Production of hydrogen over bimetallic Pt–Ni/δ-Al2O3: I. Indirect partial oxidation of propane

Indirect partial oxidation (IPOX) of propane was studied over bimetallic 0.2 wt.% Pt–15 wt.% Ni/δ-Al₂O₃ catalyst in the 623–743 K temperature range. The unreduced and reduced forms of the catalyst were characterized by ESEM–EDAX and X-ray diffraction (XRD). In the IPOX tests, the effects of steam to carbon ratio (S/C), carbon to oxygen ratio (C/O₂) and residence time (W/F (g_cat h/mol HC)) on the hydrogen production activity, selectivity and product distribution were studied in detail. The effect of temperature program applied (increasing from 623 to 743 K, ITP; decreasing from 743 to 623 K, DTP) during reaction was also tested. The results showed that the Pt–Ni bimetallic system has superior performance characteristics compared to the monometallic catalysts reported in literature. The reason is thought to be the utilization of the catalyst particles as micro heat exchangers during IPOX; the heat generated by Pt sites during exothermic total oxidation (TOX) being readily transferred through the catalyst particles acting as micro heat exchangers to the Ni sites, which promote endothermic steam reforming (SR). The optimal conditions were found as S/C = 3, C/O₂ = 2.70 and W/F = 0.51 g_cat h/mol HC for IPOX of propane on the basis of high hydrogen productivity and selectivity between 623 and 748 K for the experimental conditions tested. The thermo-neutral points obtained showed the sustainability of reaction in terms of energy.     

An experimental test of a theory of lightning-induced voltages onan overhead wire

Measured and calculated voltages induced on an unenergized overhead power line by lightning return strokes at distances greater than 5 km from the line are presented. The experiment was performed at the NASA Kennedy Space Center during the summer of 1985 and involved the simultaneous measurement of the voltage induced at one end of the top phase of a three-phase power line and the two horizontal components of the return-stroke magnetic field incident on the line. The effective ground conductivity was determined from previous simultaneous measurements of the vertical and horizontal electric fields. Experiments were performed for two cases: (1) all phases of the power line open-circuited, and (2) one end of the top line terminated at 600 Ω with the other end open-circuited and the other two phases open-circuited at both ends. The waveshapes of the measured and calculated voltages are in reasonably good agreement, and the reasons for observed discrepancies are discussed     

Making friends in online games: gender differences and designing for greater social connectedness

ABSTRACT

While online multiplayer games provide an opportunity for players to both maintain and establish new connections, male and female players have been found to experience these environments differently. Interviews (n?=?22) and focus groups (n?=?14) were used to explore these differences as they impact on creating new social connections, as well as to provide recommendations for the development of new social tools and features that account for these differences. While all participants experienced toxicity and performance pressure as barriers to forming new connections, female players uniquely reported the impacts of misogynistic targeting and stereotype threat. In turn, female players wishing to avoid these stresses would often mask their gender. The common practice of gender misrepresentation by both male and female players impacted female players’ ability to create social connections through voice technology, as well as building their distrust of unknown others. Recommendations are made to build social connectedness between players taking into account the specific constraints faced by female players. These include establishing mentoring opportunities as well as profiling players beyond their immediate skill or rank. Additionally, the desire for control of one’s online identity presents practical challenges that may be overcome through thoughtful design.     

Single image super resolution based on sparse representation using discrete wavelet transform

Multimedia Tools and Applications - Single image super resolution (SR) based on sparse representation is a promising technique where the SR problem is solved by searching for the most robust...     

Zinc Oxide Nanowire Decorated Single‐Use Electrodes for Electrochemical DNA Detection

The surfaces of pencil graphite electrodes (PGEs) were decorated with zinc oxide nanowires (ZnO NWs) for the electrochemical detection of nucleic acids. ZnO NWs were synthesized through simple hydrothermal method. PGEs decorated with ZnO NWs (ZnO NW/PGEs) were electrochemically characterized through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) following morphological characterization through transmission (TEM) and scanning electron microscopy (SEM). Enhanced sensor response obtained using ZnO NW/PGEs contrary to the bare PGE (control) samples. Our preliminary results simply reveal the potential of combining ZnO NWs with disposable sensor technology for the electrochemical detection of DNA.     

