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1.
2.
The graft copolymerization of methyl methacrylate onto natural rubber (NR) was carried out varying the concentration of monomer, initiator, thiourea, and silver nitrate over a wide range. The grafting reaction was temperature-dependent. From the Arrhenius plot, the overall energy of activation was computed. A suitable reaction scheme and rate expression for the rate of polymerization was suggested. 相似文献
3.
The concept that plasticity index of soils can be defined as a range of water contents producing a 100-fold variation in undrained shear strength has been experimentally verified with the help of a large number of tests on soils of diverse nature. This has led to the redefinition of the plastic limit as the water content at which undrained shear strength is around 170 kN/m2. Undrained shear strength of a soil at the liquid limit can be considered to be around 1.7 kN/m2. Accordingly, both the liquid limit and the plastic limit have been determined in the present work by a single consistent method, i.e., the Swedish fall cone method. The undrained shear strength-water content relationship has been found to be log-linear for a wide range of water contents beginning from lower than the plastic limit to higher than the liquid limit. This resulted in the formulation of an expression for predicting undrained shear strength of a remolded soil at any water content based solely on its liquid limit and plastic limit. 相似文献
4.
A measure for stability robustness of a linear time-invariant finite-dimensional system state equations is introduced. An upper bound for the measure is derived using the characteristic values of the system. It is shown that the set of optimal systems, namely, systems for which the stability robustness measure attains the bound, contains the normal set, which has been considered as the set of optimal robustness 相似文献
5.
Silicon - The promising capability of Triple Material Surrounding Gate Junctionless Tunnel FET (TMSG – JL – TFET) based 6 T SRAM structure is demonstrated by employing... 相似文献
6.
A number of polyurethanes (PUs) were synthesized by reacting castor oil with toluene-2,4-diisocyanate and hexamethylene diisocyanate and varying the NCO/OH ratio. All these polyurethanes were reacted with some acrylic monomers like ethyl acrylate, n-butyl acrylate, ethyl methacrylate, and butyl methacrylate using a crosslinker ethylene glycol dimethyl-acrylate and benzoyl peroxide as the initiator. The physicochemical properties of interpenetrating polymer networks (IPNs) are reported. Thermogravimetric analysis was used to study the thermal behavior of IPNs and the evaluation of kinetic parameters. Degradation mechanism has also been investigated. Some of the mechanical properties viz. tensile strength, shore-A hardness, elongation at break, etc. are also reported. © 1993 John Wiley & Sons, Inc. 相似文献
7.
The feasibility of chromium(VI) to induce graft polymerization of methyl methacrylate onto silk was investigated. The rate of grafting was determined by varying monomer concentration, chromium(VI) concentration, temperature, acidity of the medium, nature of the silk, reaction medium, and redox system. The graft yield increased with increasing monomer concentration up to 0.65M, and with further increase of monomer the graft yield decreased. The graft yield increased with increasing chromium(VI) concentration. The grafting is considerably influenced by chemical modification of silk prior to grafting. The graft yield is influenced by thiourea concentration, decreasing with increasing thiourea concentration. The effect of certain inorganic salts and anionic surfactants on the rate of grafting was investigated. 相似文献
8.
Flyash, a waste product generated in large quantities in thermal power plants, has been posing problems of disposal. The purpose of the present work was to make a meaningful utilization of flyash as filler in neat epoxy resin matrix and 2% Polybutyleneterepthalate (PBT)/epoxy blend matrix. For this purpose, the tensile, flexural, compression, impact, chemical resistance, and water absorption properties were studied. Composites were made with varying proportion of flyash in epoxy resin and 2% PBT/epoxy blend matrix. Tensile, flexural, and compression properties were measured on a computerized universal testing machine, according to ASTM procedures. Impact strength was determined using izod impact tester for un‐notched specimens. PBT (2%)/epoxy blend matrix composites showed improved mechanical properties over neat epoxy flyash composites. All the composites were found to have good chemical resistance toward acids, solvents, and alkalies. These composites showed better water resistance over neat epoxy flyash composites. POLYM. ENG. SCI. 46:946–953, 2006. © 2006 Society of Plastics Engineers 相似文献
9.
10.
The content and positional distribution of CLA in TAG fractions of lamb tissues was examined with either preformed CLA or
the linoleic acid precursor of CLA in the diet as experimental treatments. The CLA content of phospholipid (PL) from these
tissues was also examined. Thirteen lambs were randomized to the following dietary treatments: (i) control diet (no supplement);
(ii) CLA supplementation (0.33 g d−1 for 21 d prior to weaning) to milk-replacer of pre-ruminating lambs, or (iii) feeding linoleic acid-rich oil (6% safflower
oil on a dry matter basis) to weaned ruminating lambs. At slaughter, tissue samples were procured from diaphragm, rib muscle,
and subcutaneous (SC) adipose tissue. Safflower oil supplementation in the diet resulted in an increase in CLA content of
the TAG from diaphragm, rib muscle, and SC adipose tissue by about threefold (P<0.05) on a mol% basis. CLA was localized to the sn-1/3 positions of TAG. Animals that received pre-formed CLA, however, had increased proportions of CLA at the sn-2 position of TAG from SC adipose tissue, suggesting that there were tissue-specific dietary effects and possible age-related
effects on the mode of FA incorporation into TAG. Safflower oil supplementation in the diet had no effect on the CLA content
of PL from diaphragm, rib muscle, and SC adipose tissue, suggesting that CLA was preferentially incorporated into the TAG
of these tissues. 相似文献