全文获取类型
收费全文 | 1283篇 |
免费 | 42篇 |
专业分类
电工技术 | 115篇 |
综合类 | 2篇 |
化学工业 | 396篇 |
金属工艺 | 34篇 |
机械仪表 | 31篇 |
建筑科学 | 30篇 |
能源动力 | 87篇 |
轻工业 | 71篇 |
水利工程 | 1篇 |
石油天然气 | 4篇 |
无线电 | 55篇 |
一般工业技术 | 262篇 |
冶金工业 | 101篇 |
原子能技术 | 54篇 |
自动化技术 | 82篇 |
出版年
2023年 | 7篇 |
2022年 | 16篇 |
2021年 | 31篇 |
2020年 | 10篇 |
2019年 | 21篇 |
2018年 | 29篇 |
2017年 | 20篇 |
2016年 | 26篇 |
2015年 | 17篇 |
2014年 | 50篇 |
2013年 | 79篇 |
2012年 | 54篇 |
2011年 | 103篇 |
2010年 | 53篇 |
2009年 | 73篇 |
2008年 | 77篇 |
2007年 | 59篇 |
2006年 | 48篇 |
2005年 | 35篇 |
2004年 | 35篇 |
2003年 | 46篇 |
2002年 | 43篇 |
2001年 | 26篇 |
2000年 | 25篇 |
1999年 | 29篇 |
1998年 | 56篇 |
1997年 | 28篇 |
1996年 | 27篇 |
1995年 | 31篇 |
1994年 | 22篇 |
1993年 | 21篇 |
1992年 | 10篇 |
1991年 | 11篇 |
1990年 | 5篇 |
1989年 | 10篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 21篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1971年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有1325条查询结果,搜索用时 203 毫秒
1.
2.
Shouko Nishida Masaya Shibano Hiroshi Kamitakahara Toshiyuki Takano 《International journal of molecular sciences》2015,16(12):29093-29102
We recently observed that the decanoylation of N-phenylthiocarbamoyl chitosan (2) with a mixture of decanoic anhydride and pyridine at 60 °C for 24 h afforded N,N-(decanoyl)phenythiocarbamoyl-/2-isothiocynato chitosan decanoate (3b) rather than the expected product N,N-(decanoyl)phenylthiocarbamoyl chitosan decanoate (3a). This result suggested that some of the N,N-(decanoyl)phenylthiocarmbamoyl groups had been converted to isothiocyanate groups during the decanoylation process. The subsequent reaction of compound 3b with aniline gave N,N-(decanoyl)phenylthiocarbamoyl/N-phenylthiocarbamoyl chitosan decanoate (4) in high yield. A solution of compound 4 in CHCl3 was then added to a solution of copper decanoate (5) in the same solvent, and the resulting mixture was cast onto a glass plate to give a cast film. The film was annealed at 200 °C in an oven to give a greenish film, which showed good near-infrared absorption characteristic in the range of 800–2200 nm. 相似文献
3.
Toshiyuki MasuiTakanobu Chiga Nobuhito Imanaka Gin-ya Adachi 《Materials Research Bulletin》2003,38(1):17-24
Fine particles of a blue emission phosphor Sr2CeO4 have been synthesized using a chemical co-precipitation technique, and the textual and luminescent properties were compared with the one synthesized by the conventional solid-state reaction method. Particle size and distribution of the Sr2CeO4 fine powder prepared by the co-precipitation process were smaller and narrower than those obtained by the samples prepared from the conventional one. The emission intensity of the fine particles was equal to that of the larger particles prepared from the solid-state reaction, on the contrary to the general tendency that emission intensity decrease with particle size reduction. Although no Ce3+ peaks were observed in EPR measurements, X-ray photoelectron spectra of the samples clearly elucidated the existence of Ce3+ only on the surface of Sr2CeO4. 相似文献
4.
Hiroto Imai Toshiyuki Ogawa Kazuo Sugimoto Masakazu Kataoka Yumo Tanaka Takehiko Ono 《Applied catalysis. B, Environmental》2005,55(4):259-265
The Co/MFI(SiO2/Al2O3 = 30) were prepared by a precipitation method with NaOCl in alkali solutions exhibited high activities to N2 at 250 °C for the selective catalytic reduction (SCR) of NOx. These catalysts showed two UV–vis bands at 700 and 400 nm, indicating the presence of octahedral Co(III) as well as tetrahedral Co(II). The high SCR activity over such Co(III, II)/MFI(30) seems to come from Co(III)---O moieties. The Co(II)MFI(30) catalysts prepared from Co(II)Cl2 exhibited low SCR activities due to the presence of tetrahedral Co(II) ions in MFI. Less CO formation occurred over Co/MFI catalysts. The Fe/MFI(30) catalyst exhibited high activity due to the presence of some Fe---O species in MFI but more amount of CO were produced during SCR. H/MFI(30) catalyst exhibited a good SCR activity. However, more amount of carbonaceous deposits were produced on it. The correlation between acid concentration and SCR activity was discussed over H/MFIs. 相似文献
5.
