Optically Tunable Nonlinearities in Polymers Based on Photoisomerizable Metal‐Based Coordination Complexes

The bottom‐up design of polymer films exhibiting quadratic nonlinear optical properties that can be tuned optically and chemically is described. The polymer matrices are doped with metal‐containing chromophores built around a Zn^II core and photoisomerizable ligands with two different geometries. These molecules possess specifically designed photophysical and nonlinear optical properties to be used towards all‐optical poling, an interference process between one‐ and two‐photon excitations that locally induces macroscopic second‐order effects in polymer films. It is shown that grafting the molecules onto the polymer chains improves the stability of the macroscopic photoinduced nonlinearity in the films.     

Elimination of fictitious penetrating rays from PO and hybridization with AFIM

Physical optics (PO) is an approximation method for high‐frequency scattering and diffraction problems. But PO fields are inaccurate in the shadow region where the source is screened by the scatter. Two key factors of the error for PO are (i) edge diffraction coefficients and (ii) existence of fictitious penetrating rays. The correction with respect to the former has been extensively investigated by many authors using various ray techniques such as GTD, UTD, and UAT. On the other hand, the latter was identified recently by the authors. This paper proposes novel PO‐based calculation procedures termed PO‐AF and PTD‐AF, where PO and Aperture Field Integration Method (AFIM) are merged with the help of special elementary diffraction coefficients. These can uniformly cover the whole angular region and only the error factor (ii) is removed in PO‐AF while both (i) and (ii) are removed in PTD‐AF. The theoretical backgrounds of PO currents are discussed in terms of field equivalence theorem and visualization of EM waves. Next, new methods are proposed and their validity is numerically demonstrated for 2D scattering problems of a strip, a corner reflector, and a cylinder of circular arc. © 2004 Wiley Periodicals, Inc. Electr Eng Jpn, 150(2): 1–10, 2005; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20037     

Performance of solvothermally prepared Ga2O3-Al2O3 catalysts for SCR of NO with methane

The solvothermal reaction of mixtures of aluminum isopropoxide (AIP) and gallium acetylacetonate (Ga(acac)₃) directly yielded the mixed oxides of γ-Ga₂O₃-Al₂O₃. In the solvothermal synthesis, the crystal structure of mixed oxides was controlled by the initial formation of γ-Ga₂O₃ nuclei. The mixed oxides prepared in diethylenetriamine have extremely high activities for selective catalytic reduction (SCR) of NO with methane as a reducing agent. With increasing crystallite size of the spinel structure, the catalytic activity increased. The ratio of the amount of methane consumed by combustion to total methane conversion was proportional to the density of acid sites on the surface of the mixed oxides. The mixed oxide catalysts prepared in diethylenetriamine had lower densities of acid sites and showed a higher methane-efficiency for CH₄-SCR than those prepared in other solvents. These catalysts maintained their high activity even when the reaction was carried out under the severe conditions (i.e., high space velocity and low NO concentration).     

In situ measurements of ion-exchange processes in single polymer particles: laser trapping microspectroscopy and confocal fluorescence microspectroscopy

Ion-exchange processes of a cationic dye (Rhodamine B; RhB) were studied for individual polymer particles (diameter of 16-20 μm) by laser trapping microspectroscopy and confocal fluorescence laser microspectroscopy. The absorbance of RhB at 565 nm adsorbed on a cation-exchange particle increased linearly with the concentration of RhB in the aqueous phase, while it was independent of the particle diameter. Fluorescence intensity profile measurements of RhB along the particle diameter by confocal fluorescence microspectroscopy directly proved that ion exchange took place in the surface layer (～2-μm thickness) of the particle in the initial stage (1 h). Diffusion of RhB in the particle was very slow, and ion exchange proceeded gradually to the inner volume in the order of days. The ion-exchange processes were analyzed on the basis of simulation of the time course of the concentration profile of RhB in the particle, and the diffusion coefficient of RhB was determined to be (2-4) × 10(-11) cm(2)·s(-1).     

