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排序方式: 共有243条查询结果,搜索用时 15 毫秒
1.
Thanapalan Murugesan G. S. Venkat Rathnam S. Panduranga Rao P. Gangadhar Rao 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):290-294
In the present study of gas–liquid contactors, mean residence/contact time was calculated from knowledge of superficial velocity and the gas phase hold-up, for various gas rates and impeller geometry and speeds, and compared with values obtained from RTD measurements. A new correlation, involving Flow Number, Froude Number, system geometry and the physical properties, is proposed. This uses the authors data and those available in literature. 相似文献
2.
In this work, the kinetics and mechanism of free-radical polymerisation of glycidyl methacrylate (GMA) using potassium peroxydisulphate
(PDS) as water soluble initiator in the presence of synthesized 1, 4-Bis (tributyl methyl ammonium) benzene dichloride (TBMABDC)
as multi-site phase transfer catalyst (MPTC) was studied. The polymerisation reactions were carried out under inert and unstirred
conditions at constant temperature of 60 ± 1°C in cyclohexane/water biphase media. The role of concentrations of monomer,
initiator, catalyst and volume fraction of aqueous phase, solvent polarity and temperature on the rate of polymerisation (Rp)
was ascertained. The order with respect to monomer and initiator was found to be unity. The order with respect to catalyst
was found to be 0.51. The rate of polymerisation is independent of ionic strength and pH of the medium. However, an increase
in the polarity of solvent has slightly increased the Rp value. Based on the results obtained, a suitable kinetic scheme has
been proposed to account for the experimental observations and its significance discussed. 相似文献
3.
B Neppolian H C Choi S Sakthivel Banumathi Arabindoo V Murugesan 《Journal of hazardous materials》2002,89(2-3):303-317
The photocatalytic degradation of three commercial textile dyes with different structure has been investigated using TiO(2) (Degussa P25) photocatalyst in aqueous solution under solar irradiation. Experiments were conducted to optimise various parameters viz. amount of catalyst, concentration of dye, pH and solar light intensity. Degradation of all the dyes were examined by using chemical oxygen demand (COD) method. The degradation efficiency of the three dyes is as follows: Reactive Yellow 17(RY17) > Reactive Red 2(RR2) > Reactive Blue 4 (RB4), respectively. The experimental results indicate that TiO(2) (Degussa P25) is the best catalyst in comparison with other commercial photocatalysts such as, TiO(2) (Merck), ZnO, ZrO(2), WO(3) and CdS. Though the UV irradiation can efficiently degrade the dyes, naturally abundant solar irradiation is also very effective in the mineralisation of dyes. The comparison between thin-film coating and aqueous slurry method reveals that slurry method is more efficient than coating but the problems of leaching and the requirement of separation can be avoided by using coating technique. These observations indicate that all the three dyes could be degraded completely at different time intervals. Hence, it may be a viable technique for the safe disposal of textile wastewater into the water streams. 相似文献
4.
Electrodeposition of conducting polyaniline (Pani) was made under potentiostatic condition at pH 1.0 in different electrolyte media (H2SO4 and HClO4) in the absence and presence of two organic dopants, disodium salts of naphthalene-1,5-disulphonic acid (NSA) and of catechol-3,5-disulphonic acid (CSA). The rate and yield of Pani deposition were dependent on the acid medium and the dopant employed. NSA in H2SO4 caused an increase in rate and yield but CSA decrease when compared to the rate and yield of H2SO4 alone. In HClO4 medium, both the dopants showed a decrease. With regard to DC electrical conductivity, both the dopants exhibited an enhancement in H2SO4 medium but NSA a decline in HClO4. Characterisation of the electrosynthesised polymer samples by various instrumental techniques (cyclic voltammetric: CV, FTIR, UV-Visible: UV-Vis, EPR, XRD, TGA and DTG methods) revealed that between the two acid media, H2SO4 was the better one. Further, it enlightened the role of two organic dopants in relation to the acid media. The advantageous role of NSA in H2SO4 had origin on its molecular characteristics such as non-polarity, larger π-electron cloud etc., while CSA could not perform such a role because of its easily oxidisable hydroxyl groups. In HClO4, however, both the dopants could play only an unfavourable role owing to its greater polarity and oxidizing power than H2SO4. 相似文献
5.
