FTIR-ATR studies of diffusion and perturbation of water in polyelectrolyte thin films. Part 4. Diffusion, perturbation and swelling processes for ionic solutions in SPEES/PES membranes

We report diffusion rates and equilibrium concentrations of water in a polyelectrolyte SPEES/PES film using ATR/FTIR spectroscopy. The data for water obtained by fitting spectral intensities to a dual mode diffusion model in the presence of different counter ions (at 0.2 mol dm⁻³) follow the order Li⁺>Cs⁺>Na⁺>Ca²⁺>K⁺. Diffusion is progressively slower for higher concentrations of NaCl (0.2-0.85 mol dm⁻³) and the NO₃⁻ counter anion leads to a faster diffusion rate than for Cl⁻ at the same concentration. Both water uptake and diffusion rates are broadly consistent with expectations based on the differential degrees of swelling, caused by changes in the SO₃⁻/SO₃⁻ interpolymer chain repulsive forces leading to a decrease in volume diffusion compared with the value for pure water. Direct spectral measurements of the degree of swelling confirm that the process does occur, although the order of the swelling amounts does not map directly onto that of the diffusion rates. This is probably because the interfacial dissociation processes are hydration dependent.     

Qualitative response of safety injection system for a large size break in the reactor coolant system cold leg

Safety injection system, accumulator injection system and residual heat removal system of CHASNUPP-1 were simulated using the computer code APROS. We observed the qualitative response of the simulated system during injection and re-circulation phases after LOCA. During rapid depressurization of SRC system due to leakage, these systems started coolant injection in the SRC system as per plant requirement. Different thermal-hydraulic parameters of the respective systems are presented and discussed. Results obtained are in good agreement with the reported document of the reference power plant.     

Improving security of the Internet of Things via RF fingerprinting based device identification system

Neural Computing and Applications - Security is one of the primary concerns when designing wireless networks. Along detecting user identity, it is also important to detect the devices at the...     

Energy-efficient clustering in mobile ad-hoc networks using multi-objective particle swarm optimization

A mobile ad hoc network (MANET) is dynamic in nature and is composed of wirelessly connected nodes that perform hop-by-hop routing without the help of any fixed infrastructure. One of the important requirements of a MANET is the efficiency of energy, which increases the lifetime of the network. Several techniques have been proposed by researchers to achieve this goal and one of them is clustering in MANETs that can help in providing an energy-efficient solution. Clustering involves the selection of cluster-heads (CHs) for each cluster and fewer CHs result in greater energy efficiency as these nodes drain more power than noncluster-heads. In the literature, several techniques are available for clustering by using optimization and evolutionary techniques that provide a single solution at a time. In this paper, we propose a multi-objective solution by using multi-objective particle swarm optimization (MOPSO) algorithm to optimize the number of clusters in an ad hoc network as well as energy dissipation in nodes in order to provide an energy-efficient solution and reduce the network traffic. In the proposed solution, inter-cluster and intra-cluster traffic is managed by the cluster-heads. The proposed algorithm takes into consideration the degree of nodes, transmission power, and battery power consumption of the mobile nodes. The main advantage of this method is that it provides a set of solutions at a time. These solutions are achieved through optimal Pareto front. We compare the results of the proposed approach with two other well-known clustering techniques; WCA and CLPSO-based clustering by using different performance metrics. We perform extensive simulations to show that the proposed approach is an effective approach for clustering in mobile ad hoc networks environment and performs better than the other two approaches.     

Attitudes towards mobile banking: are there any differences between users and non-users?

Extant research has focused on monitoring the behaviour of people who use mobile banking (MB) but it has paid little attention to understanding the impact of information technology usage behaviour due to cultural differences. Humans are the weakest link in information technology adoption; past research has shown that not all users are predisposed to change their behaviour radically and adopt new channels of banking. This paper examines the demographic patterns of users and non-users of MB. The paper also investigates the attitudinal influences of users and non-users of MB based on innovation attributes. Using empirical research, the study identifies constructs of innovation attributes that were perceived to be significantly different among the users and non-users of MB. The study provides valuable insights into MB in Saudi Arabia that have not been previously investigated. From a practical point, findings of this study will be particularly useful to banks, financial institutions and telecommunication service providers.     

