全文获取类型
收费全文 | 235篇 |
免费 | 14篇 |
专业分类
电工技术 | 3篇 |
化学工业 | 87篇 |
金属工艺 | 1篇 |
机械仪表 | 5篇 |
建筑科学 | 1篇 |
能源动力 | 22篇 |
轻工业 | 13篇 |
水利工程 | 7篇 |
石油天然气 | 4篇 |
无线电 | 8篇 |
一般工业技术 | 67篇 |
冶金工业 | 11篇 |
原子能技术 | 2篇 |
自动化技术 | 18篇 |
出版年
2023年 | 4篇 |
2022年 | 4篇 |
2021年 | 12篇 |
2020年 | 7篇 |
2019年 | 14篇 |
2018年 | 8篇 |
2017年 | 7篇 |
2016年 | 13篇 |
2015年 | 10篇 |
2014年 | 15篇 |
2013年 | 21篇 |
2012年 | 10篇 |
2011年 | 16篇 |
2010年 | 9篇 |
2009年 | 5篇 |
2008年 | 16篇 |
2007年 | 14篇 |
2006年 | 4篇 |
2005年 | 7篇 |
2004年 | 4篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有249条查询结果,搜索用时 15 毫秒
1.
The enzymatic degradability of poly(vinyl acetate) was investigated in toluene solutions at various temperatures with hog pancreas lipase. The polymer degraded by specific scission to yield oligomeric products with a molecular weight of 700. Continuous distribution kinetics were used to determine the rate coefficients. The variation of the rate coefficients with the temperature indicated an optimum at 55°C. The p‐toluene sulfonic acid catalyzed degradation of poly(vinyl acetate) was also investigated. The degradation mechanism was random chain scission, and the energy of activation for degradation was determined from the variation of the rate coefficients with the temperature. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2579–2582, 2003 相似文献
2.
In order to minimize the impact of secret signing key exposure in attribute-based signature scenario, we construct an attribute-based key-insulated signature (ABKIS) scheme for expressive monotone boolean function access structures utilizing only four pairing operations in verification process and making the signature length constant, that is, the number of pairings required for signature verification and the size of signature are independent of the size of attribute set participated in the respective process. The (strong) key-insulated selective security of our ABKIS scheme is reduced to the computational Diffie–Hellman Exponent problem without using any random oracles. The proposed construction attains signer privacy, which is a fundamental requirement of the signature schemes in the attribute-based setting. 相似文献
3.
Hemendra Patle Ravikumar Dumpala B. Ratna Sunil 《Transactions of the Indian Institute of Metals》2018,71(4):951-959
In the present study, influence of friction stir processing (FSP) tool pin profile on the microstructure evolution, corrosion and machining characteristics of the AZ91 magnesium alloy was investigated. Three different pin profiles namely simple taper, threaded taper and square taper were selected and FSP was carried out at 1400 rpm and 25 mm/min tool travel speed. Microstructural observations indicated grain refinement from a starting grain size of 166.5–7.9, 22.1 and 4.08 µm for FSPed samples processed by simple taper, threaded taper and square taper pins, respectively. In all the FSPed samples, decreased amount of secondary phase (Mg17Al12) was observed compared with that of the unprocessed sample. From the X-ray diffraction analysis, it was observed that the square taper pin tool had induced higher texture effect compared with the other two FSP tools. From the electrochemical studies, the corrosion resistance of the sample processed with square taper pin tool was observed to be more in comparison to that of the other samples; which could be attributed to the texture effect and decreased fraction of secondary phase. Machining behavior assessed by conducting drilling experiments showed a significant influence of grain refinement on the cutting forces. 相似文献
4.
H. R. Williams R. M. Ambrosi N. P. Bannister P. Samara‐Ratna J. Sykes 《国际能源研究杂志》2012,36(12):1192-1200
Spacecraft venturing to the outer planets and beyond—or onto the planetary surface where available solar energy is reduced—benefit from the longevity and consistency of electrical and thermal energy derived from radioisotope energy sources. A review of likely mission requirements and concept studies of small electrical generating units (<10 We) reveals a potential opportunity for a unit with an electrical output of around 1 We that can also supply some heat to the spacecraft to aid thermal control: a radioisotope thermoelectric and heating unit. This power requirement cannot be achieved with current US space‐qualified modular radioisotope fuel assemblies. Additionally, new European programmes consider 241Am fuel to be much more cost effective than 238Pu. Taken together, these factors provide the rationale for taking a relatively ‘clean‐sheet’ approach to design of a radioisotope thermoelectric and heating unit fuelled with 241Am. In this paper, initial requirements and performance targets for such a unit are developed, a simple concept design and thermal model is presented and the performance and mass are estimated. The results suggest that units generating 1–2 We may achieve a specific power of around 0.7–0.9 We kg?1 without the thermal inputs to spacecraft becoming impractically large. Such units can use a bismuth telluride thermoelectric material, which is commercially applied in terrestrial applications and is therefore likely to incur lower cost and development risk than more specialised compounds. This study may form the basis of a more detailed design effort. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
5.
6.
