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Marziyeh Hayati Ghasem Rezanejade Bardajee Majid Ramezani Samaneh Sadat Hosseini Farhang Mizani 《Polymer International》2020,69(2):156-164
Hydrogels, nanogels and nanocomposites show increasing potential for application in drug delivery systems due to their good chemical and physical properties. Therefore, we were encouraged to combine them to produce a new compound with unique properties for a long‐term drug release system. In this regard, the design and application of a nanocomposite hydrogel containing entrapped nanogel for drug delivery are demonstrated. To this aim, we first prepared an iron oxide nanocomposite nanogel based on poly(N‐isopropylacrylamide)‐co‐((2‐dimethylaminoethyl) methacrylate) (PNIPAM‐co‐PDMA) grafted onto sodium alginate (NaAlg) as a biocompatible polymer and iron oxide nanoparticles (ION) as nanometric base (PND/ION‐NG). This was then added into a solution of PDMA grafted onto NaAlg. Through dropwise addition of mixed aqueous solution of iron salts into the prepared polymeric solution, a novel hydrogel nanocomposite with excellent pH, thermal and magnetic responsivity was fabricated. The synthesized samples were fully characterized using Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy with energy‐dispersive X‐ray analysis, vibrating sample magnetometry and atomic force microscopy. A mechanism for the formation of PNIPAM‐co‐PDMA/NaAlg‐ION nanogel–PDMA/NaAlg‐ION hydrogel and PND/ION nanogel is suggested. Swelling capacity was measured at various temperatures (25 to 45 °C), pH values (from 2 to 11) and magnetic field and under load (0.3 psi) and the dependence of swelling properties of the nanogel–hydrogel nanocomposite on these factors was well demonstrated. The release rate of doxorubicin hydrochloride (DOX) as an anticancer drug was studied at different pH values and temperatures in the presence and absence of a magnetic field. The results showed that these factors have a high impact on drug release from this nanocomposite. The result showed that DOX release could be sustained for up to 12.5 days from these nanocomposite hydrogels, significantly longer than that achievable using the constituent hydrogel or nanogel alone (<1 day). The results indicated that the nanogel–hydrogel nanocomposite can serve as a novel nanocarrier for anticancer drug delivery. © 2019 Society of Chemical Industry 相似文献
3.
Electroinitiated cationic copolymerisation of indene and styrene was investigated by constant potential electrolysis. Effects of copolymerisation potential and temperature on the copolymer composition and the reactivity ratios are discussed. The reactivity ratios of the monomers were calculated according to the integrated Lewis-Mayo equation. 相似文献
4.
In this paper, the test results of liquid injection impact on the performance of new alternative refrigerant mixtures such as: R-410A, R-507, R-407C and R-404A are discussed, analysed and presented. The test results were obtained using an air-source heat pump set-up with enhanced surface tubing under various liquid injection ratios. Performance tests were conducted according to the ARI/ASHRAE standards. The performance data demonstrated that as liquid injection ratio increases, compressor head pressure and discharge temperature decrease. This has a positive effect in protecting the compressor. The effect of liquid injection on mixture behaviour varies from one mixture to another depending upon the mixture's composition. Furthermore, liquid injection appears to have a significant influence on R-410A behaviour compared to the other mixtures in question. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
5.
The p53 tumor suppressor gene encodes a phosphoprotein which when overexpressed can induce growth arrest at the G1 and G2/M phases of the cell cycle, promote differentiation and apoptosis. This paper demonstrates that p53 can associate with trk tyrosine kinase. Expression of a murine temperature-sensitive (ts) p53 mutant in PC12 cells overexpressing trk (a model system to analyse cellular differentiation and signal transduction induced by NGF) induces morphological changes in the absence of NGF stimulation at 32 degrees C but not at 37 degrees C. In cells differentiated by p53, trk, but not EGFr, was hyperphosphorylated on tyrosine. Furthermore trk was not phosphorylated when expressed in Saos-2 cells (human osteosarcoma cells that lack expression of both endogenous trk and p53) at either temperature. However, transfection of ts p53 into these cells induces trk phosphorylation at 32 degrees C in the absence of NGF stimulation. Association of trk and p53 can be detected in NIH3T3 and PC12 cells co-expressing trk and the ts p53 mutant, in NIH3T3 and PC12 cells transfected with trk alone, and in untransfected PC12 cells, showing that overexpressed and/or endogenous trk associates with endogenous, low levels of p53. These data suggest a novel function for p53 which involves the stimulation of signal transduction pathways (mediating morphological properties of cells), possibly through association with and hyperphosphorylation of trk. 相似文献
6.
