Donor–acceptor-structured 1,4-diazatriphenylene derivatives exhibiting thermally activated delayed fluorescence: design and synthesis,photophysical properties and OLED characteristics

A new series of luminescent 1,4-diazatriphenylene (ATP) derivatives with various peripheral donor units, including phenoxazine, 9,9-dimethylacridane and 3-(diphenylamino)carbazole, is synthesized and characterized as thermally activated delayed fluorescence (TADF) emitters. The influence of the donor substituents on the electronic and photophysical properties of the materials is investigated by theoretical calculations and experimental spectroscopic measurements. These ATP-based molecules with donor–acceptor–donor (D–A–D) structures can reduce the singlet–triplet energy gap (0.04–0.26 eV) upon chemical modification of the ATP core, and thus exhibit obvious TADF characteristics in solution and doped thin films. As a demonstration of the potential of these materials, organic light-emitting diodes containing the D–A–D-structured ATP derivatives as emitters are fabricated and tested. External electroluminescence quantum efficiencies above 12% and 8% for green- and sky-blue-emitting devices, respectively, are achieved.     

808nm高效率激光二极管

目前808nm高效率激光二极管产品的转换效率只有50%左右,还有很大的提升空间。通过提高欧姆接触层浓度、界面渐变和波导层掺杂等方面的外延材料结构优化,减小附加电压和电阻值,设计制作了808nm大光腔应变量子阱外延材料;并制作了200μm发光区标准单管,提取了材料内部参数,材料内损耗iα为0.67cm-1,内量子效率iη为0.88;将圆片解理成2mm腔长的巴条进行腔面镀膜,并烧结成标准单管,25℃下单管电光效率达到61.1%;将巴条烧结到微通道载体上,制作成标准微通道水冷单条阵列,水温15℃110A下输出光功率126.6W,电光转换效率62.77%。     

大功率半导体激光器的腔面钝化

大功率半导体激光器的腔面退化是影响其寿命和可靠性的重要因素,长期以来一直是人们关注和研究的重点。本文利用离子铣结合腔面钝化还原层的方法对大功率半导体激光器的腔面进行处理。结果显示,离子铣腔面钝化能够在一定程度上减少半导体激光器的功率退化,168h加速老化后退化幅度降低4.5%;同时该技术对老化过程中COD阈值降低有明显的抑制作用,可有效减少使用中的突然失效。结果表明,该技术能够改善半导体激光器的腔面特性,器件的可靠性和使用寿命可望得到提高。     

1.06μm大功率连续半导体激光器

利用金属有机化学气相淀积(MOCVD)技术,生长了InGaAs/AlGaAs分别限制压应变双量子阱和单量子阱两种材料结构,通过对不同腔长单管激光器的LIV测试获得内部参数,对单、双阱两种材料结构器件参数进行对比分析,确定了单量子阱结构作为1.06μm大功率半导体激光器的材料结构。通过研究单管激光器的电光转换效率与腔长、注入电流的关系,获得了最高达到57.5%的电光转换效率。对1mm腔长单管激光器进行了大电流高温加速老化测试,结果显示研制出的单管激光器室温下在1.5A工作电流下寿命远大于104h。     

高斜率效率隧道结叠层激光器的研制

隧道结叠层激光器技术具有广泛的应用空间,如高斜率效率、高功率密度、多波长激光器等。采用LP-MOCVD系统生长隧道结材料,CCl4作为p型掺杂源,SiH4作为n型掺杂源,并采用δ掺杂技术,使得n+-GaAs的掺杂浓度大于1×1019/cm3,隧道结的面电阻率小于2×10-4Ω.cm2。设计生长了双叠层、三叠层材料,该材料制作的900nm双叠层激光器在200ns脉宽、20A工作电流下输出功率35W,斜率效率1.8W/A,是单层材料的1.8倍,隧穿结引入的压降约为0.15V;860nm三叠层激光器的斜率效率大于2.7W/A,是单层材料的2.7倍。     