One of the ways by which grease is evaluated is by using a four‐ball wear test using ASTM D2266. However, actual applications may require bearings to be subjected to spectrum loading conditions. This study focuses on using ball milling to mitigate the wear from sharp edges in the MoS2 particles. Two different blends of greases were formulated using MoS2 in the as‐received state (unmilled) and milled MoS2; they were tested under spectrum loading conditions where the load and frequency of the tests were treated as variables. It was found that ball milling of the MoS2 significantly reduces the wear under spectrum loading condition both for ramp‐up and ramp‐down conditions. It was also shown that shortening the time step for both the ramp‐up and ramp‐down cycles resulted in larger wear for unmilled MoS2 particles in comparison with milled MoS2 particles in grease. The milling process did not play a significant role when frequency of the test was either ramped up or down. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
7.
Morphology‐dependent electrocatalytic activity of nanostructured Pt/C particles from hybrid aerosol–colloid process 下载免费PDF全文
Ratna Balgis Aditya F. Arif Takahiro Mori Takashi Ogi Kikuo Okuyama Gopinathan M. Anilkumar 《American Institute of Chemical Engineers》2016,62(2):440-450
An optimum nanostructure and pore size of catalyst supports is very important in achieving high catalytic performances. In this instance, we evaluated the effects of various carbon nanostructures on the catalytic performances of carbon‐supported platinum (Pt/C) electrocatalysts experimentally and numerically. The Pt/C catalysts were prepared using a hybrid method involving the preparation of dense, hollow, and porous nanostructured carbon particle via aerosol spray pyrolysis followed by microwave‐assisted Pt deposition. Electrochemical characterization of the catalysts showed that the porous Pt/C catalyst gave the best performance; its electrochemical surface area was much higher, more than twice than those of hollow or dense Pt/C. The effects of pore size on electrocatalysis were also studied. The results showed the importance of a balance between mesopores and macropores for effective catalysis with a high charge transfer rate. A fluid flow model showed that good oxygen transport contributed to the catalytic activity. © 2015 American Institute of Chemical Engineers AIChE J, 62: 440–450, 2016 相似文献
8.
Poly(ethylene oxide) (PEO)/clay nanocomposites were prepared by a solution intercalation method using chloroform as a solvent. The nanocomposites were characterised by X-ray diffraction (XRD), differential scanning calorimetry (DSC), hot-stage polarized optical microscopy (POM), Fourier transform infrared spectroscopy (FT-IR), tensile analysis, dynamic mechanical analysis (DMA) characterisation techniques. Formation of nanocomposite was confirmed by X-ray diffraction (XRD) analysis. A decrease in PEO crystallinity in case of nanocomposite, was confirmed by a decrease in the heat of melting and spherulite size as indicated by DSC and POM studies, respectively. Improvement in tensile properties in all respect was observed for nanocomposites with optimum clay content (12.5 wt%). DMA studies indicate an increase in loss peak temperature and broadening of loss peak as a result of clay intercalation. 相似文献
9.
BACKGROUND: Much of the current research related to the development of in situ nanocomposites of olefins by polymerizing them with metallocenes in the presence of surface‐treated fillers is carried out in the slurry phase. In slurry‐phase methods a large amount of solvent is required and there is always a need of purification of the final product due to the possibility of traces of solvents present in the product. To overcome these drawbacks, to perform solvent‐free metallocene‐catalysed polymerizations with in situ incorporation of inorganic nanoparticles, we have used a gas‐phase polymerization technique as this does not require solvents and also utilizes monomer feed stocks efficiently. RESULTS: The catalyst used for the synthesis of in situ polyethylene nanocomposites by gas‐phase polymerization was nanosilica‐supported zirconocene. The fillers used were Cloisite‐20A, kaolin and nanosilica. Three different in situ polyethylene nanocomposites, i.e. Cloisite‐20A‐filled polyethylene (CFPE), kaolin‐filled polyethylene (KFPE) and nanosilica‐filled polyethylene (SFPE), were prepared by gas‐phase polymerization. The nanocomposites were obtained in the form of fine powder. The polyethylene content in the developed nanocomposites is in the orthorhombic crystalline phase. Using our approach, it is observed that the nanofillers are completely encapsulated by a thin layer of polyethylene. Significantly higher molecular weight polyethylene was formed in the case of KFPE in comparison to CFPE and SFPE. The thermal decomposition temperature, melting temperature and enthalpy are also observed to be higher for KFPE. CONCLUSIONS: The gas‐phase polymerization technique has been successfully carried out for the synthesis of in situ polyethylene nanocomposites. Copyright © 2007 Society of Chemical Industry 相似文献
10.
Samar J. Kalita Robert Fleming Himesh Bhatt Brian Schanen Ratna Chakrabarti 《Materials science & engineering. C, Materials for biological applications》2008,28(3):392-398
Controlling the strength-loss rate during biodegradation is a bottleneck in developing viable resorbable ceramic implants. Resorbable beta-tricalcium phosphate (β-TCP) bioceramic is known for its excellent biocompatibility. However, it exhibits poor sinterability and poor flexural strength. Here, we improved sintering behavior and biaxial flexural strength of β-TCP bioceramic without altering its biocompatibility by introducing multi-oxide sintering additives, in small quantities. These additives could also tailor the rate of resorption and hardness deterioration of β-TCP. A range of additives were prepared and introduced into β-TCP powder. Resultant powders were uniaxially pressed and sintered at 1250 °C, in air. Considerable improvement in densification (up to 33%) and biaxial flexural strength (up to 43%) were achieved. X-ray powder diffraction (XRD) analysis confirmed that the additives didn't alter the phase purity. In vitro cytotoxicity and biocompatibility analyses were performed using a prostate cancer cell-line. Results showed that the doped and pure β-TCP structures were non-toxic and biocompatible. 相似文献