Artificial lift infrastructure planning of shale gas horizontal wells considering endogenous and exogenous uncertainties

Artificial lift methods (ALMs) lift the accumulated fluids from horizontal shale-gas-producing wells and help sustain well performance. An artificial lift infrastructure plan includes the selection of ALMs and their operating schedule. This paper presents two discrete-time large-scale nonconvex mixed-integer nonlinear programming models to solve the artificial lift infrastructure planning problem. Two equivalent mixed-integer linear programming models are formulated using the special structure of the nonlinear terms. A set of valid inequalities is defined to tighten the models and shorten solution times to two orders of magnitude, considering well production limitations. We incorporate endogenous uncertainty in ALM-dependent production rates and exogenous uncertainty in shale gas prices into the models. For a hypothetical case study under only endogenous uncertainties, the value of the stochastic solution is 5%. For the same case study, the exogenous uncertainty in gas prices does not change the optimum solution.     

Solids transport models comparison and fine‐tuning for horizontal,low concentration flow in single‐phase carrier fluid

We determined and fine‐tuned the solids transport models appropriate for predicting the single‐phase carrier fluid velocity to transport solid particles in conduits for horizontal, low concentration flow. A database with 538 experimental data points was compiled. A literature review was performed to determine the data ranges, forces, and mechanisms used to develop 44 models, and their velocity predictions were compared against the database using statistics. Using the dimensionless forms of the models and the data, the model parameters were adjusted to improve their accuracy and identify the dominant forces. At low concentrations: for liquid/solid flow from a bed of solids and gas/solid flow from the bottom of pipelines, the particle weight, and inertial and viscous forces dominate; for gas/solid flow from a bed of solids, the particle weight, and inertial, viscous, and adhesive forces play a role; and gaps exist in the data for large‐diameter pipes and high‐density gases. © 2013 American Institute of Chemical Engineers AIChE J, 60: 76–122, 2014     

Transient electric and magnetic fields associated with establishinga finite electrostatic dipole, revisited

The authors reexamine the analysis of M.J. Master and M.A. Uman (1983), who derived and plotted the electromagnetic field waveforms generated by a square wave of current propagating with constant speed along a finite linear path, resulting in the formation of a finite electrostatic dipole. It was concluded that such a square pulse of current had charge only at its front and rear. The authors argue that errors were made in that analysis, correct these errors, and extend the overall analysis: (1) to show that the decomposition of the electromagnetic fields into electrostatic, induction, and radiation components on the basis of distance dependence is not general; (2) to demonstrate the use of the continuity equation in finding the charge distribution along a current path when the current distribution is known; and (3) to show how a seemingly simple analytical technique, the treatment of an abrupt step of current as a linearly rising current in the limit that the risetime goes to zero, can lead to erroneous results if there is not a good physical and mathematical understanding of all the variables involved     

Lightning-induced voltages at both ends of a 448-mpower-distribution line

Lightning-induced voltages due to return strokes in ground flashes beyond about 5 km were measured simultaneously at both ends of an unenergized 448-m power-distribution line. The measurements represent an extension of an earlier experiment on the same line in which voltages are obtained at only one end of the line. In addition to the induced voltage measurements, the causative lightning electric and magnetic fields are recorded. The voltage and field measurements are made as a function of the lightning direction and of the power-line termination. For both measured and idealized electric fields as inputs to a time-domain transmission-line coupling model, the authors calculate line voltages as a function of the incident angle of the lightning electromagnetic radiation and of the line termination. Measured and predicted voltages calculated from the coupling model with measured fields as inputs show, overall, good agreement in waveshape, but the predicted voltages are about a factor of three larger in amplitude. To the extent that the results can be compared, there is reasonable agreement with the earlier experiments on the same line     

The structure and analysis of nanotechnology co-author and citation networks

Research activities and collaborations in nanoscale science and engineering have major implications for advancing technological frontiers in many fields including medicine, electronics, energy, and communication. The National Nanotechnology Initiative (NNI) promotes efforts to cultivate effective research and collaborations among nano scientists and engineers to accelerate the advancement of nanotechnology and its commercialization. As of August 2008, there have been over 800 products considered to benefit from nanotechnology directly or indirectly. However, today’s accomplishments in nanotechnology cannot be transformed into commercial products without productive collaborations among experts from disparate research areas such as chemistry, physics, math, biology, engineering, manufacturing, environmental sciences, and social sciences. To study the patterns of collaboration, we build and analyze the collaboration network of scientists and engineers who conduct research in nanotechnology. We study the structure of information flow through citation network of papers authored by nano area scientists. We believe that the study of nano area co-author and paper citation networks improve our understanding of patterns and trends of the current research efforts in this field. We construct these networks based on the publication data collected for years ranging 1993 through 2008 from the scientific literature database “Web of Science”. We explore those networks to find out whether they follow power-law degree distributions and/or if they have a signature of hierarchy. We investigate the small-world characteristics and the existence of possible community structures in those networks. We estimate the statistical properties of the networks and interpret their significance with respect to the nano field.