A small (1 L) batch stirred cell system has been developed to study crude oil fouling at surface temperatures up to 400°C and pressures up to 30 bar. Fouling resistance–time data are obtained from experiments in which the principal operating variables are surface shear stress, surface temperature, heat flux, and crude oil type. The oils and deposits are characterized and correlated with the experimental heat transfer fouling data to understand better the effects of process conditions such as surface temperature and surface shear stress on the fouling process. Deposits are subjected to a range of qualitative and quantitative analyses in order to gain a better insight into the crude oil fouling phenomenon. Thermal data that can be obtained relatively quickly from the batch cell provide fouling rates, Arrhenius plots, and apparent activation energies as a function of process variables. The experimental system, supported by computational fluid dynamics (CFD) studies, allows fouling threshold conditions of surface temperature and shear stress to be identified relatively quickly in the laboratory. The data also contribute to existing knowledge about the compensation plot. 相似文献
Natural dyes extracted from fruits, vegetables, flowers, and leaves are considered as promising alternative sensitizers to replace synthetic dyes for dye‐sensitized solar cells (DSSCs). Generally, solar activity of natural dyes stem from anthocyanin pigment. Carbonyl, carboxyl, and hydroxyl groups present in the anthocyanin molecule improve the adsorption ability of dye on TiO2 and therefore facilitate charge transfer. Here, for the first time, novel natural dyes extracted from St. Lucie cherry, yellow jasmine, and madder berries are reported to act as sensitizer in DSSCs. These novel natural dye extracts are prepared by dissolving related fruits in ethanol. The ingredient of the dyes is identified by FT‐IR spectroscopy. Accordingly, FT‐IR spectrum reveals that novel natural dye extracts exhibit all the characteristic peaks of anthocyanin pigment. Specifically, St. Lucie cherry consists of more distinct carbonyl group than other sources. Also, photoanodes composed of three TiO2 layers are prepared by using a spin‐coating method. Then, they are immersed into natural dyes and analyzed by conducting UV‐Vis spectroscopy. Compared with bare TiO2, natural dye–loaded photoanodes demonstrate far higher absorption ability in the visible region. After fabrication of devices with different novel natural dye sensitizers, current‐voltage characteristics and electrochemical impedance spectroscopy measurements are performed. The best power conversion efficiency (PCE) of 0.19% is obtained by sensitization of St. Lucie cherry with an open‐circuit voltage (Voc) of 0.56 V, short‐circuit current density (Jsc) of 181 μA cm?2, and fill factor (FF) of 0.55. Furthermore, St. Lucie cherry–sensitized devices show the lowest charge transfer and highest recombination resistances. This result can be attributed to the obvious carbonyl group exhibited by St. Lucie cherry. 相似文献
Developing chemically inert, electrically conductive, and catalytically active counter electrodes (CEs) to replace conventional Pt-based ones is highly desirable for dye-sensitized solar cells. Herein, we reported a facile, cost-effective, and low-temperature synthesis pathway to develop carbon-based CEs. The performance of homemade carbon paste (H-CP)–based CE (H-CE) was compared with that of commercial carbon paste (C-CP)–based CE (C-CE) and Pt-based CE (Pt-CE). The scanning electron microscope (SEM) results showed that H-CE demonstrated a penetrable surface structure which facilitates the diffusion of electrolyte through the carbon electrode. This phenomenon enhanced the triiodide reduction with respect to C-CE having a compact structure that limits the electrolyte diffusion. The charge transfer properties and catalytic activities of the investigated devices were explored using electrochemical impedance spectroscopy and Tafel polarization measurements; the obtained results indicated that the device based on H-CE revealed relatively lower charge transfer resistance and higher exchange current density compared with C-CE-based device. The current-voltage measurements showed that the device based on H-CE has a power conversion efficiency of 2.70%, which was about 1.6 times higher than that of the device based on C-CE (1.68%). Furthermore, a fill factor of 73% was achieved for the device based on H-CE, which outperformed the Pt-based device (69%) and was among one of the highest values obtained in the literature. Also, a tape adhesion test performed on H-CP-coated glass substrate displayed its excellent robustness. 相似文献
A new parallel implementation of Strassen’s matrix multiplication algorithm is proposed for massively parallel supercomputers with 2D, all-port torus interconnection networks. The proposed algorithm employs a special conflict-free routing pattern for better scalability and is able to yield a performance rate very close to the theoretical bound for many practical network and matrix sizes. It effectively scales up to very large networks typically containing hundreds-of-thousands processors where petaflop or exaflop processing rates are sought. 相似文献
