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1.
The kinetics of hydroformylation of 1-decene using homogenous HRh(CO)(PPh3)3 catalyst has been reported in the temperature range of 50–70 °C. The effect of catalyst,P
H
2,P
CO, and 1-decene concentration on the rate of hydroformylation has been studied. Based on the analysis of initial rate data, a rate equation has been proposed and kinetic parameters evaluated. The activation energy was found to be 11.76 kcal/mol. A molecular level approach to kinetic modelling has also been illustrated. The rate equation derived assuming oxidative addition of H2 as a rate determining step, has been found to represent the data satisfactorily. The rate parameters for the mechanistic model have been evaluated for the data at 60 °C.NCL Communication No. 5735. 相似文献
2.
Nikita Tiwari Raksha Pandit Swapnil Gaikwad Aniket Gade Mahendra Rai 《IET nanobiotechnology / IET》2017,11(2):205
Aim: The authors report the biological synthesis of zinc oxide nanoparticles (ZnO‐NPs) from the petals extract of Rosa indica L. (rose). Its efficacy was evaluated against two dermatophytes: namely: Trichophyton mentagrophytes and Microsporum canis which cause onychomycosis. The activity of antibiotics against the tested dermatophytes was enhanced, when evaluated in combination with ZnO‐NPs. Methods and results: The synthesised ZnO‐NPs were preliminary detected by using ultraviolet UV visible spectroscopy, which showed specific absorbance. The ZnO‐NPs were further characterised by nanoparticle tracking analysis (NTA), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), X‐ray diffraction and Zetasizer. Moreover, nanoparticles containing nail paint (nanopaint) was formulated and its antifungal activity was also assessed against T. mentagrophytes and M. canis. ZnO‐NPs and formulated nanopaint containing ZnO‐NPs, both showed significant antifungal activity. The maximum activity was noted against M. canis and lesser against T. mentagrophytes. Minimum inhibitory concentration of ZnO‐NPs was also determined against the dermatophytes causing onychomycosis infection. Conclusion: ZnO‐NPs can be utilised as a potential antifungal agent for the treatment of onychomycosis after more experimental trials.Inspec keywords: diseases, zinc compounds, nanoparticles, nanofabrication, antibacterial activity, microorganisms, nanomedicine, ultraviolet spectra, visible spectra, Fourier transform infrared spectra, transmission electron microscopy, X‐ray diffraction, biomedical materials, patient treatmentOther keywords: zinc oxide nanoparticle biosynthesis, Rosa indica L petals extract, nail paint, antifungal activity evaluation, dermatophyte, Trichophyton mentagrophytes, Microsporum canis, antibiotics activity, ultraviolet‐visible spectroscopy, nanoparticle tracking analysis, Fourier transform infrared spectroscopy, transmission electron microscopy, X‐ray diffraction, zetasizer, antifungal agent, onychomycosis treatment 相似文献
3.
Delay and cost overrun are common phenomena in projects worldwide. However, these are especially severe in developing countries. In India as per MOSPI report, 235 projects out of 410 were severely affected cost overrun due to certain factors. A short questionnaire was conducted with 15 prominent factors responsible for cost overrun and forwarded to 190 constructional professionals across India. Total 85 responses were received and it was analyzed using various statistical tools such as analysis of variance (ANOVA) and factor analysis tool using SPSS. In this study, top three factors affecting cost overruns were identified such as price escalation of raw material, delay in planned activity and lack of co-ordination between construction parties which could be significantly responsible for cost overnun of construction project in India. Factor analysis method was also carried out to group the factors into three components of overall questionnaire. These components, such as client control component, project management component, and contractor control component, would be useful to the various parties involved in the construction activities. This paper also provides suggestive frameworks which have been framed after discussing with large number of construction professionals or expert. 相似文献
4.
5.
Swapnil S. Vyas Bimal K. Bhattacharya Prashant Kumar 《International journal of remote sensing》2016,37(24):6108-6126
Real-time data of reference evapotranspiration (ET0) at different space-time scales are essential to regional agricultural drought assessment, water accounting at the watershed to basin scale, and provide irrigation advisory to farmers. Here, we present a data-fusion approach that integrates satellite-based insolation product (8 km) from an Indian geostationary satellite (Kalpana-1) sensor (VHRR; Very High Resolution Radiometer) and high-resolution (~ 5 km) short-range weather forecast into an FAO56 model based on the classical Penman–Monteith (P-M) formulation. Five year (2009–2013) mean monthly estimates from the daily ET0 product over the Indian landmass were found to vary between 10 and 350 mm. It increased from January to May (70–350 mm), followed by a decrease to reach the lowest in November (10–140 mm), thus typically showing unimodal distribution. The comparison of daily space-based and station-based estimates (at six ground stations) produced a root mean square deviation (RMSD) ranging from 21% to 38% for 977 paired data sets with the correlation coefficient (r) varying from 0.32 to 0.82. The error was reduced from 25% to 10% with an increase in ‘r’ from 0.43 to 0.98 for daily to 10 day summation period. Spatial grid-to-grid comparison of monthly ET0 estimates with Global Data Assimilation System (GDAS) potential evapotranspiration (PET) showed RMSD within a range of 1.4–18.4% for most of the months, except for two. Further ET0 analysis over normal and drought years showed that it could be used for comprehensive drought assessment with other existing indicators. 相似文献
6.