A. Vinu T. Krithiga N. Gokulakrishnan P. Srinivasu S. Anandan K. Ariga V. Murugesan V.V. Balasubramanian T. Mori 《Microporous and mesoporous materials》2007,100(1-3):87-94
Three-dimensional cage type iron substituted mesoporous silica with different iron contents (FeSBA-1) was synthesized in a highly acidic media using cetyltriethylammonium bromide and tetraethylorthosilicate as a template and a silica source, respectively. Acylation of toluene with acetic anhydride (AA) was carried out over FeSBA-1 mesoporous catalysts with different nSi/nFe ratios in the temperature range 80–180 °C for a time-on-stream of 1–6 h under liquid phase conditions. The important factors affecting the conversion and the selectivity of the reaction, such as the reaction temperature, feed ratio, catalyst weight and time-on-stream were studied and the results are discussed in detail. The reaction conditions were optimized and the nAA/nToluene ratio of 2 and catalyst weight of 0.1 g (3.3 wt% of total reaction mixture) were maintained for all catalytic runs. It was found that the catalytic activity is strongly influenced by the amount of tetrahedral iron in the catalysts. Among the catalysts used in the present study, FeSBA-1(36) showed a high toluene conversion and selectivity to p-methylacetophenone (p-MAP) under the optimized reaction conditions. It was also found that the selectivity for p-MAP was always higher than m-MAP and o-MAP for all the catalysts and the activity of the catalysts changes in the following order: FeSBA-1(36) > FeSBA-1(90) > FeSBA-1(120). 相似文献
6.
Al-MCM-41 and Fe-containing MCM-41 molecular sieves are hydrothermally synthesized. The low-angle XRD analysis shows that iron incorporation in Al-MCM-41 retains the hexagonal structure of MCM-41. The higher d-spacing values of Fe-Al-MCM-41 catalysts than those of Al-MCM-41 indicate the incorporation of iron into the framework. The mesoporous nature of the materials was confirmed by nitrogen adsorption isotherms. Electron paramagnetic resonance (EPR) and diffuse reflectance spectra (DRS) techniques confirm the tetrahedral coordination of iron into the Al-MCM-41 framework. Acidity of the synthesized catalysts was analyzed by both TPD of ammonia and pyridine-adsorbed FT-IR spectroscopy. The acidity measurements indicate that iron incorporation increases both Lewis and Brønsted acidity of the catalysts. Vapor-phase isopropylation of phenol with the new'alkylating agent isopropyl acetate was carried over the H-forms of the above catalysts. The phenol to isopropyl acetate ratio of 1?:?2 and the phenol space velocity of 1.1 h-1 were found to be the optimum conditions for better phenol conversion and para isomer (4-isopropyl phenol) selectivity. On comparison, the Fe-incorporated Al-MCM-41 catalysts show significantly higher phenol conversion and selectivity toward the important product 4-isopropyl phenol (4-IPP) may be due to stronger Brønsted acid sites generated by the strengthening effect of nearby Lewis acid sites. Further, the undesired and dialkylated products selectivity are found to be lower over Fe-incorporated Al-MCM-41 than pure Al-MCM-41 catalysts. 相似文献
7.
Rathinasamy Sakthivel Thangavel Saravanakumar Murugesan Sathishkumar 《IET systems biology》2017,11(5):139
This study considers the problem of non‐fragile reliable control synthesis for mathematical model of interaction between the sugarcane borer (Diatraea saccharalis) and its egg parasitoid Trichogramma galloi. In particular, the control could be substituted by periodic releases of a small population of natural enemies and hence it is important to propose the time‐varying controller in sugarcane borer. The main aim of this study is to design a state feedback non‐fragile (time‐varying) reliable controller such that the states of the sugarcane borer system reach the equilibrium point within the desired period. A novel approach is proposed to deal with the uncertain matrices which appear in non‐fragile reliable control. Finally, simulations based on sugarcane borer systems are conducted to illustrate the advantages and effectiveness of the proposed design technique. The result reveals that the proposed non‐fragile control provides good performance in spite of periodic releases of a small population of natural enemies occurs.Inspec keywords: microorganisms, plant diseases, biology computing, state feedback, biocontrol, control system synthesisOther keywords: nonfragile reliable control synthesis, sugarcane borer, mathematical model, Diatraea saccharalis, egg parasitoid, Trichogramma galloi, periodic releases, natural enemies, state feedback nonfragile time‐varying reliable controller, equilibrium point, design technique 相似文献
8.