As social networks are getting more and more popular day by day, large numbers of users becoming constantly active social network users. In this way, there is a huge amount of data produced by users in social networks. While social networking sites and dynamic applications of these sites are actively used by people, social network analysis is also receiving an increasing interest. Moreover, semantic understanding of text, image, and video shared in a social network has been a significant topic in the network analysis research. To the best of the author's knowledge, there has not been any comprehensive survey of social networks, including semantic analysis. In this survey, we have reviewed over 200 contributions in the field, most of which appeared in recent years. This paper not only aims to provide a comprehensive survey of the research and application of social network analysis based on semantic analysis but also summarizes the state‐of‐the‐art techniques for analyzing social media data. First of all, in this paper, social networks, basic concepts, and components related to social network analysis were examined. Second, semantic analysis methods for text, image, and video in social networks are explained, and various studies about these topics are examined in the literature. Then, the emerging approaches in social network analysis research, especially in semantic social network analysis, are discussed. Finally, the trending topics and applications for future directions of the research are emphasized; the information on what kind of studies may be realized in this area is given. 相似文献
Collective Communication Algorithms for 2D torus networks have been investigated quite extensively in the literature and two
broad approaches, namely direct methods and indirect (message combining) methods are recognized in the field. While direct methods minimize the volume of data, the indirect methods
reduce the number of message start-ups. Consequently, either a suite of algorithms must be employed for efficiency over a
wide range of message lengths and communication operations or algorithms should be able to adapt themselves to the current
case, possibly by switching between direct and indirect routing modes as appropriate. In this paper, we propose adaptive routing
algorithms for all-port, wormhole routed, synchronous, 2D torus networks optimized for one-to-all broadcast, gossiping and complete exchange collective communication operations. The proposed algorithms employ completely-connected subnetworks where complete exchange
amongst the nodes in the subnetwork can be accomplished in one step only. Combined with suitable 2D plane tiling techniques,
the proposed algorithms share the same set of primitive operations and yield superior performance compared to previously proposed
methods, either pure or hybridized. 相似文献
The use of biodiesel-blended fuels in diesel engines improves the engine performance parameters and the partial recovery of incomplete combustion products, while also increasing the level of NOx emissions. In this study; biodiesel obtained through the transesterification of waste chicken frying oil was mixed with diesel fuel (90% diesel + 10% biodiesel-B10), and was then used as fuel in a direct injection diesel engine. To reduce the increased NOx emissions caused by the use of B10 fuel, the steam injection method (which is one of the NOx reduction methods) was applied. Steam was injected into the intake manifold at different ratios (5%-S5, 10%-S10 and 15%-S15) and at the time of the induction stroke with the aid of an electronically controlled system. Based on the study results, it was observed that steam injection into the engine using B10 fuel improved both the engine performance and the exhaust emission parameters. It was determined that the S15 steam injection ratio resulted in the best engine performance and emissions parameters. In comparison to STD fuel; the highest increase observed at the S15 steam injection ratio in the effective engine power was 2.2%, while the highest decrease in the specific fuel consumption was 3.4%, the highest increase in the effective efficiency was 3.5%, and the highest decrease in NOx emissions was 13.7%.
The bonding of resin cement to ceramic materials plays an important role in dentistry. The purpose of this study is to evaluate the effects of various surface treatments on the shear bond strength (SBS) of zirconia ceramic and metal alloy. A total of 60 specimens were prepared from Y-TZP ceramic and metal alloy. The specimens were divided into three subgroups (n = 10) that received different surface treatments for each material. An Er:YAG laser (ER), a femtosecond laser (FS), and air-borne particle abrasion (A) were employed as surface treatments. One specimen from each group was analyzed using a scanning electron microscope (SEM) at 500 x magnification after surface treatments. The self-adhesive resin cement was then bonded to the treated surfaces using a Teflon mold. The specimens were thermocycled for 5,000 cycles at 5–55 °C, and then the SBS test was performed. Kruskal–Wallis and Mann–Whitney U tests were used to determine the differences between the groups (p = 0.05), and failure modes were evaluated for each specimen. Statistical analyses revealed significant differences between the surface treatment methods. The mean SBS values of the air-borne particle-abraded groups were higher than those of the other groups. The femtosecond-irradiated groups of each material showed significantly higher SBS values than the Er:YAG-irradiated groups (p < 0.05). Within the limitations of this study, air-borne particle abrasion and the femtosecond laser were more effective than Er:YAG laser treatment. 相似文献