Heat Generation in Multilayer Piezoelectric Actuators

Multilayer piezoelectric actuators when driven under high frequency, generate significant heat, which influences the reliability and other piezoelectric properties. In this paper, heat generation in various types of multilayer PZT-based actuators was studied. Experimental results showed that heat generation is mainly caused by ferroelectric hysteresis loss in the stress-free state. A simplified analytic method was established to evaluate the temperature rise, which is useful for the design of multilayer and other high-power actuators.     

Piezoresistivity in Polymer-Ceramic Composites

Composite materials composed of randomly dispersed semiconducting ceramic particles in an insulating polymer matrix show a pronounced change in resistivity with pressure. Different amounts of iron oxide (Fe₃O₄) powder and antimony-doped tin oxide (SnO₂:Sb) powder were dispersed in an epoxy polymer matrix to form pressure-sensitive composites. In each family of materials, an insulator-to-semiconductor transition is observed in agreement with percolation theory. Composites within a certain range of filler content showed substantial piezoresistive effect under both uniaxial and hydrostatic pressure in which sensitivity is controlled by the choice of filler material and the volume fraction. The effect of temperature on the piezoresistance effect was also examined. Piezoresistors made from Fe₃O₄ composites showed larger temperature changes than those filled with Sb-doped SnO₂.     

Alternate-Day Fasting Ameliorates Newly Established Sjögren’s Syndrome-like Sialadenitis in Non-Obese Diabetic Mice

Intermittent fasting confers protections to various diseases including autoimmune disorders, but the specific effects of intermittent fasting on Sjögren’s syndrome (SS) remains inconclusive. The present study was undertaken to determine the specific impact of alternate-day fasting (ADF) on newly established SS-like sialadenitis using non-obese diabetic (NOD) mice. Female NOD mice were deprived of food every other day from 10 to 13 weeks of age, the early stage of established SS, and then analyzed for the disease characteristics. Mice in the ADF group had higher salivary flow rate and attenuated submandibular gland (SMG) inflammation, compared to the control mice fed with standard chow ad libitum. The improvements were accompanied with a decrease in the total leukocytes, T and B lymphocytes and activated CD4 and CD8 T cells, and a down-regulation of pro-inflammatory cytokines IFN-γ and IL-17, chemokine receptor CXCR3 and its ligands CXCL9 and CXCL11 in the SMGs. ADF also led to elevated mRNA levels of water channel protein aquaporin 5 and tight junction protein claudin-1, two factors crucial for normal salivary secretion in the SMGs. In addition, ADF reduced the proportion of IFN-γ- and IL-17- expressing CD4 T cells and diminished mRNA levels of IFN-γ, TNF-α, and IL-17 in the total submandibular draining lymph node cells. Taken together, ADF is effective in ameliorating newly established SS-associated salivary gland exocrinopathy in NOD mice.     

Visualizing Intramolecular Dynamics of Membrane Proteins

Membrane proteins play important roles in biological functions, with accompanying allosteric structure changes. Understanding intramolecular dynamics helps elucidate catalytic mechanisms and develop new drugs. In contrast to the various technologies for structural analysis, methods for analyzing intramolecular dynamics are limited. Single-molecule measurements using optical microscopy have been widely used for kinetic analysis. Recently, improvements in detectors and image analysis technology have made it possible to use single-molecule determination methods using X-rays and electron beams, such as diffracted X-ray tracking (DXT), X-ray free electron laser (XFEL) imaging, and cryo-electron microscopy (cryo-EM). High-speed atomic force microscopy (HS-AFM) is a scanning probe microscope that can capture the structural dynamics of biomolecules in real time at the single-molecule level. Time-resolved techniques also facilitate an understanding of real-time intramolecular processes during chemical reactions. In this review, recent advances in membrane protein dynamics visualization techniques were presented.     

Graded evolution of anisotropic microstructure during sintering from crystal-oriented powder compact

Anisotropic sintering, including shrinkage and grain growth, was examined for c-axis-oriented (Sr,Ca)₂NaNb₅O₁₅ (SCNN) ceramics, which were prepared by colloidal processing under a magnetic field. In the c-axis-oriented SCNN powder compact, shrinkage and grain growth along the c-axis were higher than those along the a-axis. The anisotropic microstructural development was clearly associated with anisotropic sintering shrinkage. X-ray diffraction, scanning electron microscopy, and energy back scattering diffraction showed that the grain growth of oriented particles by including random grains contribute to the development of the oriented microstructure. Finally, the highly crystal-oriented SCNN ceramics with a densified microstructure were obtained through anisotropic sintering. These results clearly showed the potential to develop a well-defined anisotropic microstructure during sintering by designing and controlling the particle packing structure in a powder compact.     