A. Antola R. Negrini M. G. Sami N. Scarabottolo 《The Journal of VLSI Signal Processing》1992,4(4):295-316
Fault tolerance in VLSI/WSI FFT arrays acquires relevance when defects and run-time faults become significant, due to large dimensions of processors and arrays. Then, both restructuring to overcome end-of-production defects and reconfiguration to overcome run-time faults are required, to achieve the dual purposes of higher yield and higher reliability.Adopting as basic FFT network the two-dimensions array that directly corresponds to the FFT flow graph, the usual structure redundancy techniques tailored for two-dimensions arrays reconfiguration are not well applicable, since the limited locality of this network leads to relevant area increase due to the augmented interconnection structure.In this paper,time redundancy is suggested as a viable alternative for the two-dimensions FFT array; two different solutions are presented, one based oninter-stage reconfiguration, the other one adoptingintra-state reconfiguration, both allowing for survival to multiple faults with limited increase of network complexity and very small hard-core sections. As usual in many time redundancy methods, both approaches result in a processing speed equal to half the processing speed granted by an ideal, fault-free device.Reliability and survival ratios to multiple faults are evaluated for the two cases, taking into account also the area increments necessary for fault tolerance. The reliability evaluations allow for a direct comparison of the two solutions. 相似文献
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8.
Effect of electricity tariff on the optimum insulation-thickness in building walls as determined by a dynamic heat-transfer model 总被引:5,自引:0,他引:5
Thermal insulation is one of the most effective energy-conservation measures in buildings. Despite the widespread use of insulation materials in recent years, little is known regarding their optimum thickness under dynamic thermal conditions. Insulated concrete blocks are among the units most commonly used in the construction of building walls in Saudi Arabia. Typically, the insulation layer thickness is fixed at a value in the range 2.5–7.5 cm, regardless of the climatic conditions, type and cost of insulation material, and other economic parameters. In the present study, a numerical model based on a finite-volume, time-dependent implicit procedure, which has been previously validated, is used to compute the yearly cooling and heating transmission loads under steady periodic conditions through a typical building wall, for different insulation thicknesses. The transmission loads, calculated by using the climatic conditions of Riyadh for a west-facing wall, are fed into an economic model in order to determine the optimum thickness of insulation (Lopt). The latter corresponds to the minimum total cost, which includes the cost of insulation material and its installation plus the present value of energy consumption cost over the lifetime of the building. The optimum insulation thickness depends on the electricity tariff as well as the cost of insulation material, lifetime of the building, inflation and discount rates, and coefficient of performance of the air-conditioning equipment. In the present study, the effect of electricity tariff on the computed optimum insulation thickness is investigated. Different average electricity tariffs are considered; namely, 0.05, 0.1, 0.2, 0.3 and 0.4 SR/kWh (designated as Cases 1–5, respectively; 1 US$ = 3.75 Saudi Riyals). Results using moulded polystyrene as an insulating material show that the values of Lopt are: 4.8, 7.2, 10.9, 13.7 and 16.0 cm for Cases 1–5. Under the conditions of optimal insulation thickness for each electricity tariff, Case 1 gives the lowest total cost of 17.4 SR/m2, while Case 5 gives the highest total cost of 53.1 SR/m2. Corresponding thermal performance characteristics in terms of yearly total and peak transmission loads, R-value, time lag and decrement factor are presented. 相似文献
9.
Barimani Samaneh Amini Amir Chaharmahali Iman 《Journal of Computational Electronics》2021,20(3):1332-1342
Wave absorbers are considered to be fundamental building blocks for the manipulation of light. Almost all optical systems exploit absorbers to realize some functions. A highly tunable wide-band THz absorber is presented herein. Utilizing a dual-bias scheme with a single graphene layer leads to greater freedom to control the absorption response, while a conventional periodic array of graphene ribbons and a layer of graphene sheet are also exploited. Also, a circuit model representation for all the constituent parts of the proposed absorber is developed with an evolved design methodology. According to the simulation results, wide-band absorption from 3.5 to 6 THz is achieved.
相似文献10.
An automated optimization procedure based on successive response surface method is presented. The method is applied to weight optimization of a stiffened plate used in marine structures. In the design space the surrogate model is spanned sequentially into an optimally restricted subspace that is converging towards at least a local optimum. Both objective function and all constraint functions are modeled using linear response surface method enabling the use of a robust and efficient simplex algorithm for the optimizations. Special attention is paid to CAD and FEM-model linking that plays a central role in practical industrial applications. In this project SOLIDWORKS and ANSYS software are adopted for structural modeling and analysis, respectively, and the optimization is carried out in a MatLab environment. The reported results achieved in this project prove the robustness and effectiveness of the proposed approach. 相似文献