Volumetric Change and Surface Properties of Temperature-Sensitive Polyvinylalcohol (PVA) Hydrogel

Polyvinylalcohol (PVA) polymer gel is a temperature sensitive polymeric gel, with a critical transition temperature (with H₂O) of 310 K. At higher than 310 K, this temperature sensitive polymer gel shrinks because of discharging water, whereas at lower temperatures, the gel swelled because of absorbing water. The reversibility of the gel's volume change was confirmed by temperature swing. The adsorption behavior of an organic compound onto the PVA polymer gel in water was tested at various temperatures. The amount of adsorbed organic compound increased remarkably at temperatures higher than about 310 K. Then, it was confirmed that the organic compound in PVA polymer gel could be reversibly adsorbed and desorbed by a temperature change between 293 and 323 K. The mechanism of adsorption of the organic compound onto the PVA polymer gel could be explained by hydration and dehydration of polymer gel.     

1-GHz-spaced 16-channel arrayed-waveguide grating for a wavelength reference standard in DWDM network systems

We fabricated a 1-GHz-spaced 16-channel arrayed-waveguide grating (AWG) by using a new AWG configuration where the path of each arrayed waveguide winds backward and forward across a 4-in diameter wafer without crossing any other waveguides. The ultra-narrow (< 1 GHz) and stable transmission bands of this AWG can be used to construct a wavelength reference standard covering the S, C, and L bands in the dense wavelength-division-multiplexing network systems whose frequency deviation is /spl plusmn/160 MHz.     

Effects of Surface Concentration on Drying Behavior of Carbohydrate Solutions

As the surface properties of the drying materials are very important not only for the drying rate but also for the quality change during drying, the effects of surface concentration on the drying behavior of liquid foods (sugar solutions) were investigated by isothermal drying experiments and by numerical calculation experiments. The isothermal drying experiments with gelled sugar solution systems (sucrose and maltodextrin) were carried out at various relative humidity (RH) values (RH = 0 to 84%). Separate experiments were carried out for determination of the desorption isotherms.

The isothermal drying curves of sugar solutions at RH = 0 to 51% were very similar. Numerical simulations also showed that the drying curves of these sugars at the surface concentration = 0 and 0.1 are almost the same, although the concentration distributions are different.

When a small amount of gelatin was added to sugar solutions, the drying rate decreased remarkably as the gelatin might form a thin film (skin) near the surface, and consequently the retention of ethanol increased.     

A stacking mechanism for setting bills upright in an automated teller machine

 To deal with circulated bills in various conditions regarding size, shape, and rigidity, we have developed a new bill-stacking cassette that can accept and re-dispense various-sized bills. This cassette stacks the bills upright by using deforming guides and sheet rollers under our newly developed “phase control”. It was experimentally verified by stacking tests that the cassette can handle bills in various conditions; thus, we conclude that the new cassette is practical for stacking circulated bills and re-dispensing them securely. Received: 14 August 2001/Accepted: 11 December 2001     

Controlled undercooling of liquid iron in contact with ZrO2 and MgO substrates under varying oxygen partial pressures

The objective of this study is to determine the conditions under which the inclusions present in liquid steel can act as heterogeneous nucleants for solidification. In order to study the factors that define the undercooling of a given metal/oxide couple, the undercooling of a pure iron sessile droplet in contact with Al₂O₃, ZrO₂, and MgO substrates was measured under controlled oxygen partial pressures by observing droplet recalescence. The results showed that the undercooling of iron, in contact with a particular substrate, did not have a unique value, but was significantly affected by the oxygen content on the gas phase. For oxygen partial pressures between 10⁻²¹ and 10⁻¹⁹, the undercooling of iron on ZrO₂ substrates was stable and around 290 °C. In the same range of oxygen partial pressure, the undercooling of iron on MgO substrates remained below 100 °C due to the low stability of this oxide. At lower oxygen contents, substrate decomposition might be the cause for the observed drop in the undercooling of iron on ZrO₂ substrates to below 100 °C. The undercooling also decreased for increasing oxygen content as verified when the gas was changed from gettered Ar/Ar-H₂ to CO/CO₂ mixtures. The variation in undercooling was related to the wetting of the substrate by the liquid metal, where the deep undercooling observed in the ZrO₂ experiments occurred when the highest contact angle between the liquid metal and the substrate was achieved.     

