Mechanism of simultaneous solutes separation and concentration by size exclusion cyclic separation

The semicontinuous separation/concentration of two solutes with different molecular size by the size exclusion cyclic separation method is based on the opposite swelling responses of two gels to a temperature change. Experimental results of separation and concentration of solutes are verified qualitatively by the theoretical models based on the local equilibrium assumption. Separation of two solutes is shown by the breakthrough curves in coupled gel columns. In closed coupled columns, the volumetric space for the large molecules which are totally excluded from the gels becomes smaller, creating a concentrating effect as the gels swell when temperature changes. A mechanistic model is suggested to predict the large molecule concentration to increase to its solubility limit as cycle repeats.     

Development and experimental evaluation of aerodynamic lens as an aerosol inlet of single particle mass spectrometry

This study described a development and an experimental evaluation of an efficient aerodynamic lens inlet of the single particle mass spectrometry. Several key designing parameters and systematic factors were investigated for the whole lens system through a full numerical simulation. From many tests for various designs of the system, we showed that Mach number was not an independent parameter but interrelated well with flow Reynolds numbers and pressures upstream of the orifices. By manipulating the parameters, we showed for the first time a possibility that there exist a universal correlation between optimal Stokes number and a new factor incorporating the other dimensionless variables and a design parameter. The universality was confirmed by the full simulation results. We demonstrated that the new design of the system was capable of focusing ultrafine aerosols in the size range of 30–700 nm. At two different operating conditions, the formations of sub-millimeter beams of 30–300 nm NaCl aerosols are verified by light scattering imaging as well as microprobe observation of deposited aerosol beams. Finally, the measured sizes of aerosol beams agree reasonably well with those from the simulations as a function of particle size.     

Effect of hydrogen on the impedance of passivating oxide films formed on aluminium in sodium nitrate solution

A.c. impedance has been determined at room temperature on hydrogen-free and hydrogen-charged passivating oxide films on aluminium in 0.05m Na₂SO₄ solution. Analysis of the impedance data enabled a clear distinction between the capacitance and inductance of the hydrogen-free oxide film and those of the hydrogen-charged oxide film to be made. The changes in capacitance and inductance by hydrogen-charging into the oxide films are discussed in relation to the compositional change from -Al₂O₃ to hydrated alumina.     

Mining top-k frequent patterns with combination reducing techniques

Top-k frequent pattern mining finds interesting patterns from the highest support to the k-th support. The approach can be effectively applied in numerous fields such as marketing, finance, bio-data analysis, and so on since it does not need constraints by a minimum support threshold. Top-k mining methods use the support of the k-th pattern, not a user-specified minimum support. Thus, the methods conduct mining operations based on very low supports until the k-th pattern is detected. When a low support is used in the mining process, single-paths with numerous items are generated, where the top-k mining algorithm extracts valid patterns by combining the items for each single-path. Therefore, the bigger the number of combinations is, the larger the increase in time and memory consumption is. In this paper, in order to mine top-k frequent patterns more efficiently, we consider converting patterns obtained from single-paths into composite patterns during the mining process and recovering them as the original patterns when the top-k frequent patterns are extracted. For this, we define a new concept, the composite pattern, and propose novel techniques for reducing pattern combinations in the single-path. Two algorithms are introduced in this paper, where the former is CRM (Combination Reducing method), applying our reduction manner, and the latter is CRMN (Combination Reducing method for N-itemset), considering N-itemset, i.e., patterns’ lengths. A performance evaluation shows that CRM and CRMN algorithms can efficiently reduce pattern combinations in single-paths compared to state-of-the-art algorithms. The experimental results also illustrate that our approaches have outstanding performance in terms of runtime, memory, and scalability.     

Ultrasonic spray pyrolysis of nano crystalline spinel LiMn2O4 showing good cycling performance in the 3 V range

Spherical lithium manganese oxide spinel was synthesized by an ultrasonic spray pyrolysis method, and has been characterized using X-ray diffraction, scanning electron microscopy, transimission electron microscopy and electrochemical cycling at 3 V regions. The LiMn₂O₄ powders were composed of about 10 nm-sized primary particles. The delivered discharge capacity of the synthesized nano-material was 125 mAh g⁻¹ between 2.4 and 3.5 V and its retention was about 96% upon 50 cycling. From the high resolution transmission electron microscopic study, it was found that structural transition of the parent material did not occur even after the 50th electrochemical cycling on the 3 V region. It seems that the reversible structural change is possible for nanocrystalline LiMn₂O₄ as observed by the X-ray diffraction and transition electron microscopic observations.     

