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1.
Somnath Karmakar 《Polycyclic Aromatic Compounds》2019,39(2):159-171
Eigensolutions of {X( = C,B,N),Y( = C,B,N)}-cyclacene graphs with next nearest neighbor (nnn) interactions have been obtained in analytical forms by adapting n-fold rotational symmetry followed by two-fold rotational symmetry (or a plane of symmetry). Expressions of eigensolution indicate the subspectral relationship among such cyclacenes with an even number of hexagonal rings e.g., eigenvalues of {X,Y}-di-cyclacene are found in the eigenspectra of all such even cyclacenes. Total π-electron energies and highest occupied molecular orbital and lowest unoccupied molecular orbital (HOMO–LUMO) gaps are calculated using the analytical expressions obtained and are found to vary negligibly with the variation of nnn interactions in such cyclacenes. Total π-electron energy is found to increase due to increase in restriction intensity of nnn interactions, whereas the HOMO–LUMO gap of polyacenecs having the even number of hexagonal rings and with one electron at each site (atom) decreases with increase in the restriction intensity since such systems contain degenerate half-filled HOMO (bonding or nonbonding) that are much more vulnerable for perturbations imposed through nnn interactions. 相似文献
2.
Mostofa Shamim Somnath Sinhamahapatra Jahangir Hossain Sayan Lahiri Kausik Dana 《Ceramics International》2018,44(2):1868-1874
The mechanistic pathway of MgO-Al2O3 reaction in solid state to form MgAl2O4 spinel was investigated to correlate the kinetic parameters with ratio of reactants (MgO:Al2O3) and with the presence of a doping agent, TiO2. The time-temperature-expansion data of oxide compacts was analyzed using several model free analyses and model based (linear and non-linear) kinetic algorithms. These indicated that spinel formation process can be best described by single step with n-dimensional Avrami equation for every MgO:Al2O3 ratio, irrespective of titania dopant. The activation energy (Ea) of the process was proportional to % spinel formed in each system and validated with quantitative XRD analysis. The higher value of Avrami coefficient (n) in 90 wt% Al2O3 compositions has been explained with geometric considerations of powder packing. Incorporations of 1% TiO2 in the MgO: Al2O3 oxide compact did not markedly affect the reaction model, frequency factor and Activation energy. 相似文献
3.
Dhyanjyoti Deka Deepu S. Joseph Somnath Ghosh Michael J. Mills 《Metallurgical and Materials Transactions A》2006,37(5):1371-1388
This paper develops an experimentally validated computational model based on crystal plasticity for the analysis of two-phase
α/β Ti-6242 polycrystalline alloys. A rate-dependent elastic-crystal plasticity model is incorporated in this model to accommodate
anisotropy in material behavior and tension-compression asymmetry inherent to this alloy. A combination of microtesting, orientation
imaging microscopy, computational simulations, and minimization process, involving genetic algorithms, is implemented in this
study for careful characterization and calibration of the material parameters. Size effects are considered in this analysis
through a simple scaling process. A homogenized equivalent model of the primary α with transformed β colonies is developed
for incorporation in the Ti-6242 FE model. The polycrystalline Ti-6242 computational model incorporates accurate phase volume
fractions, as well as statistically equivalent orientation distributions to those observed in the orientation imaging microscopy
scans. The effects of orientation, misorientations, and microtexture distributions are investigated through simulations by
this computational model. The model is used to simulate constant strain rate and creep tests in compression and tension, and
the results are compared with experiments. The effects of microstructure and creep-induced load-shedding on the localization
of microstructural stresses and strains are studied for potential crack initiation criteria. 相似文献
4.
Abstract. A pth‐order random coefficient integer‐valued autoregressive [RCINAR(p)] model is proposed for count data. Stationarity and ergodicity properties are established. Maximum likelihood, conditional least squares, modified quasi‐likelihood and generalized method of moments are used to estimate the model parameters. Asymptotic properties of the estimators are derived. Simulation results on the comparison of the estimators are reported. The models are applied to two real data sets. 相似文献
5.
Strength reduction factors (SRFs) continue to play a key role in obtaining design forces from elastic design spectra (via
response modification factors) in ductility-based earthquake-resistant design. Despite several years of sustained research
efforts, it has not been conclusively shown how SRF for a given singledegree-of-freedom structural system depends on various
source and site parameters. A parametric study is carried out here for the explicit dependence of SRF spectrum (describing
variation of SRF with system period for a given ductility demand) on strong motion duration, earthquake magnitude, geological
site conditions, and epicentral distance in case of (non-degrading) elasto-plastic oscillators. For this, scaled response
spectra are considered for different combinations of earthquake magnitude, site conditions and epicentral distance, and SRF
spectra are generated from 1274 accelerograms recorded in western USA after making those compatible with each of these spectra.
It is shown that there is no clear and significant dependence of SRF spectrum on strong motion duration. Further, the parametric
dependence on earthquake magnitude, site conditions, and epicentral distance broadly conforms to the trends reported by earlier
investigations. In particular, this study confirms that the dependence of SRF spectra on earthquake magnitude should not be
ignored.
This paper has been contributed in honour of Professor R N Iyengar, Indian Institute of Science, on the occasion of his formal
retirement. 相似文献
6.
The effectiveness of Cocos nucifera pollen extract immunotherapy (CPE-IT) was studied in 96 patients allergic to C. nucifera pollen. A placebo-controlled study was performed at random for a period of 6-12 months. The clinical status of the patients measured by the symptom-medication scores demonstrated that C. nucifera pollen-allergic patients had significant (p < 0.005) clinical improvement after CPE-IT in comparison to placebo treatment. Serological study resulted a significant reduction (p < 0.001) of specific IgE and significant elevation (p < 0.01) of specific IgG in post-therapeutic patients' sera which were correlated significantly (r = 0.45, p < 0.001); the changes of the above immunoglobulin levels in the placebo-treated patients were nonsignificant. However, there was no correlation between symptom-medication scores and changes in specific serum IgE or IgG levels. 相似文献
7.
Nemai Chandra Karmakar 《国际射频与微波计算机辅助工程杂志》2007,17(3):311-319
The resonant frequency of a circular patch antenna with and without circular cavity is measured. The patch miniaturization in the presence of the cavity is proved. Different methods of reducing resonant frequencies and broadening bandwidth without significantly reducing antenna gain are presented. Capacitively loaded patch and slits on the patch stimulate the patch at lower frequencies and multiple resonances, thus help miniaturization. Finally ferrite loading on the feed probe further increases the bandwidth without significantly reducing the antenna gain. The method is much more improved than that for a resistive loaded patch and a deformed patch. © 2007 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2007. 相似文献
8.
Artificial Intelligence Review - Data are being continuously generated from various operational steps in the oil and gas industry. The recordings of these data and their proper utilization have... 相似文献
9.
Nagavarapu Sarat Chandra Vachhani Leena Sinha Arpita Buriuly Somnath 《International Journal of Control, Automation and Systems》2021,19(1):491-504
International Journal of Control, Automation and Systems - The system of multiple agents working in coordination for a given task has several advantages on faster completion, fault-tolerance, etc.... 相似文献
10.