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1.
2.
Wolfgang Knoll Mieko Matsuzawa Andreas Offenhäusser Jürgen Rühe 《Israel journal of chemistry》1996,36(4):357-369
Various strategies are described for the bio-functionalization of solid substrates by design of interfacial architectures. The first approach is based on the self-assembly process of long-chain thiol molecules from solution to a (noble) metal surface. If some of these building blocks carry a binding site (ligand) for proteins (receptors, antibodies, etc.) the metal surface can be tailored for maximum specific binding while simultaneously minimizing nonspecific adsorption. The second concept is based on polymers that are covalently attached to (oxide) surfaces. The preparation of these (end-) grafted functional polymers involves either the binding of preformed macromolecules to corresponding sites at the surface of the support or the recently introduced “grafting-from” method, by which an initiator molecule is first covalently bound to the surface and then activated — either by heat or light — in the presence of suitable monomer units such that a polymer chain grows from the solid/solution interface. Finally, the functionalization of patterned surfaces by peptide chains that mimic the binding domains of cell adhesion proteins is summarized. It is demonstrated that not only the selective adhesion of neuronal cells can then be controlled, but also their development with the outgrowth of dendrites and axons. 相似文献
3.
The prediction capabilities of simple whiteness formulae based on photometer reflectance readings (A, G, B) as compared to linear formulae with adjustable parameters based on chromaticity values (x, y, Y) have been investigated. For each formula, the instrumentally determined whiteness was compared with visually estimated whiteness using the plates of the Ciba–Geigy Plastic White (CGPW) Scale as a standard. This was carried out for a set of 48 fluorescent cotton cloth samples previously studied, as well as for a new set of 86 non–fluorescent cotton cloth samples. As expected, the AGB formulae were inferior to those based on chromaticity values; however, the Taube formula performed quite well for fluorescent samples. On the set of non–fluorescent samples, a formula having green hue preference was required; the Berger formula was found to be the most successful among the simple AGB formulae. 相似文献
4.
Thick carbonate-dominated successions in northwestern Siberia document secular variations in the C-isotopic composition of seawater through Mesoproterozoic and early Neoproterozoic (Early to early Late Riphean) time. Mesoproterozoic dolomites of the Billyakh Group, Anabar Massif, have delta 13C values that fall between 0 and -1.9 permil versus PDB, with values in the upper part of the succession (Yusmastakh Formation) consistently higher than those of the lower (Ust'-Il'ya and Kotuikan formations). Consistent with available biostratigraphic and radiometric data, delta 13C values for Billyakh carbonates compare closely with those characterizing early Mesoproterozoic carbonates (about 1600-1200 Ma) worldwide. In contrast, late Mesoproterozoic to early Neoproterozoic limestones and dolomites in the Turukhansk Uplift exhibit moderate levels of secular variation. Only the lowermost carbonates in the Turukhansk succession (Linok Formation) have delta 13C values that approximate Billyakh values. Higher in the Turukhansk succession, delta 13C values vary from -2.7 to +4.6 permil (with outliers as low as -5.0 permil interpreted as diagentically altered). Again, consistent with paleontological and radiometric data, these values compare well with isotopic values from 1200 to 850 Ma successions elsewhere. Five sections measured in different parts of the Turukhansk basin show nearly identical patterns of variation, confirming that carbonate delta 13C correlates primarily with time and not facies. The Siberian sections illustrate the potential of integrated biostratigraphic and chemostratigraphic data in the intra- and interbasinal correlation of Mesoproterozoic and early Neoproterozoic rocks. 相似文献
5.
Template‐Free Fabrication of Mesoporous Alumina Nanospheres Using Post‐Synthesis Water‐Ethanol Treatment of Monodispersed Aluminium Glycerate Nanospheres for Molybdenum Adsorption
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Indra Saptiama Yusuf Valentino Kaneti Yoshitaka Suzuki Kunihiko Tsuchiya Nobuyoshi Fukumitsu Takeji Sakae Jeonghun Kim Yong‐Mook Kang Katsuhiko Ariga Yusuke Yamauchi 《Small (Weinheim an der Bergstrasse, Germany)》2018,14(21)
This work reports the template‐free fabrication of mesoporous Al2O3 nanospheres with greatly enhanced textural characteristics through a newly developed post‐synthesis “water‐ethanol” treatment of aluminium glycerate nanospheres followed by high temperature calcination. The proposed “water‐ethanol” treatment is highly advantageous as the resulting mesoporous Al2O3 nanospheres exhibit 2–4 times higher surface area (up to 251 m2 g?1), narrower pore size distribution, and significantly lower crystallization temperature than those obtained without any post‐synthesis treatment. To demonstrate the generality of the proposed strategy, a nearly identical post‐synthesis “water treatment” method is successfully used to prepare mesoporous monometallic (e.g., manganese oxide (MnO2)) and bimetallic oxide (e.g., CuCo2O4 and MnCo2O4) nanospheres assembled of nanosheets or nanoplates with highly enhanced textural characteristics from the corresponding monometallic and bimetallic glycerate nanospheres, respectively. When evaluated as molybdenum (Mo) adsorbents for potential use in molybdenum‐99/technetium‐99m (99Mo/99mTc) generators, the treated mesoporous Al2O3 nanospheres display higher molybdenum adsorption performance than non‐treated Al2O3 nanospheres and commercial Al2O3, thereby suggesting the effectiveness of the proposed strategy for improving the functional performance of oxide materials. It is expected that the proposed method can be utilized to prepare other mesoporous metal oxides with enhanced textural characteristics and functional performance. 相似文献
6.
