Understanding the Corrosion Inhibition Mechanism of Mild Steel in Hydrochloric Acid by a Triazole Derivative: A Combined Experimental and Theoretical Approach

Protection of Metals and Physical Chemistry of Surfaces - The effect of an heterocycle triazole, namely (1-(4-methoxyphenyl)-1H-1,2,3-triazol-4-yl)methanol (MTM) on the corrosion of mild steel in...     

An Overview on the Performance of 1,2,3-Triazole Derivatives as Corrosion Inhibitors for Metal Surfaces

This review accounts for the most recent and significant research results from the literature on the design and synthesis of 1,2,3-triazole compounds and their usefulness as molecular well-defined corrosion inhibitors for steels, copper, iron, aluminum, and their alloys in several aggressive media. Of particular interest are the 1,4-disubstituted 1,2,3-triazole derivatives prepared in a regioselective manner under copper-catalyzed azide-alkyne cycloaddition (CuAAC) click reactions. They are easily and straightforwardly prepared compounds, non-toxic, environmentally friendly, and stable products to the hydrolysis under acidic conditions. Moreover, they have shown a good efficiency as corrosion inhibitors for metals and their alloys in different acidic media. The inhibition efficiencies (IEs) are evaluated from electrochemical impedance spectroscopy (EIS) parameters with different concentrations and environmental conditions. Mechanistic aspects of the 1,2,3-triazoles mediated corrosion inhibition in metals and metal alloy materials are also overviewed.     

Induction Motors Broken Rotor Bars Diagnosis Through the Discrete Wavelet Transform of the Instantaneous Reactive Power Signal under Time-varying Load Conditions

Abstract—In this article, a method based on the application of the discrete wavelet transform to the instantaneous reactive power signal, for diagnosing the occurrence of broken rotor bars in induction motors operating under time-varying load conditions, is presented. This method is based on the decomposition of the instantaneous reactive power signal, from which wavelet approximation and detail coefficients are extracted. The energy evaluation of known bandwidths permits to de?ne a fault severity factor. This method has been tested through the simulation of an induction motor using a mathematical model based on the winding-function approach. These simulation results are complemented by experimental tests conducted on an induction motor with several faulty rotors that can be interchanged and both simulation and experimental results have shown the effectiveness of the proposed method for broken rotor bars diagnosis in induction motors even under time-varying load conditions.     

Development and validation of a coupled heat and mass transfer model for green roofs

This paper describes a dynamic model of transient heat and mass transfer across a green roof component. The thermal behavior of the green roof layers is modeled and coupled to the water balance in the substrate that is determined accounting for evapotranspiration. The water balance variations over time directly impact the physical properties of the substrate and the evapotranspiration intensity. This thermal and hydric model incorporates wind speed effects within the foliage through a new calculation of the resistance to heat and mass transfer within the leaf canopy. The developed model is validated with experimental data from a one-tenth-scale green roof located at the University of La Rochelle. A comparison between the numerical and the experimental results demonstrates the accuracy of the model for predicting the substrate temperature and water content variations. The heat and mass transfer mechanisms through green roofs are analyzed and explained using the modeled energy balances, and parametric studies of green roof behavior are presented. A surface temperature difference of up to 25 °C was found among green roofs with a dry growing medium or a saturated growing medium. Furthermore, the thermal inertia effects, which are usually simplified or neglected, are taken into account and shown to affect the temperature and flux results. This study highlights the importance of a coupled evapotranspiration process model for the accurate assessment of the passive cooling effect of green roofs.     

A numerical study of three-dimensional laminar mixed convection past an open cavity

A numerical study has been carried out to analyze the effects of mixed convective flow over a three-dimensional cavity that lies at the bottom of a horizontal channel. The vertical walls of the cavity are isothermal and all other walls are adiabatic. The cavity is assumed to be cubic in geometry and the flow is laminar and incompressible. A direct numerical simulation is undertaken to investigate the flow structure, the heat transfer characteristics and the complex interaction between the induced stream flow at ambient temperature and the buoyancy-induced flow from the heated wall over a wide range of the Grashof number (10³–10⁶) and two Reynolds numbers Re = 100 and 1000. The computed thermal and flow fields are displayed and discussed in terms of the velocity fields, streamlines, the temperature distribution and the averaged Nusselt number at the heated and cooled walls. It is found that the flow becomes stable at moderate Grashof number and exhibit a three-dimensional structure, while for both high Reynolds and Grashof numbers the mixed convection effects come into play, push the recirculating zone further upstream and the flow becomes unsteady with Kelvin–Helmholtz instabilities at the shear layer.     

Anti-Corrosive Properties of (1-benzyl-1H-1,2,3-triazol-4-yl) Methanol on Mild Steel Corrosion in Hydrochloric Acid Solution: Experimental and Theoretical Evidences

Protection of Metals and Physical Chemistry of Surfaces - The corrosion inhibitory effect of (1-benzyl-1H-1,2,3-triazol-4-yl) methanol (BTM) for mild steel in 1 M HCl at (298–328 K) was...     

Analysis of the flow and heat transfer characteristics for assisting incompressible laminar flow past an open cavity

A numerical study has been carried out to analyze the effects of mixed convective assisting flow past three-dimensional open cavity over a wide range of Reynolds (100–1000) and Richardson (0.001–10) numbers. The vertical walls in the inflow and outflow sides are isothermal while all other walls are adiabatic. The cavity is assumed to be cubic in geometry and the flow is laminar. A direct numerical simulation is undertaken to investigate the flow structure, the heat transfer characteristics and the complex interaction between the induced stream flow at ambient temperature and the buoyancy-induced flow from the heated wall. It is found that the flow becomes stable at moderate Grashof number and exhibits a three-dimensional structure, while for high Richardson number the mixed convection effects come into play and push the recirculating zone further upstream and the flow may becomes unstable.     

Measurement-based admission control in UMTS

In this paper, we develop an efficient Call Admission Control (cac) algorithm forumts systems. We first introduce the expressions that we developed for Signal-to-Interference (sir) for both uplink and downlink, to obtain a novelcac algorithm that takes into account, in addition tosir constraints, the effects of mobility, coverage as well as the wired capacity behind the base station, for the uplink, and the maximal transmission power of the base station, for the downlink. As of its implementation, we investigate the measurement-based approach as a means to predict future, both handoff and new, call arrivals and thus manage different priority levels depending on a tunable coefficient. Compared to classicalcac algorithms, ourcac mechanism achieves better performance in terms of outage probability and QoS management.     

Fully Adaptive Multiscale Schemes for Conservation Laws Employing Locally Varying Time Stepping

In recent years the concept of fully adaptive multiscale finite volume schemes for conservation laws has been developed and analytically investigated. Here the grid adaptation is performed by means of a multiscale analysis. So far, all cells are evolved in time using the same time step size. In the present work this concept is extended incorporating locally varying time stepping. A general strategy is presented for explicit as well as implicit time discretization. The efficiency and the accuracy of the proposed concept is verified numerically.