Electrochemical characterization of alternate conducting carbazole-bisthiophene units

An electrochemical and theoretical character of alternate copolymer of carbazole and bithiophene units was investigated. Polymerization is processed as two steps bielectronic oxidation of molecule. With monoelectronic oxidation is connected stable radical cation with spin located mainly on carbazole. The electrochemical properties of polymer are dependent on thickness of film deposited on electrode. In case of the thin layers one it is observed characteristic redox couple of carbazole oxidation to radical cation. Analysis of polymer behavior and results of spectrochemical measurements indicate on mixed type of electroconductivity.Molecular structures, HOMO-LUMO gaps and nature of highest occupied and lowest unoccupied molecular orbitals were also studied in presented work for oligomers ranging from monomer to octamer. The studies applied density functional theory (DFT).     

La transition secondaire postsecondaire abordée sous l'angle de l'harmonisation des manières d'utiliser le symbolisme chez les enseignants

Nos observations au secondaire et au collégial et les travaux menés sur la transition secondaire postsecondaire en mathématiques ont permis de documenter un ensemble de ruptures dans le passage d'un ordre à l'autre, soulignant l'importance de s'attarder à l'articulation entre ces deux ordres. C'est afin de mieux comprendre ces articulations possibles qu'une recherche collaborative a été menée avec des enseignants des deux ordres. L'analyse, puisant ses fondements en ethnométhodologie, fait apparaître l'utilisation du symbolisme comme un thème central de cette articulation interordres, et permet de retracer une trajectoire d'harmonisation qui se développe durant les rencontres en lien avec cette utilisation.     

Identifying the Magnitude and Location of a Load on a Slender Beam Using a Strain Gauge Based Force Transducer

A unique strain gauge based method is developed to identify the magnitude and location of a load on a slender beam with variable cross sections, and pinned, firm rest, soft rest, pinned‐fixed, and fixed boundary conditions. Four uniaxial strain gauges are mounted to the bottom surface of the beam, and the bending moment diagram of the beam can be constructed using measured strains on the beam. By combining individually scaled strain gauge outputs, the magnitude and location of the load can be accurately identified. The strain gauge based force transducer methodology is experimentally validated on prismatic beams with firm rest, soft rest, firm rest‐fixed, and fixed boundary conditions, and a continuously tapered beam with rest boundary conditions. The force transducer methodology is independent of the boundary conditions of the beam, and the error from strain gauge drift due to uniform thermal expansion on a prismatic beam can cancel out.     

Optimization of Settling Behavior for an Efficient Solvent‐Extraction Process for Biobased Components

Extraction is a downstream process option in biobased processes. Because knowledge of phase‐separation behavior is essential for designing efficient separation processes, this study investigates the settling and coalescence behavior of biobased extraction systems by using a standard laboratory‐scale settling cell. The influence of different buffer media and Escherichia coli cells on coalescence was determined for the reactive extraction of hexane‐1,6‐diamine with isostearic acid and di(2‐ethylhexyl)phosphoric acid by using kerosene and oleyl alcohol as diluents. As a result, an increasing pH value of the buffer significantly increases the settling time. The presence of E. coli cells hinders phase separation of the investigated systems, in particular, with dispersed organic phases.     

An adaptive RAM-DFE for storage channels

A modification of the decision feedback equalizer (DFE), RAM-DFE, is presented and analyzed for use in channels with trailing nonlinear intersymbol interference, especially binary saturation-recording channels. In the RAM-DFE, a look-up table, which can be easily implemented with random access memory, (RAM), replaces the transversal filter feedback section of the DFE. The feedforward section of the equalizer remains linear. A general nonlinear Markov (or finite-state machine) model is used to model the nonlinear intersymbol interference (ISI) channel. With this Markov model, a method is introduced for computing the minimum-mean-squared-error settings of the feedforward filter coefficients and the feedback filter and look-up table contents for the linear DFE and the RAM-DFE, respectively. RAM-DFE with these settings can be significantly better than the linear DFE for channels with trailing nonlinear ISI. Globally convergent gradient-type algorithms for updating the feedforward section coefficients and the contents of the feedback table are introduced and analyzed. Results based on data taken from disk storage units are discussed     

Broad-band frequency characterization of double Y-branch nanojunction operating as room-temperature RF to DC rectifier

Room-temperature dc and broad-band high-frequency (HF) to dc conversion measurements of a double Y-branch junction (YBJ) are presented and discussed. Nonlinear dc characteristics of the devices at room temperature are observed and HF to dc conversion up to 40 GHz at room temperature is presented. The HF to dc conversion efficiency degradation is found to be partly due to losses in interconnects feeding the device. A small-signal equivalent circuit of the YBJ is proposed in order to verify the frequency dependence of intrinsic elements.     

Contact stresses in the glenoid component in total shoulder arthroplasty

Several studies of retrieved glenoid components from total shoulder arthroplasty show an erosion of the rim, surface irregularities, component fracture and wear resulting from polyethylene deformation in vivo. Particles resulting from polyethylene wear might be one of the reasons for the very high rate of glenoid component loosening found clinically. Because wear can be the result of high contact stresses, the aim of this study is to find out whether or not contact stresses are high enough to cause wear of the glenoid component and what influence the component type and geometry have on polyethylene contact stresses for different humerus abduction angles. Elasticity theory is used in a parametric study of contact stresses in several glenoid component designs. A finite element method is used to confirm the accuracy of the analytical solution. The analysis shows that the peak stress generated in glenoid components under conditions of normal living can be as high as 25 MPa; since this exceeds the polyethylene yield strength, wear and also cold flow of the components can be expected. It is predicted that more conforming components have lower contact stresses, which might result in lower wear rate and less cold flow. It is also found that a metal-backed component promotes higher contact stresses than an all-polyethylene component with the same total thickness, therefore it can be expected that metal-backed components have inferior wear properties.     

Assessment of patient organ doses and effective doses using the VIP-Man adult male phantom for selected cone-beam CT imaging procedures during image guided radiation therapy

A Monte Carlo based computational procedure for determining organ doses and effective doses has been described for two procedures used in newly developed image-guided radiation treatment: kilovoltage cone-beam computed tomography (kV CBCT) and mega-voltage computed tomography (MV CBCT). A whole-body patient computational phantom, VIP-Man phantom, is employed for Monte Carlo dose calculations. Results indicate that the thyroid dose is always the highest in head and neck (H&N) scan for both kV and MV CBCT, and the bladder dose is the highest in prostate scan for both kV and MV CBCT. For the VIP-Man phantom, it has been found that the effective dose for kV CBCT (assuming a total exposure of 1350 mAs) is approximately 9.5 mSv for the two anatomical sites, whereas the effective dose for MV CBCT (assuming a total of 6 monitor unit) ranges from 5.10 mSv for the H&N case to 8.39 mSv for the prostate scan. The estimated whole-body effective doses allow different imaging procedures to be compared and evaluated.