Adsorption behavior of Cu2+ and UO ions on crosslinked poly[2,2-bis(acrylamido)acetic acid]

The synthesis of a water-insoluble metal ion complexing resin was carried out by radical polymerization of 2,2-bis(acrylamido) acetic acid. The resin was characterized by elemental analyses, FTIR spectroscopy, and thermal analyses. The ability to bind copper(II), iron(II), iron(III), and uranium(VI) as well as the elution of the metal ions from the loaded resins were studied. For uranyl ions, pH 5 was the optimum sorption pH value. Sorption selectivity from the binary mixture Cu(II) + U(VI) was studied at pH 2. The thermal stability is increased by adsorption of UO. According to these results a coordination mechanism is suggested for sorption of copper and uranium. © 1995 John Wiley & Sons, Inc.     

Modified poly(ethyleneimine) supports for vanadium,molybdenum, and rhenium removal

Summary The solution behaviour of the polycarboxylic acid derived from scleroglucan (sclerox) has been investigated as a function of NaOH concentration and temperature by means of polarimetry and viscosimetry techniques. In comparison to the native polymer, sclerox is less sensitive to degradation at high NaOH concentration (up to NaOH equal to 0.4 M) and thermally more stable. The viscosity data show a normal polyelectrolyte effect and the polymer chains seem to be not stiff. We conclude that at high pH sclerox chains are in a flexible, probably single stranded conformation.     

An electronic throttle control strategy including compensation of friction and limp-home effects

An electronic throttle is a low-power dc servo drive which positions the throttle plate. Its application in modern automotive engines leads to improvements in vehicle drivability, fuel economy, and emissions. Transmission friction and the return spring limp-home nonlinearity significantly affect the electronic throttle performance. The influence of these effects is analyzed by means of computer simulations, experiments, and analytical calculations. A dynamic friction model is developed in order to adequately capture the experimentally observed characteristics of the presliding-displacement and breakaway effects. The linear part of electronic throttle process model is also analyzed and experimentally identified. A nonlinear control strategy is proposed, consisting of a proportional-integral-derivative (PID) controller and a feedback compensator for friction and limp-home effects. The PID controller parameters are analytically optimized according to the damping optimum criterion. The proposed control strategy is verified by computer simulations and experiments.     

Analysis of switched quantizer based on the quadratic spline functions

In this paper, an approximation of the optimal compressor function using the quadratic spline functions with 2L?=?8 segments is described. Since the quadratic spline with 2L?=?8 segments provides better approximation of the optimal compression function than quadratic spline with 2L?=?4 segments, capitalizing on the benefits of the obtained spline approximation, quantizer designing process is firstly performed for the so assumed number of segments and the Laplacian source of a unit variance. Then, to enhance the usability of the proposed model, the switched quantization technique is applied and a beneficial analysis is derived, providing insight in the robustness of the proposed quantizer performances with respect to the mismatch in designed for and applied to variances. Reached quality has been compared to another model from the literature, and it has been shown that the proposed model outperforms the previous model by almost 1.3?dB.     

Study of progesterone and cortisol concentrations in the Italian Friesian claw

The present research was conducted to study progesterone and cortisol concentrations in the claw of cattle and to verify whether the cattle claw could be considered an efficient matrix to provide retrospective information regarding progesterone and cortisol concentrations related to pregnancy and peripartum periods. These 2 steroids are involved in hoof growth. The study was performed on 32 calves and 24 pregnant milking cows of the Holstein breed, which were clinically healthy and lacking any claw disorders. Samples of at least 0.5 cm in thickness were taken from the sole. Progesterone and cortisol concentrations were determined by RIA. The cortisol concentration in the horny shoe of calves from 0 to 30 d of age was significantly higher than the concentration at 31 to 60 and 61 to 120 d of age. Conversely, the progesterone concentration showed no statistically significant difference in relation to age. The horn progesterone concentrations recorded in the milking dairy cows at 7 mo of pregnancy showed high variability in the horizontal sections of the sole (the individual coefficient of variation ranged between 0.09 and 1.11). In 6 cows, genuine extreme values (genuine outliers) of the progesterone level were found. Moreover, significant differences existed among the progesterone concentrations of the sole's transverse sections. We detected a significant positive correlation between the weight of the horn samples after freeze-drying and their weight after hydration. The cortisol and progesterone levels in soaked horn samples were found to be significantly lower than in the same dry samples. These results show that cortisol and progesterone can be measured in the cattle claw horn. The claws of mature dairy cows could not be used as a matrix to provide a retrospective measure of cumulative hormone secretion, whereas the analysis of the calves’ claw horns showed retrospective hormonal information similar to hair samples.     