Hydrocarbons with a homoconjugated polyene system and their monoepoxy derivatives: Sex attractants of geometrid and noctuid moths distributed in Japan

Although several sex pheromones of the family Geometridae have been characterized, investigations on Japanese species are limited. In order to obtain more information, screening using known sex pheromones and their analogs was carried out. The (Z,Z,Z)-3,6,9-triunsaturated and (Z,Z)-6,9-diunsaturated hydrocarbons with straight C¹⁹-C²¹ chains were synthesized by the Grignard coupling reaction as a key step starting from linolenic and linoleic acids, respectively. Oxidation of the homoconjugated trienes withm-chloroperoxybenzoic acid yielded a 111 mixture of three monoepoxy derivatives that could be separated by silica gel chromatography. The chemical structure of each positional isomer was confirmed using two-dimensional NMR techniques and MS measurements, which enabled characteristic fragment ions from the isomers to be identified. Field tests using lures incorporating only one of the above six hydrocarbons or nine epoxides were carried out in a forest in Tokyo. Consequently, attraction of male moths of 14 geometrid species in addition to four species in another family, the Noctuidae, was observed. It was concluded that hydrocarbons with a homoconjugated polyene system and the monoepoxy derivatives are important components of sex pheromones produced by Japanese lepidopterous insects, particularly the geometrid moths.     

A high‐performance sorting algorithm for multicore single‐instruction multiple‐data processors

Many sorting algorithms have been studied in the past, but there are only a few algorithms that can effectively exploit both single‐instruction multiple‐data (SIMD) instructions and thread‐level parallelism. In this paper, we propose a new high‐performance sorting algorithm, called aligned‐access sort (AA‐sort), that exploits both the SIMD instructions and thread‐level parallelism available on today's multicore processors. Our algorithm consists of two phases, an in‐core sorting phase and an out‐of‐core merging phase. The in‐core sorting phase uses our new sorting algorithm that extends combsort to exploit SIMD instructions. The out‐of‐core algorithm is based on mergesort with our novel vectorized merging algorithm. Both phases can take advantage of SIMD instructions. The key to high performance is eliminating unaligned memory accesses that would reduce the effectiveness of SIMD instructions in both phases. We implemented and evaluated the AA‐sort on PowerPC 970MP and Cell Broadband Engine platforms. In summary, a sequential version of the AA‐sort using SIMD instructions outperformed IBM's optimized sequential sorting library by 1.8 times and bitonic mergesort using SIMD instructions by 3.3 times on PowerPC 970MP when sorting 32 million random 32‐bit integers. Also, a parallel version of AA‐sort demonstrated better scalability with increasing numbers of cores than a parallel version of bitonic mergesort on both platforms. Copyright © 2011 John Wiley & Sons, Ltd.     

Partial redundancy elimination for access expressions by speculative code motion

We present a new memory access optimization for Java to perform aggressive code motion for speculatively optimizing memory accesses by applying partial redundancy elimination (PRE) techniques. First, to reduce as many barriers as possible and to enhance code motion, we perform alias analysis to identify all the regions in which each object reference is not aliased. Secondly, we find all the possible barriers. Finally, we perform code motions in three steps. For the first step, we apply a non‐speculative PRE algorithm to move load instructions and their following instructions in the backwards direction of the control flow graph. For the second step, we apply a speculative PRE algorithm to move some of them aggressively before the conditional branches. For the third step, we apply our modified version of a non‐speculative PRE algorithm to move store instructions in the forward direction of the control flow graph and to even move some of them after the merge points. We implemented our new algorithm in our production‐level Java just‐in‐time compiler. Our experimental results show that our speculative algorithm improves the average (maximum) performance by 13.1% (90.7%) for jBYTEmark and 1.4% (4.4%) for SPECjvm98 over the fastest algorithm previously described, while it increases the average (maximum) compilation time by 0.9% (2.9%) for both benchmark suites. Copyright © 2004 John Wiley & Sons, Ltd.     

Numerical computation of cross‐coupled algebraic Riccati equations related to H2/H∞ control problem for singularly perturbed systems

In this paper, we present a numerical algorithm to the cross‐coupled algebraic Riccati equations(CARE) related to H₂/H_∞ control problems for singularly perturbed systems (SPS) by means of Newton's method. The resulting algorithm can be widely used to solve Nash game problems and robust control problems because the CARE is solvable even if the quadratic term has an indefinite sign. We prove that the resulting iterative algorithm has the property of the quadratic convergence. Using the solution of the CARE, we construct the high‐order approximate H₂/H_∞ controller. Copyright © 2004 John Wiley & Sons, Ltd.