Effects of Light, Oxygen, and pH on the Absorbance of 2,2-Diphenyl-1-picrylhydrazyl

ABSTRACT: The absorbance of 2,2-diphenyl-1-picrylhydrazyl (DPPH) at 517 nm in methanol and acetone decreased by 20 and 35% for 120 min at 25 °C under light, respectively; in the dark it did not change significantly for 150 min. Decomposition of DPPH under 21% oxygen after 90 min under light was significantly higher than that under 1% oxygen. Absorbance of DPPH in pH 4 buffer solution in methanol, and in pH 10 buffer solution in acetone, decreased by 55 and 80%, respectively, under light for 120 min. The evaluation of antioxidant activity by the changes of DPPH absorbance should be carefully interpreted since the absorbance of DPPH at 517 nm is decreased by light, oxygen, pH, and type of solvent in addition to the antioxidant.     

Comparison of Two Drying Schedules for European Hophornbeam (Ostrya carpinifolia Scop.) Lumber

Two types of conventional kiln-drying schedules (mild and harsh) based on moisture content (MC) were compared with regard to time, drying quality, and energy cost. The results were evaluated according to the classification of the European Drying Group. Proper drying periods of mild and harsh schedules were found to be 550 and 514 h, respectively. Evaluations in terms of drying quality indicated that better results were achieved with the mild schedule, especially when comparing drying defects and final MC. From an energy efficiency point of view, the harsh schedule, by saving 36 h of drying time, reduced electricity by 594 KWh and was therefore found to be $65 more profitable in this trial.     

The statistical modeling of surface roughness in high-speed flat end milling

Surface roughness is one of the most important requirements in machining process. The surface roughness value is a result of the tool wear. When tool wear increase, the surface roughness also increases. The determination of the sufficient cutting parameters is a very important process obtained by means of both minimum surface roughness values and long tool life. The statistical models were developed to predict the surface roughness.This paper presents the development of a statistical model for surface roughness estimation in a high-speed flat end milling process under wet cutting conditions, using machining variables such as spindle speed, feed rate, depth of cut, and step over. First- and second-order models were developed using experimental results of a rotatable central composite design, and assessed by means of various statistical tests. The highest coefficient of correlation (R_adj²) (88%) was obtained with a 10-parameter second-order model. Meanwhile, a time trend was observed in residual values between model predictions and experimental data, reflecting the probable effect of the tool wear on surface roughness. Thus, in order to enhance the estimation capability of the model, another independent variable was included into the model to account for the effect of the tool wear, and the total operating time of the tool was selected as the most suitable variable for this purpose. By inserting this new variable as a linear term into the model, R_adj² was increased to 94% and a good fit was observed between the model predictions and supplementary experimental data.In this study, it was observed that, the order of significance of the main variables is as X₅>X₃>X₄>X₁>X₂ (total machining time, depth of cut, step over, spindle speed and feed rate, respectively).     

Influence of the cross‐sectional shape on the structure and properties of polyester fibers

The effects of the fiber cross‐sectional shape on the structure and properties of polyester fibers were investigated. Fully drawn yarn (FDY) polyester fibers (167 dtex and 48 filaments) were produced under the same spinning conditions used in a spinning plant. The only difference between the fibers was their cross‐sectional shapes. Four different cross‐sectional shapes were chosen for the experimental work: round, hollow‐round, trilobal, and hollow‐trilobal. The crystallinity and values of the maximum stress, maximum strain, modulus, yield stress, shrinkage in boiling water, and unevenness of the fibers were determined. The difference in the cross‐sectional shapes influenced the modulus, maximum strain, yield stress, and shrinkage in boiling water. No effects on the crystallinity and maximum stress were observed. The results suggested that the hollow fibers had higher amorphous orientation than the full fibers. The hollow‐round fiber had the highest unevenness value. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2615–2621, 2007     

Fusion of smartphone sensor data for classification of daily user activities

Multimedia Tools and Applications - New mobile applications need to estimate user activities by using sensor data provided by smart wearable devices and deliver context-aware solutions to users...     

Micro-milling performance of AISI 304 stainless steel using Taguchi method and fuzzy logic modelling

In this study, micro-milling of AISI 304 stainless steel with ball nose end mill was conducted using Taguchi method. The influences of spindle speed, feed rate and depth of cut on tool wear, cutting forces and surface roughness were examined. Taguchi’s signal to noise ratio was utilized to optimize the output responses. The influence of control parameters on output responses was determined by analysis of variance. In this study, the models describing the relationship between the independent variables and the dependent variables were also established by using regression and fuzzy logic. Efficiency of both models was determined by analyzing correlation coefficients and by comparing with experimental values. The results showed that both regression and fuzzy logic modelling could be efficiently utilized for the prediction of tool wear, cutting forces and surface roughness in micro-milling of AISI 304 stainless steel.     

