F-LEACH: a fuzzy-based data aggregation scheme for healthcare IoT systems

The Journal of Supercomputing - Internet of Things (IoT) is an emerging paradigm that consists of numerous connected and interrelated devices with embedded sensors, exchanging data with each other...     

Characterization of titania thin films grown by dip-coating technique

A dip-coating technique was employed to prepare anatase phase of titania thin films. Fluorine doped tin oxide substrates were used to prepare titania thin films. The samples were annealed at 550 °C for 18 h. X-ray diffraction results revealed the amorphous and anatase phases of TiO₂ for as-synthesized and annealed samples, respectively. The crystallite size of anatase TiO₂ thin films was almost 25 nm for annealed samples. UV–visible confirmed the energy band gap 3.86 and 3.64 eV for as-prepared and calcinated titania thin films. The reduction in the energy band gap could be due to the change in crystallization and agglomeration of small grains after calcination. The morphology of the prepared films was investigated by field emission scanning electron microscopy which demonstrated the agglomeration of spherical particles of TiO₂ with average particle size of about 30 nm. The molecular properties (chemical bonding) of the samples were investigated by means of Fourier Transform Infrared (FTIR) spectroscopy. FTIR analysis exhibited the formation of titania, functional group OH, hydroxyl stretching vibrations of the C–OH groups, bending vibration mode of H–O–H, alkyl C–H stretch, stretching band of Ti–OH, CN asymmetric band stretching, and C=O saturated aldehyde.     

Failure analysis of unidirectional polymeric matrix composites with two serial pin loaded-holes

The objective of this study is to investigate the effects of geometrical and physical parameters on failure modes and failure loads in unidirectional polymeric matrix composites with two serial pin loaded holes, analytically and experimentally. It is assumed that all of unidirectional fibers in the laminate lie in one direction while loaded by a load p ₀ at infinity, parallel to the direction of the fibers. To derive equilibrium equations based on a Shear-Lag theory, a rectangular arrangement of fibers is considered and with the proper use of boundary and boundness conditions, stress and displacement fields are computed within the laminate, along with the surrounding pinholes. Finally by using the Hashin criterion failure modes and failure loads are estimated. To validate analytical results based on shear-lag theory, an experimental program is carried out. A very good agreement is observed between two procedures. Based on results, in small sizes of two pins, the dominant failure mode is bearing and with the increasing of hole sizes, failure modes are changed to tension and shear modes.     

Effect of stirring on behaviour of double oxide film defects in A356 aluminium melt

The effect of stirring of melt on the behaviour of double oxide film (bifilm) defects in A356 melt was investigated using a reduced pressure test (RPT) technique. The melt was poured from a height into a crucible to introduce bifilms into the melt. The melt was then either remained stagnant or mechanically stirred, and RPT samples were taken from the melt at 8 min intervals. The RPT samples were then characterised by determination of their porosity parameters and examination of the internal surfaces of the pores using a scanning electron microscope. The results showed that stirring of the melt facilitated the diffusion of H in the melt into the atmosphere of the defects and hence accelerated the removal of the defects from the melt by floatation. This effect was attributed to the increase in the stress induced to the defects, which increased the rate of formation of cracks on their layers.     

The Role of Matrix Metalloproteinase Polymorphisms in Ischemic Stroke

Stroke remains the fifth leading cause of mortality in the United States with an annual rate of over 128,000 deaths per year. Differences in incidence, pathogenesis, and clinical outcome have long been noted when comparing ischemic stroke among different ethnicities. The observation that racial disparities exist in clinical outcomes after stroke has resulted in genetic studies focusing on specific polymorphisms. Some studies have focused on matrix metalloproteinases (MMPs). MMPs are a ubiquitous group of proteins with extensive roles that include extracellular matrix remodeling and blood-brain barrier disruption. MMPs play an important role in ischemic stroke pathophysiology and clinical outcome. This review will evaluate the evidence for associations between polymorphisms in MMP-1, 2, 3, 9, and 12 with ischemic stroke incidence, pathophysiology, and clinical outcome. The role of polymorphisms in MMP genes may influence the presentation of ischemic stroke and be influenced by racial and ethnic background. However, contradictory evidence for the role of MMP polymorphisms does exist in the literature, and further studies will be necessary to consolidate our understanding of these multi-faceted proteins.     

Semitransparent polymer solar cells

Bulk heterojunction based polymer:fullerene solar cells have attracted intensive research interest both in academic and industrial communities in the last two decades, mainly related to their potential low‐cost production process. A power conversion efficiency of over 10% has been reported recently, making the commercialization of this clean and cheap solar energy convertor a realistic prospect for the near future. The intrinsic features of semitransparency and color tunability of the thin polymeric photoactive films are the greatest asset for polymer solar cells. Recently, aesthetic semitransparent polymer solar cells (ST‐PSCs) that can be integrated into transparent windows, roofs, glass and other semitransparent architectural elements have received much attention. In this perspective paper, we present the progress in achieving high performance ST‐PSCs, discuss the requirements for transparent electrodes, focusing on alternatives to tin‐doped indium oxide, and address the challenges ahead to make ST‐PSC viable for real applications. © 2013 Society of Chemical Industry     

TiO2 hollow spheres as a novel antibiotic carrier for the direct delivery of gentamicin

The TiO₂ hollow spheres were synthesized using a green, cheap, and easy process, in which carbonaceous spheres were chosen as the removable template. The prepared materials were characterized by X-ray diffraction (XRD), Field emission scanning electron microscopy (FESEM), Energy-dispersive X-ray spectroscopy (EDX), Atomic force microscopy (AFM), Fourier Transform Infrared Spectroscopy (FTIR), and Brunauer–Emmett–Teller (BET) analysis. According to the results, the obtained mesoporous TiO₂ hollow spheres demonstrated an external diameters less than 200?nm with shell thickness around 40?nm. The antibacterial activities of the TiO₂ hollow spheres were evaluated against gram-positive (Bacillus subtilis and Staphylococcus aureus) and gram-negative (Escherichia coli and Pseudomonas aeruginosa). No antibacterial activity was found for TiO₂ hollow spheres in the used concentrations. TiO₂ hollow spheres were loaded with gentamycin as a selected antibiotic to magnify their benefits in biomedical applications. TiO₂ hollow spheres exhibited good antibiotic carrier activity for the direct delivery of gentamicin, which was attributed to interaction between gentamicin and surface due to their larger specific surface area, more abundant porous structure, and their spherical morphology. The application of TiO₂ hollow spheres as gentamicin carrier undoubtedly opens an avenue to use hollow sphere materials in other drug delivery applications.