Shashank S. Tiwari Swapnil V. Ghatage Jyeshtharaj B. Joshi Bo Kong 《American Institute of Chemical Engineers》2022,68(8):e17725
Multifluid model (MFM) simulations have been carried out on liquid–solid fluidized beds (LSFB) consisting of binary and higher-order polydisperse particle mixtures. The role of particle–particle interactions was found to be as crucial as the drag force under laminar and homogenous LSFB flow regimes. The commonly used particle–particle closure models are designed for turbulent and heterogeneous gas–solid flow regimes and thus exhibit limited to no success when implemented for LSFB operating under laminar and homogenous conditions. A need is perceived to carry out direct numerical simulations of liquid–solid flows and extract data from them to develop rational closure terms to account for the physics of LSFB. Finally, a recommendation flow regime map signifying the performance of the MFM has been proposed. This map will act as a potential guideline to identify whether or not the bed expansion characteristics of a given polydisperse LSFB can be correctly simulated using MFM closures tested. 相似文献
7.
Poly(ethylene oxide) (PEO)/clay nanocomposites were prepared by a solution intercalation method using chloroform as a solvent. The nanocomposites were characterised by X-ray diffraction (XRD), differential scanning calorimetry (DSC), hot-stage polarized optical microscopy (POM), Fourier transform infrared spectroscopy (FT-IR), tensile analysis, dynamic mechanical analysis (DMA) characterisation techniques. Formation of nanocomposite was confirmed by X-ray diffraction (XRD) analysis. A decrease in PEO crystallinity in case of nanocomposite, was confirmed by a decrease in the heat of melting and spherulite size as indicated by DSC and POM studies, respectively. Improvement in tensile properties in all respect was observed for nanocomposites with optimum clay content (12.5 wt%). DMA studies indicate an increase in loss peak temperature and broadening of loss peak as a result of clay intercalation. 相似文献
8.
Swapnil Y. Dhumal Tyrone L. Daulton Jingkun Jiang Bamin Khomami Pratim Biswas 《Applied catalysis. B, Environmental》2009,86(3-4):145-151
Titanium dioxide is a wide band gap (3.2 eV) semiconductor which is photo-active when irradiated with UV light. For wider scale use of TiO2 as a photocatalyst, its activity needs to be extended to the visible light region (constituting 45% of total incident solar energy). A diffusion flame aerosol reactor (FLAR) with an oxygen lean environment in the particle formation zone has been used to synthesize oxygen deficient titanium suboxide (TiOx with x < 2) nanoparticles. Using a standard-based electron energy loss spectroscopy (EELS) technique, the non-stoichiometry (x in TiOx) in the flame synthesized particles has been quantified with high accuracy (uncertainty less than 3%). Under an oxygen lean environment in the particle formation zone, the non-stoichiometry in the TiOx particles is a function of the flame temperature. The value of x in the flame synthesized TiOx nanoparticles is in the range of 1.88 < x < 1.94. Diffuse reflectance spectra confirmed that the oxygen deficient TiOx particles absorbed visible light. Visible light activity of the TiOx particles is demonstrated by photocatalytic degradation of methyl orange solution under visible light illumination. 相似文献
9.
This paper presents the analytical study of flat plate collector based on the computer‐based thermal models considering two different cases, case A (fully covered by glass) and case B (fully covered by photovoltaic (PV) module). These models are developed based on energy balance equations. An analytical expression for characteristic equation for photovoltaic–thermal flat plate collector has been derived as a function of design and climatic parameters. This paper shows the detailed analysis of energy, exergy and electrical energy by varying the number of collectors by considering four weather conditions (A, B, C and D type) for five different cities (New Delhi, Bangalore, Mumbai, Srinagar and Jodhpur) of India. It is observed that the collectors fully covered by PV module combine the production of hot water in addition to electricity generation and it is beneficial in terms of exergy, thermal energy and electrical energy gain. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
10.
Swapnil Doijad S.B. Barbuddhe Sandeep Garg Sushanta Kalekar Jenney Rodrigues Dilecta D’Costa S. Bhosle Trinad Chakraborty 《Food Control》2011,22(12):1900-1904
The presence of Listeria in three milk processing environments as a potential source of milk contamination was assessed. Swab samples (n = 210) taken from milk processing plants were examined. Sample sites included the milk processing equipment, besides areas handling raw and pasteurized milk. The USDA Listeria-selective enrichment procedure was used to process the samples. Forty one (19.52%) Listeria isolates were recovered. The isolates were further subjected to biochemical and genotypic characterization. Out of 41 isolates, 16 (7.62%) were confirmed as Listeria monocytogenes, 2 (0.95%) as L. ivanovii, 19 (9.05%) as L. innocua. 1 (0.48%) as L. seeligeri and 3 (1.43%) as L. grayi. All the L. monocytogenes isolates were positive for the hlyA gene. PCR based serotyping revealed all L. monocytogenes to be of 1/2a, 1/2c, 3a and 3c serovar group. AscI and ApaI restriction analysis yielded four PFGE clusters for 16 L. monocytogenes isolates obtained from raw milk collector, milk silos, buttermilk mixer, cheese and other milk product processor. No predominant PFGE cluster was observed among these L. monocytogenes isolates. The main sources of L. monocytogenes were found to be raw milk collector and milk silos. In the present study L. monocytogenes was isolated from milk and milk products processing plants which could cross-contaminate the processed products and may possess a potential threat to public health. 相似文献