Pragyan Paramita Vimala Devi Subramaniam Ramachandran Murugesan Madhumala Gopinath Ilangovan Ramachandran Satish Ramalingam Xiao Feng Sun Antara Banerjee Francesco Marotta Surajit Pathak 《IET nanobiotechnology / IET》2018,12(6):727
Research dealing with early diagnosis and efficient treatment in colon cancer to improve patient''s survival is still under investigation. Chemotherapeutic agent result in high systemic toxicity due to their non‐specific actions on DNA repair and/or cell replication. Traditional medicine such as Lycopodium clavatum (LC) has been claimed to have therapeutic potentials against cancer. The present study focuses on targeted drug delivery of cationic liposomal nanoformulated LC (CL‐LC) in colon cancer cells (HCT15) and comparing the efficacy with an anti‐colon cancer drug, 7‐ethyl‐10‐hydroxy‐camptothecin (SN38) along with its nanoformulated form (CL‐SN38). The colloidal suspension of LC was made using thin film hydration method. The drugs were characterised using ultraviolet, dynamic light scattering, scanning electron microscopy, energy, dispersive X‐ray spectroscopy. In vitro drug release showed kinetics of 49 and 89% of SN38 and LC, whereas CL‐SN38 and CL‐LC showed 73 and 74% of sustained drug release, respectively. Studies on morphological changes, cell viability, cytotoxicity, apoptosis, cancer‐associated gene expression analysis of Bcl‐2, Bax, p53 by real‐time polymerase chain reaction and western blot analysis of Bad and p53 protein were performed. Nanoformulated LC significantly inhibited growth and increased the apoptosis of colon cancer cells indicating its potential anti‐cancer activity against colon cancer cells.Inspec keywords: cancer, biological organs, cellular biophysics, drug delivery systems, drugs, nanomedicine, genetics, DNA, molecular biophysics, biochemistry, lipid bilayers, toxicology, suspensions, colloids, light scattering, X‐ray chemical analysis, solvation, enzymes, nanostructured materialsOther keywords: energy dispersive X‐ray spectroscopy, in vitro drug release, morphological changes, cell viability, cytotoxicity, apoptosis, cancer‐associated gene expression analysis, Bcl‐2, Bax, real‐time polymerase chain reaction, western blot analysis, Bad protein, p53 protein, scanning electron microscopy, dynamic light scattering, ultraviolet scattering, thin film hydration method, colloidal suspension, nanoformulated form CL‐SN38, 7‐ethyl‐10‐hydroxy‐camptothecin, anticolon cancer drug, colon cancer cells HCT15, cationic liposomal nanoformulated LC, targeted drug delivery, therapeutic potentials, Lycopodium clavatum, traditional medicines, cell replication, DNA repair, nonspecific actions, high systemic toxicity, chemotherapeutic agents, patient survival, colon cancer treatment, colon cancer diagnosis, CL‐LC, potential anticancer activity 相似文献
9.
In addition to moving itself in a greener direction and leveraging other environmental initiatives, IT could help create green awareness among IT professionals, businesses, and the general public by assisting in building communities, engaging groups in participatory decisions, and supporting education and green advocacy campaigns. Along these lines, tools such as environmental Web portals, blogs, wikis, and interactive simulations of the environmental impact of an activity could offer assistance. Green IT is an economic, as well as an environmental, imperative. Greening IT is and will continue to be a necessity, not an option. Green IT represents a dramatic change in priority in the IT industry. So far, the industry has been focusing on IT equipment processing power and associated equipment spending. It's not been concerned with other requirements such as power, cooling, and data center space. However, going forward, the IT industry will need to deal with all of the infrastructure requirements and the environmental impact of IT and its use. The challenges of green IT are immense; however, recent developments indicate that the IT industry has the will and conviction to tackle our environmental issues head-on. The IT sector and users must develop a positive attitude toward addressing environmental concerns and adopt forward-looking, green-friendly policies and practices. 相似文献
10.
A numerical scheme based on the method of fundamental solutions is proposed for the solution of two-dimensional boundary inverse
Stokes problems, which involve over-specified or under-specified boundary conditions. The coefficients of the fundamental
solutions for the inverse problems are determined by properly selecting the number of collocation points using all the known
boundary values of the field variables. The boundary points of the inverse problems are collocated using the Stokeslet as
the source points. Validation results obtained for two test cases of inverse Stokes flow in a circular cavity, without involving
any iterative procedure, indicate the proposed method is able to predict results close to the analytical solutions. The effects
of the number and the radius of the source points on the accuracy of numerical predictions have also been investigated. The
capability of the method is demonstrated by solving different types of inverse problems obtained by assuming mixed combinations
of field variables on varying number of under- and over-specified boundary segments. 相似文献