REACTOR-MEMBRANE PERMEATOR CASCADE FOR ENHANCED PRODUCTION AND RECOVERY OF H2 AND CO2 FROM THE CATALYTIC METHANE-STEAM REFORMING REACTION

The catalytic reforming of methane by steam is an important industrial process that produces H₂, CO and CO₂, thus chemically transforming natural gas, coal gas and light hydrocarbon feedstocks to synthesis gas or hydrogen fuel. Methane-steam reforming may consist of a number of reactions depending on the reforming catalyst, operating conditions and feedstock composition, The typical industrially desirable reactions are the reverse of methanation (CH₄ + H₂O = CO + 3H₂) and the water-gas shift (CO + H₂O = CO₂ + H₂). Both reactions are equilibrium limited and the composition of the mixture that exits the reformer is in accordance with the one calculated thermodynarmically. Removal of reaction products at the reactor exit by means of selective membrane permeation can offer improved CH₄ conversions and CO₂ and H₂ yields, assuming the subsequent utilization of the reject streams by a second methane-steam reformer. We numerically investigated the feasibility of a system of two tubular methane-steam reformers, in series with an intermediate permselective polyimide membrane permeator, as means of improving the overall CH₄ conversion and the H₂, CO₂ yields over conventional methane-steam reforming equilibrium reaction-separation schemes that are currently in industrial practice. The unique feature of the permselective polyimide separator is the simultaneous removal of H₂ and CO₂ versus CH₄ and CO from the reformed streams. The utilized 6FDA-3,3', 5,5'-TMB aromatic polyimide was reportedly characterized [10] and found to exhibit superior permselective properties compared with other polyimides of the same or different dianhydride sequence. Conversion and yield of the designed reactor-membrane permeator reforming system can be maximized by optimizing the permselective properties of the membrane material and the design variables of the reactors and the permeator. Product recovery and purity in the permeate stream need to be compromised to overall enhance methane conversion and product yield. The operating variables that were varied to investigate their effect on the magnitude of conversion and yield included the inlet pressure of the first reformer, the temperature of both reformers, and the permeator dimensionless Pe' number (variation of the first two variables results to a drastic change in the composition of the reformed stream that enters into the permeator). The numerical results show that the new reformer-membrane permeator cascade process can be more effective (it can offer increased CH₄ conversions and H₂, CO₂ yields) than conventional equilibrium methane-steam reforming reaction-separation processes currently in practice.     

A repairable queueing model with two-phase service,start-up times and retrial customers

A repairable queueing model with a two-phase service in succession, provided by a single server, is investigated. Customers arrive in a single ordinary queue and after the completion of the first phase service, either proceed to the second phase or join a retrial box from where they retry, after a random amount of time and independently of the other customers in orbit, to find a position for service in the second phase. Moreover, the server is subject to breakdowns and repairs in both phases, while a start-up time is needed in order to start serving a retrial customer. When the server, upon a service or a repair completion finds no customers waiting to be served, he departs for a single vacation of an arbitrarily distributed length. The arrival process is assumed to be Poisson and all service and repair times are arbitrarily distributed. For such a system the stability conditions and steady state analysis are investigated. Numerical results are finally obtained and used to investigate system performance.     

Adaptive Head-to-Tail: Active Queue Management based on implicit congestion signals

Active Queue Management is a convenient way to administer the network load without increasing the complexity of end-user protocols. Current AQM techniques work in two ways; the router either drops some of its packets with a given probability or creates different queues with corresponding priorities. Head-to-Tail introduces a novel AQM approach: the packet rearrange scheme. Instead of dropping, HtT rearranges packets, moving them from the head of the queue to its tail. The additional queuing delay triggers a sending rate decrease and congestion events can be avoided. The HtT scheme avoids explicit packet drops and extensive retransmission delays. In this work, we detail the HtT algorithm and demonstrate when and how it outperforms current AQM implementations. We also approach analytically its impact on packet delay and conduct extensive simulations. Our experiments show that HtT achieves better results than Droptail and RED methods in terms of retransmitted packets and Goodput.     

Online political marketing in Greece: An evaluation of the 2007 national elections and two case studies

This paper presents findings on the use of Web sites as a political marketing tool in the context of the 2007 Greek national elections. The questions guiding this research are how popular were online campaigns in terms of candidate use of Web sites and which trust and credibility-building Web site design cues were leveraged by candidates. This study also explored differences in online campaign practices both between Greek political parties and between the 2007 national Greek elections and the 2002 federal US elections.     

Accessibility-based reranking in multimedia search engines

Multimedia Tools and Applications - Traditional multimedia search engines retrieve results based mostly on the query submitted by the user, or using a log of previous searches to provide...     

Do websites influence the nature of voting intentions? The case of two national elections in Greece

This paper aims to contribute to the growing body of research on online political marketing by investigating the use of websites as a marketing tool in the 2007 and 2009 general elections in Greece. The two main research objectives are firstly to establish the key factors affecting voters’ trust when it comes to using politicians’ websites and secondly to examine whether and to what extent the influence of trust-building factors changes over-time, as the online environment matures. The key findings of this research are that users tend to visit the websites of favoured candidates, which reinforces their positive perceptions of them, while as far as the websites themselves and their content and the services provided are concerned there is still room for improvement.     

Cooperative schemes for path establishment in mobile ad-hoc networks under shadow-fading

The performance of routing protocols for multi-hop path-establishment in Mobile Ad-hoc NETworks (MANET) is examined when the individual radio links undergo shadow fading of parameterized severity. Such propagation modeling is typical of ground-level networking along with node mobility. The metrics of main interest are the probability of having a reliable multi-hop path plus the temporal statistics of such availability under a Markovian model. Such availability is an indicator for the suitability of the network to carry delay-sensitive applications (push-to-talk voice, streaming video) in uninterrupted manner. It is shown that high levels of diversity are necessary in such adverse environments, as obtained either by multiple independent paths or via concurrent cooperative transmission. Analytical and simulation comparisons of typical routing options are presented on the above metrics, plus on the required nodal engagement for supporting such diversity.