Structure and electrical characteristics of Ce4+-doped Ba2In2O5

The In-site of Ba₂In₂O₅ with Brownmillerite structure was partially substituted for Ce⁴⁺ ions in order to examine the doping effect on the order-disorder transition. Ba₂In_{2 – x} Ce _x O_{5 + x/2} (x = 0.1, 0.2, 0.3, 0.5, 1.0, and 1.5) were prepared by solid state reaction. X-Ray diffraction analyses of these powder samples demonstrated that Ba₂In_{2 – x} Ce _x O_{5 + x/2} (x = 0.1 and 0.2) possesses Brownmillerite structure. With increasing content of Ce⁴⁺ ion the crystal system of Ba₂In_{2 – x} Ce _x O_{5 + x/2} (x = 0.3, 0.5, and 1.0) changed to cubic perovskite structure above the order-disorder transition temperature of Ba₂In₂O₅. Arrhenius plots of the electrical conductivities of Ba₂In_{2 – x} Ce _x O_{5 + x/2} (x = 0.2, 0.3, and 1.0) exhibited no discontinuity. These compounds had high transference numbers of oxide ion above 973 k.     

Copolymerization of methylmethacrylate on a ball-milled surface of coal at 77 K

The ball-milling of coal with methylmethacrylate monomer was carried out under vacuum at 77 K and at room temperature and in air. The e.s.r. and i.r. spectra of ball-milled material showed that a copolymer of coal and methylmethacrylate was formed on the surfaces of coal created by ball-mining. Oxygen is an inhibitor to this process.     

Fibrous support for immobilization of enzymes

A poly(vinyl alcohol) (PVA) fiber support incorporating various aminoacetal functional groups has been developed for immobilizing enzymes. The aminated PVA fiber seems to adsorb enzymes with electrostatic force of attraction; thus the immobilization procedure is simple. By the use of this fiber having immobilized enzymes, the reaction between enzymes and substrates is nearly independent of the size of subtstrates. This newly developed type of fiber, which is formed by a mass superfine fibers (SFF), each measuring 1 μm or less in diameter, permits much more increased surface area than the conventional enzyme immobilization supports. Our studies of the properties of the fiber for immobilization of enzymes show the following results: (1) SFF has a greater ability for the immobilization of invertase than ordinary fibers; (2) dimethyl-aminated SFF has the best performance for the immobilization of invertase. From these results, it is concluded that the dimethyl-aminated SFF is an excellent support for the immobilization of invertase.     

In-situ monitoring of the stabilization with hydrogen of free radicals thermally induced from coal using high pressure e.s.r., d.t.a. and p.d.a. equipment

High temperature, high pressure e.s.r. measurements of the hydrogenation reaction of Taiheiyo coal in the presence of catalysts were carried out to understand the stabilization of thermally and/or catalytically induced free radicals. A decrease in free radical concentration with increasing temperature was observed for ZnCl₂ and SnCl₂ · 2H₂O catalysts at 10MPa under hydrogen gas. High pressure modified single-cell d.t.a. and p.d.a. equipment augmented the uniquely designed high temperature, high pressure e.s.r. cell. The hydrogenation reaction was monitored under the same experimental conditions as for e.s.r. From the results of the combination of high temperature, high pressure e.s.r. with high pressure d.t.a. and p.d.a., it was established that H₂ molecules can react efficiently with free radicals from coal molecules created by the presence of ZnCl₂ and SnCl₂ · 2H₂O catalysts.     

Tele‐Cocooning: Mobile Texting and Social Scope

The present study examines the tele‐cocooning hypothesis in the context of general trust using a nationally representative survey of Japanese youth. We find that although frequency of texting is positively correlated with general trust, this correlation is spuriously caused by how heavy mobile texters interpret the words “most people” in the general trust measurement. Heavy users assume that “most people” only refers to friends, family, and others going to the same school. When the effect of the “most people” assumption is controlled, the positive association between texting and general trust disappears. Further exploration of the data shows that heavy texting nevertheless has negative implications for social tolerance and social caution, both of which are theoretically proximate to general trust.     

Emerging From the Cocoon? Revisiting the Tele‐Cocooning Hypothesis in the Smartphone Era

The tele‐cocooning hypothesis posits that mobile communication increases interaction with communication rich ties, while simultaneously weakening interaction with communication weak ties. In this study, we demonstrate how smartphones can be used to mitigate tele‐cocooning behavior by stimulating interaction with communication weak ties. Using a smartphone application to collect non‐identifying mobile communication log data, we conducted a field experiment with 193 Japanese participants. The treatment consisted of onscreen reminders designed to stimulate interaction with communication weak ties. The results indicate that the treatment promoted the activation of communication weak ties and the acquisition of information through those ties, suggesting that smartphones can be utilized to promote access to social capital.     

