The Evaluation Of Ozonation and Chlorination On Disinfection By-Product Formation for a High-Bromide Water

High-bromide raw water was ozonated or chlorinated with and without hydrogen peroxide to study the effect of the disinfectants on the disinfection by-product (DBP) formation. Less bromate was formed when ozonation was made at the ambient pH of 5.8 as compared to ozonation at pH 7, showing the effectiveness of pH reduction in controlling the bromate formation. When chlorine dose was 1 mg/L instead of 2.3 mg/L, the trihalomethane formation was 50 μg/L instead of >100 μg/L, and the proportional distribution of the trihalomethanes was similar. The use of ozone for this water could provide good results in respect of the DBP formation.     

Distributed information service architecture for overlapping multiaccess networks

Multimedia delivery in mobile multiaccess network environments has emerged as a key area within the future Internet research domain. When network heterogeneity is coupled with the proliferation of multiaccess capabilities in mobile handheld devices, one can expect many new avenues for developing novel services and applications. New mechanisms for audio/video delivery over multiaccess networks will define the next generation of major distribution technologies, but will require significantly more information to operate according to their best potential. In this paper we present and evaluate a distributed information service, which can enhance media delivery over such multiaccess networks. We describe the proposed information service, which is built upon the new distributed control and management framework (DCMF) and the mobility management triggering functionality (TRG). We use a testbed which includes 3G/HSPA, WLAN and WiMAX network accesses to evaluate our proposed architecture and present results that demonstrate its value in enhancing video delivery and minimizing service disruption in an involved scenario.     

Molecular size fractions of treated aquatic humus

The effects of ozone, chlorine, hydrogen peroxide, and permanganate on the aquatic humic matter with different molecular size fractions and the organic acid formation in drinking water treatment were studied. Aquatic humus in lake water (LW), artificially recharged groundwater (AW), and purified artificially recharged groundwater (PW) were fractionated by high-pressure size-exclusion chromatography (HP-SEC) with UV-254nm detection before and after oxidation, a technique which resulted generally in seven peaks. The sum of the molecular size fractions (SMSF) of the LW was reduced by 47% during the bank filtration process, and the SMSF of the AW was reduced by 55% during the process in the water treatment plant. The oxidation of the AW resulted in reductions in the range of 18-35% of the SMSF; the respective range of the PW was 15-69%. However, the content of the total organic carbon (TOC) reduced only slightly, and a high correlation between the TOC and the SMSF (0.911) was observed in the whole material. The greatest decreases appeared in the highest-molecular-weight fractions while the low-molecular-weight fractions remained nearly unchanged. The total content of the six organic small-molecular-weight acids (sum of the organic acids, SOA) (formate, acetate, propionate, pyruvate, oxalate, and citrate) varied between 0.1-5.1% and 0.1-9.7% of the reduced TOC in the AW and the PW, respectively. The formation of the SOA, especially of oxalate, was the greatest after hydrogen peroxide combined with ozonation (as much as 1,100 microg/L), while chlorination resulted in the SOA of < 50 microg/L.     

Microbially available organic carbon, phosphorus, and microbial growth in ozonated drinking water

Ozonation is a disinfection technique commonly used in the treatment of drinking water. It destroys harmful microbes, but it also degrades organic matter in water, increasing the bioavailability of organic matter. Recently, it was found that not only organic carbon but also phosphorus can limit the microbial growth in drinking water, which contains high amount of organic matter. We used a bioassay to analyze whether ozone could also increase the microbially available phosphorus (MAP) in drinking water, and whether MAP in ozone-treated water was associated with the growth of heterotrophic microbes. We found that both assimilable organic carbon and MAP concentrations were increased by ozone treatment. In ozonated water, microbial growth was mainly limited by phosphorus, and even minor changes in MAP concentration dramatically increased the growth potential of heterotrophic microbes. In this study, ozonation increased the MAP by 0.08-0.73 microgram P/l, resulting in an increase of 80,000-730,000 CFU/ml in water samples. In contrast to MAP, the content of assimilable organic carbon (AOCpotential) did not correlate with microbial growth. The results show that in water treatment not only AOCpotential but also MAP should be considered as an important factor that can limit microbial growth in drinking water.     