B.K. Satapathy R. Weidisch K. Schneider K. Knoll 《Engineering Fracture Mechanics》2006,73(16):2399-2412
The crack initiation and propagation behaviour of styrene-butadiene (SB) star block copolymer/polystyrene blends (ST3/PS) forming PS-rich and polybutadiene (PB)-rich nanosized domains by self-assembling have been investigated using the essential-work-of-fracture (EWF) approach. Three morphological transitions have been observed, which are crucial to understand the crack toughness behaviour: (i) 0-30 wt.% PS homopolymer: A co-continuous domain structure of PS-rich and PB-rich domains has been observed. For PS homopolymer fraction (?PS) < 10 wt.% PS homopolymer (i.e. only pure ST3) the rubbery PB-rich phase forms the major phase and for ?PS > 10 wt.% the glassy PS-rich phase. (ii) At 40-60 wt.% PS homopolymer, a layer-like morphology is formed where the PS-rich layer thickness is ?50 nm, a critical dimension, which is crucial for understanding the ductile-to-semiductile transition. (iii) For 80 wt.% PS homopolymer, PS-rich phase starts to form the matrix combined with a transition from shear stress dominated (shear yielding) to normal stress dominated behaviour (PS-like crazes). The co-continuous morphology at 20 wt.% and 30 wt.% PS is capable of improving toughness of block copolymers, demonstrated by the observed maximum in the non-essential work of fracture and thus explaining a new way of toughening of polymers while retaining high transparency. The correspondence between the ductile-to-semiductile transition and the change in the shape of plastic zone from circular to elliptical as revealed from strain field analysis could be clearly reaffirmed by the observed transition from shear to normal force induced deformation in the fractured surface analysis of these blends. The conceptual correspondence of βwp and we with TJ and δ0.2 respectively reveal that resistance against crack propagation (βwp and TJ) is morphology sensitive while the resistance against crack initiation (we and δ0.2) is matrix sensitive. 相似文献
7.
Based on the fracture mechanics analysis of crack propagation, the phenomenon of subcritical crack growth was utilized for
a controlled debonding of directly wafer-bonded interfaces. The approach allowed the well-defined separation of bonded wafers
although the bond strength was high due to thermal annealing. The achieved splitting velocity depended on the wafer material,
the wafer thickness ratio, the bonding process parameters, and the environmental conditions during cleaving. In combination
with wafer bonding, the method can be used for a temporary stiffening and handling of thin and brittle wafers during fabrication,
even if the wafers are exposed to high process temperatures. The approach can also be applied to fabricate micromechanical
systems (MEMS).
Received: 12 July 2001/Accepted: 26 February 2002
This paper was presented at the Conference of Micro System Technologies 2001 in March 2001. 相似文献
8.
We describe the use of surface plasmon- and surface plasmon fieldenhanced fluorescence spectroscopy for the detection of hybridization reactions between surface-attached probe oligonucleotides and complement strands binding from solution. These targets, exhibiting different base mismatches relative to the probe 15-mer sequences, carry a fluorophore at their 5'-end thus allowing for sensitive detection and quantification of association, kon, and dissociation, koff, rate constants, as well as affinity constants, Ka. We demonstrate that by the competitive binding / replacement of single strand binding proteins the mismatch discrimination can be further enhanced. 相似文献
9.
N-(3-Aminothioacryloyl)-formamidines 3 react with primary amines to give either 4(1H)-pyrimidinthiones 6 or transaminated N-(3-aminothioacryloyl)-formamidines 5 . Alkylation of the latter compounds gives rise to cyclised 6(1H)-pyrimidinimines 7 . The 4(1H)-pyrimidinthiones 6 can be S-alkylated to 4-alkylmercaptopyrimidinium salts 8 . Subsequent substitution of the alkylmercapto group of the 8 results in the formation of 4-aminopyrimidinium salts 9 , which can also be obtained starting from the 3 by a reversed reaction sequence that is first by S-alkylation to 3-alkylmercapto-2-azapentamethinium salts 10 and subsequent reaction with primary amines. 相似文献
10.
Knoll P Gröller E Höll K Mirzaei S Koriska K Köhn H 《IEEE transactions on medical imaging》2000,19(12):1258-1261
Distributed computing that uses dynamic networks will change the way we work and communicate thanks to the interaction of devices and services, that are automatically added and removed from the network as needed. The Jini technology, which is built atop the Java programming language, provides a homogenous view of the network and extends the ability of code to migrate in Java. This software design model simplifies the configuration and access to hardware devices and software services in a network. Thus, it becomes possible to execute new services without pre-installing software on client machines. This new programming paradigm is especially important in medical applications, where the reliable transmission of information is essential. This paper demonstrates how single photon emission computerized tomography data can be iteratively reconstructed using a Jini service. 相似文献