Analysis of PD-generated SF/sub 6/ decomposition gases adsorbed on carbon nanotubes

Chemical byproducts analysis has been recognized as a powerful diagnosis method for SF₆ gas-insulated switchgear (GIS). The authors have previously demonstrated that a carbon nanotube (CNT) gas sensor could detect partial discharge (PD) generated in SF₆ gas. However, PD-generated decomposition gas species, which were responsible for the CNT gas sensor response, have not been identified yet. In this paper, two kinds of experiments were conducted in order to identify the responsible decomposition gas species. At first, the decomposition gas molecules adsorbed on CNTs were analyzed by Fourier transformation infrared (FTIR) spectroscopy. FTIR absorbance was observed around 735 cm^-1 after CNTs were exposed to PD generated in SF₆. In the second experiment, the CNT gas sensor responses to typical SF₆ decomposition products (HF and SF₄) were examined. The CNT gas sensor responded to these gases in the same way as to PD generated in SF₆. SF₄ response was larger than HF response. Based on these results, SF ₄ and SOF₂ emerged as candidates for the responsible decomposition gases. Electrochemical interactions between adsorbed gas molecules and CNT were discussed based on theoretical predictions of molecular orbital calculations. The calculation results suggested that both of SOF₂ and SF₄ could increase the CNT gas sensor conductance     

Software system of the Earth Simulator

The Earth Simulator (ES) is a large scale, distributed memory, parallel computer system consisting of 640 processor nodes (PN) with shared memory vector multi-processors (64GFLOPS/PN, 5120 APs in total, AP: arithmetic processor). All the nodes are connected via a high speed (16GB/s) single-stage crossbar network called the Interconnection Network (IN).

The operating system for the Earth Simulator is based on SUPER-UX, the UNIX operating system for the SX series scientific supercomputers. In order to realize high-performance parallel processing on the highly parallel machine, the operating system is enhanced for scalability.

The Earth Simulator system is managed as a two-level cluster system called the Super Cluster System. In the Super Cluster System, the Earth Simulator system is divided into 40 clusters (16 PNs/cluster). A single controller called Super Cluster Control Station (SCCS) manages all these clusters. This management system provides Single System Image (SSI) operation, management and job control for the large scale multi-node system.

The Job Scheduler (JS) and NQS running on the SCCS control all jobs of the system. They schedule the resources such as processing nodes and files which have not usually been treated as scheduling resources. This allows efficient scheduling of large scale jobs.

The MPI library (MPI/ES) and the HPF compiler (HPF/ES) are available for distributed parallel programming on the Earth Simulator. MPI/ES conforms to the MPI 2.0 standard and is optimized to exploit the hardware features. HPF/ES conforms to the core part of HPF 2.0 and supports some features of the HPF 2.0 approved extensions and HPF/JA 1.0 extensions. HPF/ES suitably handles the 3-level parallelism of the Earth Simulator system, that is, vectorization, shared-memory parallelization, and distributed-memory parallelization. Moreover, HPF/ES extends the language to easily handle irregular problems.     

Determination method of equivalent insulation test voltage at room temperature for high temperature superconducting power apparatus with coil structure

This paper deals with the determination method of the equivalent insulation test voltage at room temperature that secures the reliability of the cryogenic electrical insulation of the high temperature superconducting (HTS) power apparatus. The high voltage test is related to the apparatus with coil structure at the stages of its development, manufacturing and shipment. In the test method, the equivalent insulation test voltage at room temperature is derived from the standard test voltage at cryogenic temperature, based on the idea that the HTS power apparatus should be operated without partial discharges (PDs). The conversion factor between the two voltages is given by the product of the two medium factors, i.e. the one relating to the potential distribution along the coil winding and the other relating to the PD inception condition at the weakest part in the electrical insulation system. In order to determine the latter factor concerned with the non-linear phenomena against electrical stresses, the PD inception voltages at cryogenic and room temperatures are theoretically and experimentally estimated for modeled turn-to-turn insulation system. The results show that both estimated and measured values are in fairly good agreement and the proposed method is useful for the equivalent high voltage test at room temperature for the HTS power apparatus.     

Development and Use of a Kinetical and Real-Time Monitoring System to Analyze the Replication of Hepatitis C Virus

In microbiological research, it is important to understand the time course of each step in a pathogen’s lifecycle and changes in the host cell environment induced by infection. This study is the first to develop a real-time monitoring system that kinetically detects luminescence reporter activity over time without sampling cells or culture supernatants for analyzing the virus replication. Subgenomic replicon experiments with hepatitis C virus (HCV) showed that transient translation and genome replication can be detected separately, with the first peak of translation observed at 3–4 h and replication beginning around 20 h after viral RNA introduction into cells. From the bioluminescence data set measured every 30 min (48 measurements per day), the initial rates of translation and replication were calculated, and their capacity levels were expressed as the sums of the measured signals in each process, which correspond to the areas on the kinetics graphs. The comparison of various HuH-7-derived cell lines showed that the bioluminescence profile differs among cell lines, suggesting that both translation and replication capacities potentially influence differences in HCV susceptibility. The effects of RNA mutations within the 5′ UTR of the replicon on viral translation and replication were further analyzed in the system developed, confirming that mutations to the miR-122 binding sites primarily reduce replication activity rather than translation. The newly developed real-time monitoring system should be applied to the studies of various viruses and contribute to the analysis of transitions and progression of each process of their life cycle.