全文获取类型
收费全文 | 305篇 |
免费 | 3篇 |
国内免费 | 5篇 |
专业分类
电工技术 | 30篇 |
综合类 | 1篇 |
化学工业 | 95篇 |
金属工艺 | 9篇 |
机械仪表 | 9篇 |
建筑科学 | 18篇 |
能源动力 | 2篇 |
轻工业 | 25篇 |
水利工程 | 1篇 |
石油天然气 | 3篇 |
无线电 | 16篇 |
一般工业技术 | 40篇 |
冶金工业 | 4篇 |
原子能技术 | 22篇 |
自动化技术 | 38篇 |
出版年
2022年 | 3篇 |
2021年 | 3篇 |
2019年 | 2篇 |
2018年 | 3篇 |
2017年 | 2篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 6篇 |
2013年 | 16篇 |
2012年 | 2篇 |
2011年 | 9篇 |
2010年 | 8篇 |
2009年 | 6篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 10篇 |
2005年 | 20篇 |
2004年 | 8篇 |
2003年 | 11篇 |
2002年 | 6篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 7篇 |
1998年 | 6篇 |
1997年 | 13篇 |
1996年 | 8篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 5篇 |
1992年 | 9篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 11篇 |
1978年 | 5篇 |
1977年 | 7篇 |
1976年 | 7篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1968年 | 3篇 |
1964年 | 1篇 |
排序方式: 共有313条查询结果,搜索用时 0 毫秒
1.
The crystallization process of hexagonal boron nitride in the presence of copper has been investigated. The positive effect of copper on the crystallinity of boron nitride was observed in the three studied systems of: nitrided boron, nitrided boron–carbon, and previously prepared turbostratic boron nitride. However, the presence of copper hindered the formation of boron carbonitride and produced graphite and boron nitride phases separately. Poor crystallinity was found as a conditio sine qua non for the existence of such a compound. Well-crystallized boron nitride had a very low spacing parameter 0.3328 nm and a regular hexagonal shape. 相似文献
2.
Tsutomu Osawa Masashi Ando Saori Sakai Tadao Harada Osamu Takayasu 《Catalysis Letters》2005,105(1-2):41-45
The role of acetic acid added to the reaction media for the enantio-differentiating hydrogenation of methyl acetoacetate over
a (R,R)-tartaric acid-in-situ-modified nickel catalyst was studied from the viewpoint of the hydrogenation rate during repeated
runs. The hydrogenation of methyl acetoacetate on the “enantio-differentiating sites” of a tartaric acid-modified nickel catalyst
was specifically accelerated by the acetic acid added to the reaction media to increase the enantio-differentiating ability
of the catalyst. In order to increase the enantio-differentiating ability, the addition of acetic acid to the reaction media
was required in each run during the repeated use of the catalyst. 相似文献
3.
This article reviews the enantio-differentiating hydrogenation of prochiral ketones over a asymmetrically modified catalyst, focusing on the hydrogenation of simple prochiral alkanones. The parameters affecting catalytic activity and enantiodifferentiating ability are considerable in number, and each parameter should be optimized in order to attain a highperformance enantio-differentiating catalyst. Optimization of the parameters and the mode of enantio-differentiation are discussed and compared with the enantio-differentiating hydrogenation of β-ketoesters. 相似文献
4.
S-menthyloxycarbonylmethyl l- and d-cysteines were prepared by the reaction of l- or d-cysteine and (?)-menthyl chloroacetate in liquid ammonia and were then polymerized to poly(S-menthyloxycarbonylmethyll- and d-cysteines) by the N-carboxyanhydride (NCA) method. From the results obtained by means of infra-red spectra, X-ray diffractions, optical rotatory dispersions (o.r.d.), and circular dichroisms (c.d.), was found to be a right-handed α-helix in the solid state and in ethyl ether/chloroform and chloroform solutions. Similarly, was a left-handed α-helix. The helix-coil transition of these polymers was observed in the vicinity of 3–4% trifluoroacetic acid (TFA) in chloroform/TFA mixtures. 相似文献
5.
By transforming the personal computer into a communication appliance, the Internet has initiated the true home computing revolution. As a result, Computer Mediated Communication (CMC) technologies are increasingly used in domestic settings, and are changing the way people keep in touch with their relatives and friends. This article first looks at how CMC tools are currently used in the home, and points at some of their benefits and limitations. Most of these tools supportexplicit interpersonal communication, by providing a new medium for sustaining conversations. The need for tools supportingimplicit interaction between users, in more natural and effottless ways, is then argued for. The idea of affective awareness is introduced as a general sense of being in touch with one's family and friends. Finally, the KAN-G framework, which enables affective awareness through the exchange of digital photographs, is described. Various components, which make the capture, distribution, observation and annotation of snapshots easy and effortless, are discussed. 相似文献
6.