Delay and link utilization aware routing protocol for wireless multimedia sensor networks

Wireless Multimedia Sensor Networks (WMSNs) consist of networks of interconnected devices involved in retrieving multimedia content, such as, video, audio, acoustic, and scalar data, from the environment. The goal of these networks is optimized delivery of multimedia content based on quality of service (QoS) parameters, such as delay, jitter and distortion. In multimedia communications each packet has strict playout deadlines, thus late arriving packets and lost packets are treated equally. It is a challenging task to guarantee soft delay deadlines along with energy minimization, in resource constrained, high data rate WMSNs. Conventional layered approach does not provide optimal solution for guaranteeing soft delay deadlines due to the large amount of overhead involved at each layer. Cross layer approach is fast gaining popularity, due to its ability to exploit the interdependence between different layers, to guarantee QoS constraints like latency, distortion, reliability, throughput and error rate. The paper presents a channel utilization and delay aware routing (CUDAR) protocol for WMSNs. This protocol is based on a cross-layer approach, which provides soft end-to-end delay guarantees along with efficient utilization of resources. Extensive simulation analysis of CUDAR shows that it provides better delay guarantees than existing protocols and consequently reduces jitter and distortion in WMSN communication.     

Simulation framework for small scale engagement

Developing future weapons systems has become increasingly complicated and costly. The armed forces of major nations use modeling and simulation techniques for new weapons systems from the conceptual stage to design, production, deployment and training stages to shorten the development cycle and guarantee their effectiveness. Failure in the development cycle carries too much loss in time and money. Therefore, computer-based modeling and simulation techniques are applied from the conceptual stage to gauge the efficacy of new weapons systems. The objective of this study is to develop a modeling and simulation methodology for small scale engagement using the DEVS formalism. The entities required for modeling and simulation are divided into three categories: combat, logical, and environmental entities. Combat entities represent the military hardware or combatants; logical entities represent the judgment and decision entities for the interaction between various entities; and environmental entities emulate the constituents of real combat environment. The combat entities are further modeled into Shell and Core Parts to maximize their reusability under various combat scenarios. The proposed framework is verified using a one-on-one combat engagement simulation (written in C++) between two submarines.     

Structure-activity relationships for analogs of (+)-(E)-endo-Β-bergamoten-12-oic acid,an oviposition stimulant ofHelicoverpa zea (Boddie)

-Bergamotenoic acid, a compound previously shown to stimulate oviposition inH. zea, was converted into a set of bicyclic analogs and tested with a set of acyclic side chain analogs to ascertain the molecular structure that maximizes insect behavioral response. While changes in the bicyclic ring elicited no variation in response, alteration in the side chain structure of-bergamotenoic acid resulted in significant changes in moth preference. Free rotation about the C-C bond proximal to the carboxylic acid group appears to be an important structural factor, since saturation of the side chain double bond significantly increased activity. The carboxylic acid group seems to be required for strong oviposition stimulation, since analogs lacking the carboxylic acid group exhibited no significant oviposition activity. Oviposition preference ofH. zea was also influenced by the length of the hydrocarbon chain to which the carboxylic acid is attached. While hexanoic acid was found inactive, the ovipositional preference for the heptanoic and octanoic acids was greatest for the one 8-carbon tested. This and other work suggest that carboxylic acids of specific chain lengths influence the oviposition behavior of bothHelicoverpa andHeliothis species and may be associated with host-plant selection. The potential use of this information in designing integrated pest management strategies for control ofH. zea is discussed.     

Electrically assisted stress relief annealing of automotive springs

Journal of Mechanical Science and Technology - In the present study, Electrically assisted (EA) stress relief annealing for automotive springs is experimentally investigated. A concept of EA stress...     

Arm length dependency of Pt-decorated CdSe tetrapods on the performance of photocatalytic hydrogen generation

Pt-decorated CdSe tetrapods with different arm lengths were tested for the photocatalytic hydrogen generation reaction. Well-defined CdSe tetrapods with controlled wurtzite arm lengths were synthesized by the continuous precursor injection (CPI) approach. Pt nanocrystals with an extremely small size of ～1 nm were directly decorated on the overall surfaces of CdSe tetrapods. Ligand-exchanged Pt-decorated CdSe tetrapods with different arm lengths were employed as photocatalysts for photocatalytic hydrogen generation reaction in the presence of hole scavengers. Pt-decorated CdSe tetrapods with shorter arm length showed the highest photocatalytic efficiency, which is due to higher probability of charge separation.