Influence of HMTA ligand in MMA AGET ATRP emulsion polymerization

Interactions of hexamethylenetetramine ligand in atom transfer radical polymerization initiated by activator generated by electron transfer were studied. Polymerization of methyl methacrylate was done using two-step experimental procedure in 2 L emulsion batch reactor at 50, 60, and 80°C. The selection of reactant ratios was quite challenging for a reactor of this size. Replicate runs were conducted for data reproducibility purpose. Gravimetry method and gel permeation chromatography were used to determine monomer conversion, Mn, and PDI of polymer samples. PMMA produced was also characterized by means of dynamic light scattering, Fourier-transform infrared spectroscopy and nuclear Magnetic Resonance spectroscopy. Results showed high monomer conversion up to 93% and Mn ranging 243–274 kg/mol with PDI from 1.45 to 1.60. Besides, combining HMTA with sodium dodecyl sulfate, an anionic surfactant, a well-controlled polymer with a lower Mn of 201 kg/mol and PDI of 1.56 was obtained in 3 hr reaction time.     

Statistical synchronization among participants in real-time multimedia conferencing

In this paper, an algorithm to determine the set of packets generated continuously and periodically from different participants that are arriving at a node either for mixing at the master of a conference, or for simply playing back at a regular participant of a conference, is proposed. The essence of the algorithm is to estimate the expected packet arrival time (or reference time) for each participant. With the reference time at hand, the maximum jitter and the optimum waiting time for a mixer to wait packets from all participants can be determined. An enhancement to improve synchronization which deals with the estimation of the time offsets between the individual periods of the sources and the period of the receiver is also presented. The error of the proposed algorithm is enumerated by the Chernoff bound and demonstrated by simulation and is shown to be acceptable in practical application. The algorithm can also be employed when traffic sources operate with different periods.     

A modified flow enforcement technique for ATM networks

In ATM networks the requirement of providing the negotiated Quality of Service (QOS) needs an efficient flow enforcement technique that will result in preventive congestion control. A very effective technique is the Exponentially Weighted Moving Average (EWMA) method. In this paper, we have suggested improvements to the EWMA and call it the Enhanced EWMA (EEWMA). Simulation results show that the EEWMA is consistently better than the EWMA in most of the situations. We present comparisons of cell loss under various conditions. No theoretical analysis is presented.     

HYDCOND: A Computer Program to Calculate Hydraulic Conductivity from Grain Size Data in Saudi Arabia

Hydrogeologists always look for reliable techniques to determine the hydraulic conductivity of the aquifers with which they are concerned, for better groundwater management and conservation. The use of grain size distribution for unconsolidated aquifer materials is considered feasible and sound. Several empirical equations to calculate hydraulic conductivity using grain size distribution are well established in the literature. The present paper describes a computer program, HYDCOND, which is designed to calculate hydraulic conductivity using grain size data. In addition, the program calculates grain size statistics and classifies the aquifer materials in terms of their main size percentage. HYDCOND is menu-driven, interactive and user friendly program. It was tested extensively and successfully using materials from Minjur aquifer in central Saudi Arabia. The results were found to be reliable and comparable to those obtained using other, costly techniques. HYDCOND can be implemented successfully to calculate hydraulic conductivity in all types of aquifers in Saudi Arabia and other regions of the world.     

Novel thermally and mechanically stable hydrogel for enzyme immobilization of penicillin G acylase via covalent technique

κ‐Carrageenan hydrogel crosslinked with protonated polyethyleneimine (PEI⁺) and glutaraldehyde (GA) was prepared and evaluated as a novel biocatalytic support for covalent immobilization of penicillin G acylase (PGA). The method of modification of the carrageenan biopolymer is clearly illustrated using a schematic diagram and was verified by FTIR, elemental analysis, DSC, and INSTRON using the compression mode. Results showed that the gels' mechanical strength was greatly enhanced from 3.9 kg/cm² to 16.8 kg/cm² with an outstanding improvement in the gels thermal stability. It was proven that, the control gels were completely dissolved at 35°C, whereas the modified gels remained intact at 90°C. The DSC thermogram revealed a shift in the endothermic band of water from 62 to 93°C showing more gel‐crosslinking. FTIR revealed the presence of the new functionality, aldehydic carbonyl group, at 1710 cm^?1 for covalent PGA immobilization. PGA was successfully immobilized as a model industrial enzyme retaining 71% of its activity. The enzyme loading increased from 2.2 U/g (control gel) to 10 U/g using the covalent technique. The operational stability showed no loss of activity after 20 cycles. The present support could be a good candidate for the immobilization of industrial enzymes rich in amino groups, especially the thermophilic ones. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

High-performance polymer alloys of polybenzoxazine and bismaleimide

Two series of high-performance polymer alloys were prepared by mixing typical benzoxine monomers, 3-phenyl-3,4-dihydro-2H-1,3-benzoxazine (P-a) or 6,6-(1-methylethyliden)-bis-(3,4-dihydro-3-phenyl-2H-1,3-benzoxazine) (B-a), with a typical bismaleimide, 4,4-bismaleimidodiphenyl methane by various ratios followed by thermal treatment up to 240 °C. DSC and IR of the alloys were examined to follow the curing reaction. These analyses showed that the obtained polymer alloys are AB co-cross-linked polymer networks through the formation of ether linkage between the hydroxyl group of polybenoxazine and the double bond of bismaleimide. Viscoelastic analysis and softening temperature measurement revealed that the polymer alloys have much higher glass transition temperatures than those of each homopolymer. The thermal stability also increased with the increase of bismaleimide content as evidenced by TGA.     

A sensing strategy for the reverse engineering of machined parts

The reverse engineering of machined parts requires sensing an existing part and producing a design (and perhaps a manufacturing process) for it. We have developed a reverse engineering system that has proven effective with a set of machined parts. This paper describes the system, presents some results, and discusses strategy for a new system.This work was supported by ARPA under ARO grant number DAAH04-93-G-0420, DARPA grant N00014-91-J-4123, NSF grant CDA 9024721, and a University of Utah Research Committee grant. All opinions, findings, conclusions or recommendations expressed in this document are those of the authors and do not necessarily reflect the views of the sponsoring agencies.