Calciothermic reduction of titanium oxide in molten CaCl<Subscript>2</Subscript>

Titanium oxides were reduced to metallic titanium using the liquid calcium floating on the molten CaCl₂. A part of Ca dissolved into CaCl₂ and reacted with TiO₂ settled below CaCl₂. The by-product CaO also dissolved by about 20 mol pct into CaCl₂, which was effective in reducing the oxygen concentration in the obtained Ti particles. The compositional region in the Ca-CaCl₂-CaO system was examined for the less oxygen contamination in Ti and the better handling in leaching. A large amount of the residual calcium oxidized the titanium powder in leaching. The metallic Ti powder less than 1000 mass ppm oxygen could be obtained only for 3.6 ks using 5 to 7 mol pct Ca-CaCl₂ at 1173 K. The powder was slightly sintered like sponge, and contained approximately 1500 ppm Ca. The anatase phae, the intermediate product in the refining process of TiO₂, could be also supplied as raw material as well as rutile.     

A delay-encoding-logic array processor for dynamic-programming matching of data sequences

Computationally very expensive dynamic-programming matching of data sequences has been directly implemented in a fully-parallel-architecture VLSI chip. The circuit operates as digital logic in the signal domain, while analog processing is carried out in the time domain based on the delay-encoding-logic scheme. As a result, a high-speed low-power best-match-sequence search has been established with a small chip area. The typical matching time of 80 ns with the power dissipation of 2 mW has been demonstrated with fabricated prototype chips.     

Human papillomavirus investigation of patients with cervical intraepithelial neoplasia 3, some of whom progressed to invasive cancer

Unstable expansion of the CTG repeats in the 3' untranslated region encoding a member of the protein kinase family in the q13.3 band on chromosome 19 is a mutation specific for myotonic dystrophy. To examine the correlation between clinical expression and CTG trinucleotide repeat length, we carried out Southern blot analysis in a family with myotonic dystrophy. In this pedigree, the expanded CTG repeats were transmitted maternally. The mother had three female children. The mother had about 200 CTG repeats, and the number of repeats for each child was about 800, 1500 and 1600 in birth order. The mother and the patient with 800 repeats were unaware of muscle weakness or myotonia. Symptoms were present from age 3 years in the patient with 1500 repeats and from birth in the one with 1600 repeats. Although the mother menstruated regularly, the patients with 800 and 1500 repeats both menstruated irregularly, and the one with 1600 repeats has never menstruated. The age of onset and severity of the disease were correlated with the size of the expanded repeats. Endocrinological studies revealed that the basal levels of the gonadotropins, PRL and E2 were within normal range, and a pituitary response to LHRH was observed. These data suggest that the amenorrhea and menstrual irregularities were caused by a suprahypophyseal dysfunction. When expanded CTG repeats are transmitted maternally, abnormal products resulting from the metabolic disturbance in the affected mother may harm the fetus in utero. A heterozygous fetus, who has more CTG repeats, may be unable to metabolize the pathologic products sufficiently and therefore may become more severely affected. This may explain the exclusive maternal transmission of congenital myotonic dystrophy.     

STEAM DRYING TECHNOLOGIES: JAPANESE R&D

This report reviews some fundamental and practical aspects of steam drying technologies based mainly on studies published in Japan. Steam drying kinetics, and some industrial technologies particularly for drying of foods, textiles and sludges are reviewed with focus on quality of dried material, drying time, dryer selection and energy recovery from steam dryer exhaust. For energy recovery, heat pump technologies are outlined along with characteristics of different types of steam compressors. A new process is proposed for steam drying; it combines a direct-indirect dryer followed by a direct steam dryer for internal moisture removal.