Studies on the dechlorination and detoxificaton of organochlorine compounds. I. PCBs and PCNs

In the analysis of organochlorines such as polychlorinated biphenyls (PCBs) and polychlorinated naphthalenes (PCNs), levels of, for example, PCB concentration are often expressed as a ‘total PCB’ value, using a straight GC pattern-matching technique with electron capture detection. Such methods provide little information about the identity of the individual components. In the present study, preliminary investigations using dechlorination with a NiCl₂/NaBH₄ catalyst indicated that the technique offered a comprehensive method for the analysis of PCBs and PCNs, as well as a method of detoxification of the ‘priority pollutants’ . This paper reports the use of capillary column GC-MS with an ion trap detector (ITD^TM) for the analysis of a number of PCBs and PCNs, including the commercially produced Aroclor 1254 and 1221, employing this dechlorination technique.     

Counting and Integrating Readout for Direct Conversion X-ray Imaging: Concept, Realization and First Prototype Measurements

A novel signal processing concept for X-ray imaging with directly converting pixelated semiconductor sensors is presented. The novelty of this approach compared to existing concepts is the combination of charge integration and photon counting in every single pixel. Simultaneous operation of both signal processing chains extends the dynamic range beyond the limits of the individual schemes and allows determination of the mean photon energy. Medical applications such as X-ray computed tomography can benefit from this additional spectral information through improved contrast and the ability to determine the hardening of the tube spectrum due to attenuation by the scanned object. A prototype chip in 0.35-micrometer technology has been successfully tested. The pixel electronics are designed using a low-swing differential current mode logic. Key element is a configurable feedback circuit for the charge sensitive amplifier which provides continuous reset, leakage current compensation and replicates the input signal for the integrator. This paper will discuss measurement results of the prototype structures and give details on the circuit design     

Effects of international collaboration and status of journal on impact of papers

This study examines the effect of international collaboration of Slovenian authors and the status of journals where papers are published (as determined by their impact factors) on the impact of papers as measured by the number of citations papers receive. Research programme groups working in Slovenia in the 2004–2008 period in the fields of physics, chemistry, biology, biotechnology, and medical science were used for analyses. The results of the analyses show that the effects of the two factors differ among the fields. We discuss possible reasons for this, including the possibility that differences are the result of Slovenia’s science policy.     

Performance of energy-aware and link-adaptive routing metrics for ultra wideband sensor networks

Wireless sensor networks are energy constrained since sensors operate with limited battery capacity. Thus, energy consumption is one of the most critical issues in the design of routing protocols. In addition, the link quality needs to be taken into account in the route decision for a wireless multihop network in order to efficiently exploit the inherent spatial diversity. In this paper we consider energy-aware and link-adaptive routing strategies for UWB (Ultra Wide Band) sensor networks. We utilize the ranging capabilities offered by UWB and employ adaptive modulation to take advantage of favorable link conditions. Different routing metrics are proposed based on the availability of sensor node’s location, link quality and next hop battery capacity information. These routing metrics integrate the measure of next hop remaining battery capacity with the throughput performance measures, Maximum Forward Progress (MFP) or Maximum Information Progress (MIP). The effectiveness of these metrics is evaluated in different simulation scenarios in terms of network throughput and lifetime for both random and grid sensor network topologies. Jinghao Xuis a D.Sc. candidate of the Department of Electrical and Computer Engineering at the George Washington University. He received his B.Sc. and M.S. degrees in telecommunication and electrical engineering from the Tianjin University, China, in 1993 and 1996, respectively. From 1996 to 2001, he was with Research Institute of Telecommunication Transmission of Ministry of Information Industry, Beijing, China, and China Wireless Telecommunication Standards group, where he was involved in the standardization of IMT-2000 communication systems for China. His research interests include performance evaluation and modeling of wireless ad hoc networks, Ultra Wide Band systems and multiuser detection techniques. Bojan M. Peric received the B.S. degree in electrical engineering from the University of Belgrade, Belgrade, Serbia and Montenegro in 2001. He is currently working toward the D.Sc. degree in electrical engineering at the George Washington University, Washington, DC. His research interests include wireless communications, with an emphasis on ad hoc networks. Branimir R. Vojcic is a professor in, and a past Chairman of, the Department of Electrical and Computer Engineering at the George Washington University. He has received his Dipl. Ing., M.Sc. and D.Sc. degrees from the University of Belgrade in Serbia and Montenegro in 1980, 1986 and 1989, respectively. His current research interests are in the areas of communication theory, performance evaluation and modeling mobile and wireless networks, mobile internet, code division multiple access, multiuser detection, adaptive antenna arrays, space-time coding and ad-hoc networks. He has also been an industry consultant and has published and lectured extensively in these areas. He co-authored the book: The cdma2000 System for Mobile Communications. Dr Vojcic received NSF CAREER Award in 1995. He is a Senior Member of IEEE, was an Associate Editor for IEEE Communications Letters and is presently an Associate Editor for Journal on Communications and Networks.