Query optimization in information integration

The problem of decentralized data sharing, which is relevant to a wide range of applications, is still a source of major theoretical and practical challenges, in spite of many years of sustained research. In this paper we focus on the challenge of efficiency of query evaluation in information integration systems that use the global-as-view approach, with the objective of developing query-processing strategies that would be widely applicable and easy to implement in real-life applications. Our algorithms take into account important features of today’s data sharing applications: XML as likely interface or representation for data sources; the potential for information overlap across data sources; and the need for inter-source processing, as in joins of data across sources. The focus of this paper is on performance-related characteristics of several alternative approaches that we propose for efficient query processing in information integration, including an approach that uses materialized restructured views. We use synthetic and real-life datasets in our implementation of an information integration system shell to provide experimental results that demonstrate that our algorithms are efficient and competitive in the information integration setting. In addition, our experimental results allow us to make context-specific recommendations on selecting query-processing approaches from our proposed alternatives. As such, our approaches could form a basis for scalable query processing in information integration and interoperability in many practical settings.     

Pipeline materials modify the effectiveness of disinfectants in drinking water distribution systems

We studied how pipe material can modify the effectiveness of UV- and chlorine disinfection in drinking water and biofilms. This study was done with two pipe materials: copper and composite plastic (polyethylene, PE) in a pilot scale water distribution network. UV-disinfection decreased viable bacterial numbers in the pilot waterworks and outlet water of pipes on average by 79%, but in biofilms its disinfecting effect was minor. Chlorine decreased effectively the microbial numbers in water and biofilms of PE pipes. In outlet water from copper pipes, the effect of chlorination was weaker; microbial numbers increased back to the level before chlorination within a few days. In the biofilms present in the copper pipes, chlorine decreased microbial numbers only in front of the pipeline. One reason for weaker efficiency of chlorine in copper pipes was that its concentration declined more rapidly in the copper pipes than in the PE pipes. These results means that copper pipes may require a higher chlorine dosage than plastic pipes to achieve effective disinfection of the pipes.     

Biomanipulating the drinking water reservoir of Estonia's capital city: Prospects for success

The possibility of utilizing biomanipulation to improve the water quality of Tallinn's drinking water reservoir (Lake Ülemiste) was analysed on the basis of water quality data, test fishing by different methods, and earlier studies on aquatic plants, light climate and sediments. Eutrophic, polymictic Lake Ülemiste is characterized by a prevalence of high filamentous cyanobacteria biomass, rotifers in the zooplankton community, mature bream in the fish biomass, and a high density of planktivores (YOY perch). Several prerequisites for being a potential target for biomanipulation were identified, including (i) decreased external total phosphorus (TP) loading; and (ii) a sufficient stock of piscivorous fish in the lake. Prohibition of fishing should favour biomanipulation efforts. The potential for recolonization of macrophytes and large Daphnia species in Lake Ülemiste could be judged from historical data. The in-lake TP concentrations are within the limits that facilitate successful restoration. As phytoplankton biomass was significantly limited by phosphorus in Lake Ülemiste, its water quality improvement will be driven primarily by reduced nutrient concentrations, and then by zooplankton grazing. Internal TP loading and a new phytoplankton species community were assessed as major challenges for successful implementation of biomanipulation as a means of improving the water quality of Lake Ülemiste.     

Bromate Formation during Ozonation of Bromide Containing Drinking Water- a Pilot Scale Study

The effect of bromide ion concentration, pH, temperature, alkalinity, and hydrogen peroxide content on bromate formation was studied. Increase in pH was found to give the greatest increase in bromate formation. Also increase in the ozonation temperature, bromide ion concentration and hydrogen peroxide content increased the observed bromate concentration. Only increased alkalinity decreased the bromate formation during the ozonation experiments. Bromate formation exceeded the EU limit value for bromate ion, 10 μg/l, when the initial bromide ion concentration was around 100 μg/l, except for the alkalinity of 1.4 mmol/1, when the bromate formation was 9.4 μg/l.