Role of situational method engineering to improve visual information systems in agile distributed environment

Software product prone to continuous evolution due to increase in the use of technology. Therefore, more stakeholders are involved in software evolution increases the cost and complexity. This required optimization of resources and cost to handle evolution with Global Software Development (GSD) to utilize time zones efficiently. The significance challenge of GSD reports: time zone difference, geographical location, communication delays, knowledge sharing, control among stakeholders and development team. Because of these challenges, the requirements for development in GSD environment are also challenge as compared to on site development. Different requirement engineering methods have been used to improve the requirements analysis to deal with ambiguities and inconsistency in large set of requirements. The customization and tailoring of requirements according to changing project’s situations required to improve project development with reusing existing agile methods during requirement engineering phase. Moreover, complex information systems where heterogeneity is inevitable that implies the involvement of divergent stakeholders and necessitate a comprehensive framework to capture multidimensional viewpoints and fulfill aforementioned issues. Therefore, a situational multi-dimensional agile requirement engineering method has been proposed to support team and stakeholders’ viewpoints. The schema of the proposed method is based on challenges recognized by performing Literature Review. Then proposed method has been evaluated via experimental approach and statistical analysis conducted to validated reliability of data collected. This result is significant approved both practically and statistically that the proposed approach ease to use, implement, trained and increased productivity and performance. Hence, the experimental study for the evaluation of the proposed approach results concluded that, proposed approach is the important multimedia tool for supporting organization and distributed development team for information sharing, collaboration, product development.

     

Biomathematical study of time-dependent flow of a Carreau nanofluid through inclined catheterized arteries with overlapping stenosis

Journal of Central South University - This work is concerned with the analysis of blood flow through inclined catheterized arteries having a balloon (angioplasty) with time-variant overlapping...     

Molecular dynamics simulations of enantiomeric separations as an interfacial process in HPLC

Since chromatographic separation is a dynamic process, with the interactions between the drug and the chiral stationary phase mediated by the solvent, no single interacting structure, such as could be found by minimizing the energy, could possibly describe and account for the ratio of residence times in the chromatographic column for the enantiomeric pair. We describe the use of explicit-solvent fully atomistic molecular dynamics simulations, permitting all the interactions between the atoms constituting the chiral stationary phase, solvent molecules and the drug molecule. This allows us to better understand the molecular dynamic chiral recognition that provides the discrimination, which results in the separation of enantiomers by high performance liquid chromatography. It also provides a means of predicting, for a given set of conditions, which enantiomer elutes first and an estimate of the expected separation factor. In this review, we consider the use of molecular dynamics toward this understanding and prediction.     

Single phase multi color emitting Ca2LuTaO6: Dy3+/Eu3+ double perovskite oxide phosphors

The trivalent rare-earth (RE³⁺) doped phosphors show tremendous achievement in narrow band multicolor line emission for various applications. However, the 4f–4f absorption transition of these ions is forbidden in UV and blue light excitation. Usually, a sensitizer having spin allowed transition was used as a co-dopant to excite these ions via the energy transfer phenomenon. Another approach promisingly using to excite these ions by efficient energy transfer from the intrinsic emission of the Ca₂LuTaO₆ double perovskite phosphors host lattice. Phosphors of Ca₂LuTaO₆ with double perovskite structure were synthesized by using a high-temperature solid-state reaction method. The produced Ca₂LuTaO₆ double perovskite phosphors show an intrinsic broad band emission centered at 424 nm under the excitation of 313 nm UV light. The origin of this broad band blue emission was deeply investigated by using computation and experimental approaches. The trivalent activator Dy³⁺ and Eu³⁺ were doped is a single and co-dopant in the produced Ca₂LuTaO₆ phosphors to check their excitation in UV and near-UV spectral region. X-ray diffraction and scanning electron microscopy were used to investigate the structure and phase analysis. Various characterizations such as photoluminescence excitation, emission, and CIE chromaticity coordinates were measured which illustrate the potential of Dy³⁺ and Eu³⁺ activated Ca₂LuTaO₆ double perovskite phosphors for narrow band multicolor line emission for various applications.     

Your comments matter: incorporating viewers’ comments for ranking online video content using bibliometrics

ABSTRACT

The quality of user-generated content over World Wide Web media is a matter of serious concern for both creators and users. To measure the quality of content, webometric techniques are commonly used. In recent times, bibliometric techniques have been introduced to good effect for evaluation of the quality of user-generated content, which were originally used for scholarly data. However, the application of bibliometric techniques to evaluate the quality of YouTube content is limited to h-index and g-index considering only views. This paper advocates for and demonstrates the adaptation of existing Bibliometric indices including h-index, g-index and M-index exploiting both views and comments and proposes three indices h_vc, g_vc and m_vc for YouTube video channel ranking. The empirical results prove that the proposed indices using views along with the comments outperform the existing approaches on a real-world dataset of YouTube.