Shunjiro Ogawa Hideyo Suzuki Masatake Toyoda Yoshio Ito Masahiro Iwaida Hiroko Nonogi Tazu Fuke Kazuo Obara Tadao Adachi Koichi Fujita Makiko Ikuzawa Tetsuo Izumi Takashi Hamano Yukimasa Mitsuhashi Yukio Matsuki 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1979,168(4):293-298
Summary Detection and determination of traces of sulphites in foods was attempted by use of the modified Rankine apparatus and pararosaniline colorimetry. Replacement of alkaline titration reported previously by pararosaniline colorimetry lowered the absolute detection limit from 30 g (titration method) to 2 g. In view of clean analysis, in the color developing system, 0.1 N-sodium hydroxide was used in place of mercuric chloride solution commonly used as an absorbant of sulphites. In order to prevent oxidative decomposition of sulphites during operation, nitrogen gas was used as carrier instead of air. Dimedone and sodium azide were used for the elimination of aldehydes and nitrites, respecitvely, in the sample, which will disturb the color development of sulphites with pararosaniline-formaldehyde reagents. With this improved method, it was possible to determine the residual sulphites in frozen peeled shrimps, sugared beans and other foods with low sulphite contents accurately.
Studies on the Analyses of Sulphites in Foods (IV) 相似文献
Colorimetrische Mikrobestimmung von Sulfiten in Lebensmitteln bei Anwendung der modifizierten IV. Rankine Apparatur
Zusammenfassung Geringe Sulfitmengen in Lebensmitteln (geschälte Garnelen, gezuckerte Bohnen) können colorimetrisch bestimmt werden. Die neuentwickelte Methode beruht auf einer Kombination von colorimetrischer Bestimmung mittels p-Rosanilin und der Bestimmungsmethode nach Rankine. Auf diese Weise lassen sich Gehalte von 2 g noch genau bestimmen. Bei der Farbentwicklung wurde das giftige Quecksilbertetrachlorid durch 0.1 n-NaOH ersetzt, anstelle von Luft Stickstoff als Trägergas verwendet und somit eine Oxydation des Sulfits während der Bestimmung vermieden. Da Nitrit und Aldehyde die Farbentwicklung stören, wurde ihr Einfluß durch Dimedon und Natriumazid ausgeschaltet.
Studies on the Analyses of Sulphites in Foods (IV) 相似文献
7.
Weidong Ding Ryota Hayashi Kohei Ochi Junya Suehiro Kiminobu Imasaka Masanori Hara Noriaki Sano Eiichi Nagao Tadao Minagawa 《Dielectrics and Electrical Insulation, IEEE Transactions on》2006,13(6):1200-1207
Chemical byproducts analysis has been recognized as a powerful diagnosis method for SF6 gas-insulated switchgear (GIS). The authors have previously demonstrated that a carbon nanotube (CNT) gas sensor could detect partial discharge (PD) generated in SF6 gas. However, PD-generated decomposition gas species, which were responsible for the CNT gas sensor response, have not been identified yet. In this paper, two kinds of experiments were conducted in order to identify the responsible decomposition gas species. At first, the decomposition gas molecules adsorbed on CNTs were analyzed by Fourier transformation infrared (FTIR) spectroscopy. FTIR absorbance was observed around 735 cm-1 after CNTs were exposed to PD generated in SF6. In the second experiment, the CNT gas sensor responses to typical SF6 decomposition products (HF and SF4) were examined. The CNT gas sensor responded to these gases in the same way as to PD generated in SF6. SF4 response was larger than HF response. Based on these results, SF 4 and SOF2 emerged as candidates for the responsible decomposition gases. Electrochemical interactions between adsorbed gas molecules and CNT were discussed based on theoretical predictions of molecular orbital calculations. The calculation results suggested that both of SOF2 and SF4 could increase the CNT gas sensor conductance 相似文献
8.
采用气相色谱定量测量了聚氯乙烯(PVC)、乙丙橡胶(EPR)和氯磺化聚乙烯(CSM)等线缆绝缘材料经辐照后在不同温度下热老化过程中的O2消耗量.对实验数据进行了反应动力学分析,发现线缆绝缘材料的热氧化降解反应为一级反应.同时获得了不同温度下的反应常数,并与根据Arrhenius 方程计算的理论结果进行了比较. 相似文献
9.
Abstract A method of describing centrosymmetric gratings (radial, circular and spiral) is presented. The moiré-fringe profile produced by centrosymmetric gratings is analysed using polar coordinates. The concept of the angle of intersection for two superimposed gratings is examined and it is shown how from this study moiré patterns formed from centrosymmetric gratings can be analysed automatically by digital computer. Examples of theoretically predicted patterns, generated by the proposed procedure, are compared with actual moiré-fringe patterns. This method provides for the first time a procedure that can be used in engineering for improving the contrast of moiré patterns and for sharpening these patterns. 相似文献
10.
DNA‐Templated Synthesis of Perylenediimide Stacks Utilizing Abasic Sites as Binding Pockets and Reactive Sites 下载免费PDF全文
Dr. Tadao Takada Misa Ido Akane Ashida Dr. Mitsunobu Nakamura Prof. Kazushige Yamana 《Chembiochem : a European journal of chemical biology》2016,17(23):2230-2233
DNA is considered to be a promising biomolecule as a template and scaffold for arranging and organizing functional molecules on the nanoscale. The construction and evaluation of DNAs containing multiple functional molecules that are useful for optoelectronic devices and sensors has been studied. In this paper we report the efficient incorporation of perylenediimide (PDI) units into DNA by using abasic sites both as binding sites and as reactive sites and the construction of PDI stacks within the DNA structure, accomplished through the preorganization of the PDI units in the hydrophobic pocket within the DNA. Our approach could become a valuable method for construction of DNA/chromophore hybrid structures potentially useful for the design of DNA‐based devices and biosensors. 相似文献