembly process. In this work, we show that this hierarchical structure requires massive interfacial aggregation of PA molecules, suggesting the importance of rapid diffusion barrier formation. Strong PA aggregation is induced here through the use of heparin‐binding PAs with heparin and also with polyelectrolytes of varying charge density. Small angle X‐ray scattering shows that in the case of weak PA‐polyelectrolyte interaction, membranes formed display a cubic phase ordering on the nanoscale that likely results from clusters of PA nanostructures surrounded by polyelectrolyte chains.     

Nanoparticles of CdCl2 with closed cage structures

Nanoparticles of various layered compounds having a closed cage or nanotubular structure, designated also inorganic fullerene-like (IF) materials, have been reported in the past. In this work IF-CdCl₂ nanoparticles were synthesized by two methods. In one technique, a high temperature evaporation and subsequent condensation of dried cadmium chloride powder was used. In the other method, electron beam irradiation of the source powder led to its recrystallization into closed nanoparticles with a nonhollow core. The two methods are shown to produce nanoparticles of different topologies. While mostly spherical nested structures are obtained from the high temperature process, polyhedra with hexagonal or elongated rectangular characters are obtained by the electron beam induced process. The analysis also shows that, while the source (dried) powder is orthorhombic cadmium chloride monohydrate, the crystallized IF cage consists of the anhydrous 3R polytype which is not stable as bulk material in ambient atmosphere. Consistent with previous observations, this study shows that the seamless structure of the IF materials can stabilize phases, which are otherwise unstable in ambient conditions.     

Influence of clays on the rheology of cement pastes

The fresh state of concrete is becoming increasingly important in furthering the types of applications of today's construction world. Processing techniques have resulted in technologies such as self-consolidating concrete and depend on the microstructural changes that take place during and immediately after mixing and placing. These changes to the microstructure reflect the flocculation behavior between the particles in suspension. The ability to modify this behavior allows control over the balance among flowability and shape-stability of concrete. This study investigates how clay admixtures affect the microstructure of cement pastes from a rheological stand point. Shear and compressive rheology techniques are used to measure how the solids volume fraction of suspensions with different admixtures evolves with stress. Based on these relationships, the effectiveness of clays on the balance between flowability and shape-stability is measured. Results are consistent with green strength tests performed on concrete mixes derived from the cement paste mixes.     

Static and Dynamic Mechanical Behavior of Electron Beam‐Cured Monomer and Monomer/Liquid Crystal Systems

Summary: This paper discusses static and dynamic mechanical properties of electron beam‐cured mixtures made of the nematic liquid crystal (LC) E7 and either tripropyleneglycol diacrylate (TPGDA) or propoxylated glycerol triacrylate (GPTA) as monomers differing essentially by their functionality. Dilution of the initial mixture with LC leads to a significant weakening of the film mechanical strength. Strong effects were found on Young modulus and rubbery state modulus. As the concentration of LC increases, these mechanical parameters drop significantly together with the glass transition temperature of the polymer showing a plasticizing effect. The results for the glass transition temperatures for the polymer and the LC were confirmed by thermograms obtained by differential scanning calorimetry.

Storage tensile modulus versus temperature of EB‐cured TPGDA/E7 films for different LC concentrations.