Effects of polyglycerol esters of fatty acids and ethylene‐vinyl acetate co‐polymer on crystallization behavior of biodiesel

Biodiesel fuels (BDF) have many problems in the cold due to their crystallization properties. In particular, precipitation of large crystals of high‐melting fractions in BDF at low temperatures remarkably changes cold flow property of BDF and, thereby, it increases the values of cold filter plugging point. In this study, we evaluated polyglycerol esters of fatty acids (PGE) and ethylene‐vinyl acetate co‐polymer (EVA) as chemical additives to improve the cold flow property of palm oil‐based FAME (PFME). The results of solid fat content measurement indicate that the simultaneous addition of PGE and EVA showed synergistic effects on suppression of crystallization of PFME, however such effect was not observed when EVA was used alone. DSC thermograms indicated that the PGE additives not only decreased the crystallization temperature but also kinetically suppressed the crystal growth. Polarized light microscopy showed that the simultaneous addition of PGE and EVA led to the formation of considerably small and fine‐dispersed crystals of PFME. These results indicate that combined effects of PGE and EVA caused the formation of fine‐dispersed PFME crystals, which could improve the viscous properties of palm oil‐based BDF at relatively cold temperatures.     

Micro-/nanostructural investigation of laser-cut surfaces of single- and polycrystalline diamonds

Micrometer- to nanometer-scale structures of the cut surfaces of single- and polycrystalline diamonds by a pulsed ultraviolet laser have been thoroughly investigated by scanning and transmission electron microscopy. Within the laser-cut grooves, the processed diamond surfaces are extensively covered with laser-modified debris which consists of complex layered units of graphite with various crystallinities. The units consist of 1) highly oriented graphite, 2) corrugated graphite, and 3) nanocrystalline graphite, which are sequentially located from the surface of the underlying diamond substrate to the center of the grooves. Detailed textural examinations revealed that the highly oriented graphite unit is a product of the initial graphitization of diamond by a solid-state diffusion process, whereas the latter two units are deposition products from the liquid and/or vapor phases of carbon in the later stage. The present study demonstrates that the laser-cutting of diamonds proceeds in a two-step process: 1) extensive graphitization of laser-scanning path and 2) subsequent sublimation of the pre-formed graphite. These processes are basically identical among the three different types of diamonds (single crystal type Ib, single crystal type IIa and nano-polycrystalline aggregate) tested in this study.     

Prolonged Aftereffect of Visuomotor Adaptation to Gradually Distorted Reality Displayed on a See-Through Head-Mounted Device

Growing evidence suggests that the gradual transformation of visuomotor association drives a distinct learning process from abrupt transformation in humans. In the current study, we developed a novel omnidirectional visuomotor transformation paradigm to study details of such difference in more realistic environment than conventional experimental systems. Participants were asked to perform a repetitive three-dimensional (3D) arm-reaching task to a target on a front touch panel, wearing a video see-through head-mounted device that displayed a rotating view of surrounding images. In the abrupt condition, the images were rotated by 20°; in the gradual condition, the rotation was increased in a stepwise-manner from 0° to 20°. In both conditions, pointing errors were decreased after adaptation. Further, although the aftereffect of adaptation was not different between conditions, the speed of decay of the aftereffect, which was quantified by an exponential fit, was slower in the gradual condition, suggesting longer-lasting aftereffects for the gradual shift.     

Thick Film Patterned Ceramics Using UV-Curable Pastes

Screen-printed layers of Al₂O₃, BaTiO₃, 0.90Pb(Mg_1/3Nb_2/3)-0₃–0.10PbTiO₃, Pb(Zr,Ti)O₃, ZnO, and glass alumina pastes have been patterned using photoprinting techniques. Curability of each paste by ultraviolet light and formation of holes with various diameters were studied for application as a production method for very small-sized vias. The dependence of hole diameters on various experimental parameters is presented and discussed. Wall slopes were found to depend on the transmission of the powders used in the pastes.