9μm截止波长128×128 AlGaAs/GaAs量子阱红外焦平面探测器阵列

报道了128×128 AlGaAs/GaAs量子阱红外焦平面探测器阵列的设计和制作.采用金属有机化学气相淀积外延技术生长外延材料,并在GaAs集成电路工艺线上完成工艺制作.为得到器件参数,设计制作了台面尺寸为300μm×300μm的大面积测试器件;77K下2V偏压时暗电流密度为1.5×10-3A/cm2;80K工作温度下,器件峰值响应波长为8.4μm,截止波长为9μm,黑体探测率DB 为3.95×108(cm·Hz1/2)/W.将128×128元 AlGaAs/GaAs量子阱红外焦平面探测器阵列芯片与相关CMOS读出电路芯片倒装焊互连,在80K工作温度下实现了室温环境目标的红外热成像,盲元率小于1%.     

9μm截止波长128×128 AlGaAs/GaAs量子阱红外焦平面探测器阵列

报道了128×128 AlGaAs/GaAs量子阱红外焦平面探测器阵列的设计和制作.采用金属有机化学气相淀积外延技术生长外延材料,并在GaAs集成电路工艺线上完成工艺制作.为得到器件参数,设计制作了台面尺寸为300μm×300μm的大面积测试器件;77K下2V偏压时暗电流密度为1.5×10-3A/cm2;80K工作温度下,器件峰值响应波长为8.4μm,截止波长为9μm,黑体探测率DB 为3.95×108(cm·Hz1/2)/W.将128×128元 AlGaAs/GaAs量子阱红外焦平面探测器阵列芯片与相关CMOS读出电路芯片倒装焊互连,在80K工作温度下实现了室温环境目标的红外热成像,盲元率小于1%.     

Possible Involvement of the Upregulation of ΔNp63 Expression Mediated by HER2-Activated Aryl Hydrocarbon Receptor in Mammosphere Maintenance

Cancer stem cells (CSCs) contribute to the drug resistance, recurrence, and metastasis of breast cancers. Recently, we demonstrated that HER2 overexpression increases mammosphere formation via the activation of aryl hydrocarbon receptor (AHR). In this study, the objective was to identify the mechanism underlying mammosphere maintenance mediated by HER2 signaling-activated AHR. We compared the chromatin structure of AHR-knockout (AHRKO) HER2-overexpressing MCF-7 (HER2-5) cells with that of wild-type HER2-5 cells; subsequently, we identified TP63, a stemness factor, as a potential target gene of AHR. ΔNp63 mRNA and protein levels were higher in HER2-5 cells than in HER2-5/AHRKO cells. Activation of HER2/HER3 signaling by heregulin treatment increased ΔNp63 mRNA levels, and its induction was decreased by AHR knockdown in HER2-5 cells. The results of the chromatin immunoprecipitation assay revealed an interaction between AHR and the intronic region of TP63, which encodes ΔNp63. A luciferase reporter gene assay with the intronic region of TP63 showed that AHR expression increased reporter activity. Collectively, our findings suggest that HER2-activated AHR upregulates ΔNp63 expression and that this signaling cascade is involved in CSC maintenance in HER2-expressing breast cancers.     

大中华CRM的十个挑战--由手机服务所想到的

信息技术和互联网的应用软件创新会给CRM的业界带来挑战吗?当然!但会是何种挑战,我们又应当如何应对呢?即使这些创新软件仅限于手机上的应用,也会令人惊叹不已。到2005年底中国预计有超过4亿的手机订户,这意味着庞大数量的中国人正逐渐以手机作为主要的联络工具,超越了报纸、广播、电视、邮政等媒介的影响。客户关系是靠沟通培养的,因此,兴起的手机应用软件创新,为建立双赢关系提供了新方法。下文中介绍了10种手机软件的创新。1.电话内置插件:是内置电话的iPOD,还是内置iPOD的电话内容:NEC公司在中国销售带有摄像功能的手机,韩国三星公…