Energy- and reliability-aware task scheduling onto heterogeneous MPSoC architectures

Scheduling periodic tasks onto a multiprocessor architecture under several constraints such as performance, cost, energy, and reliability is a major challenge in embedded systems. In this paper, we present an Integer Linear Programming (ILP) based framework that maps a given task set onto an Heterogeneous Multiprocessor System-on-Chip (HMPSoC) architecture. Our framework can be used with several objective functions; minimizing energy consumption, minimizing cost (i.e., the number of heterogeneous processors), and maximizing reliability of the system under performance constraints. We use Dynamic Voltage Scaling (DVS) for reducing energy consumption while we employ task duplication to maximize reliability. We illustrate the effectiveness of our approach through several experiments, each with a different number of tasks to be scheduled. We also propose two heuristics based on Earliest Deadline First (EDF) algorithm for minimizing energy under performance and cost constraints. Our experiments on generated task sets show that ILP-based method reduces the energy consumption up to 62% percent against a method that does not apply DVS. Heuristic methods obtain promising results when compared to optimal results generated by our ILP-based method.     

Experimental and numerical studies on the determination of twist drill temperature in dry drilling: A new approach

In this paper, the influences of the spindle speed and feed rate on the drill temperature responses have been investigated. A new experimental approach was developed to measure drill temperature in drilling process. Drill temperatures were measured by inserting standard thermocouples through the coolant (oil) hole of TiAlN-coated carbide drills. Experimental parameters used in the study has based on Taguchi’s method. Experimental study was conducted by using two different workpiece materials, AISI 1040 steel and Al 7075-T651. The drill bit temperature was predicted using a numerical calculation with Third Wave AdvantEdge^TM Lagrangian based on explicit finite element analysis software. The results obtained from experimental study and finite element analyses (FEA) were compared. Good agreement between the measured and analyzed temperature results was found in dry drilling process.     

A stochastic MIMO channel model with joint correlation of both link ends

Abstract-This paper presents a novel stochastic channel model for multiple-input multiple-output (MIMO) wireless radio channels. In contrast to state-of-the-art stochastic MIMO channel models, the spatial correlation properties of the channel are not divided into separate contributions from transmitter and receiver. Instead, the joint correlation properties are modeled by describing the average coupling between the eigenmodes of the two link ends. The necessary and sufficient condition for the proposed model to hold is that the eigenbasis at the receiver is independent of the transmit weights, and vice versa. The authors discuss the mathematical elements of the model, which can be easily extracted from measurements, from a radio propagation point of view and explain the underlying assumption of the model in physical terms. The validation of the proposed model by means of measured data obtained from two completely different measurement campaigns reveals its ability to better predict capacity and spatial channel structure than other popular stochastic channel models.     

Dynamic soil–structure interaction analysis of layered unbounded media via a coupled finite element/boundary element/scaled boundary finite element model

In this paper, a coupled model based on finite element method (FEM), boundary element method (BEM) and scaled boundary FEM (SBFEM) (also referred to as the consistent infinitesimal finite element cell method) for dynamic response of 2D structures resting on layered soil media is presented. The SBFEM proposed by Wolf and Song (Finite‐element Modelling of Unbounded Media. Wiley: England, 1996) and BEM are used for modelling the dynamic response of the unbounded media (far‐field). The standard FEM is used for modelling the finite region (near‐field) and the structure. In SBFEM, which is a semi‐analytical technique, the radiation condition at infinity is satisfied exactly without requiring the fundamental solution. This method, also eliminates the need for the discretization of interfaces between different layers. In both SBFEM and BEM, the spatial dimension is decreased by one. The objective of the development of this coupled model is to combine advantages of above‐mentioned three numerical models to solve various soil–structure interaction (SSI) problems efficiently and effectively. These three methods are coupled (FE–BE–SBFEM) via substructuring method, and a computer programme is developed for the harmonic analyses of SSI systems. The coupled model is established in such a way that, depending upon the problem and far‐field properties, one can choose BEM and/or SBFEM in modelling related far‐field region(s). Thus, BEM and/or SBFEM can be used efficiently in modelling the far‐field. The proposed model is applied to investigate dynamic response of rigid and elastic structures resting on layered soil media. To assess the proposed SSI model, several problems existing in the literature are chosen and analysed. The results of the proposed model agree with the results presented in the literature for the chosen problems. The advantages of the model are demonstrated through these comparisons. Copyright © 2004 John Wiley & Sons, Ltd.