This paper proposes a new belt drive control method for reducing a belt velocity-fluctuation that is caused by a belt thickness-variation in the circumferential direction. A belt driving system performs feedback control with a rotary encoder-output mounted on a driven roller. This proposed method correct the reference value of the feedback control for the purpose of the belt velocity regulation. The correction includes two steps. The first step acquires the encoder-output of the driven roller and calculates the rotational angular velocity-fluctuation with one cycle of the belt rotation. The second step converts from the velocity-fluctuation to the correction value of the feedback reference. The correction value cancels a detection error of the driven roller caused by the belt thickness-variation. After these steps, the belt driving system controls the belt velocity as compensating the belt velocity-fluctuation. Experimental result showed the significant fluctuation reduction on a typical tandem-engine printer. 相似文献
6.
R. Kaji S. Adachi H. Sasakura S. Muto H. Kumano I. Suemune 《Journal of Superconductivity and Novel Magnetism》2007,20(6):447-451
We investigated optical pumping of nuclear spin polarizations in a single self-assembled In0.75Al0.25As/Al0.3Ga0.7As quantum dot. The nuclear spin polarization exhibits the abrupt jump and hysteresis in the excitation power dependence at
a particular excitation polarization. Measurement of circular polarization rate of the photoluminescence reveals that the
abrupt change of the nuclear spin polarization is created mainly by the spin flip-flop process between nuclei and an electron
of a positive charged exciton in this single quantum dot. Model calculation explains well the experimentally observed bistable
behavior in InAlAs quantum dot. By using this abrupt change, the sign and magnitude of electron and hole g-factors in z-direction are verified.
相似文献
7.
OomiG KagayamaT SmithJL LacerdaAH KajiS OhashiM 《中国稀土学报(英文版)》2004,22(1):7-12
Electrical resistance, thermal expansion, lattice constants of the intermediate valence materials, α-Ce and CeBe13, were measured at high pressure. It is found that the Grttneisen parameters of Kondo temperature TK are 13 and 42 for α-Ce and CeBe13, respectively, and it decreases with increasing pressure. The magnetoresistance of α-Ce shows H^2 dependence and its coefficient increases with pressure below 1 GPa, but becomes nearly constant above 1 GPa. The results indicate that the intermediate valence states are enhanced at high pressure indicating the enhancement of hybridization between the 4f electron and conduction band. 相似文献
8.
Y Yonemura H Kimura S Fushida K Tugawa Y Nakai M Kaji L Fonseca A Yamaguchi I Miyazaki 《Canadian Metallurgical Quarterly》1993,71(8):2448-2453
BACKGROUND: Proliferative activities of tumors are thought to be prognostic features of malignant tumors, but their value as measured by proliferating cell nuclear antigen (PCNA) labeling remains unclear in gastric cancer. METHODS: PCNA labeling rates (LR) were quantified in 121 paraffin-embedded biopsy specimens from primary tumors by immunocytochemistry. RESULTS: Immunohistochemical analyses have demonstrated that PCNA presents an intense staining in the nuclei of tumor cells and mucous neck cells of gastric glands. The PCNA LR ranged from 12% to 79% (mean +/- standard deviation), and a significant correlation was found between bromodeoxyuridine labeling indices and PCNA LR: PCNA LR were closely associated with tumor size, serosal invasion, and nodal involvement. The patients with tumors with high PCNA LR (greater than 40%) were dead significantly earlier than were those with tumors with low PCNA LR: When the PCNA LR and all the clinicopathologic parameters were entered into a Cox regression model, PCNA LR emerged as an independent prognostic factor. CONCLUSION: These results indicate that PCNA LR may be a potentially useful prognostic factor for gastric cancer. 相似文献
9.
T Kaji Y Fujiwara M Hoshino C Yamamoto M Sakamoto H Kozuka 《Canadian Metallurgical Quarterly》1995,95(1-3):87-92
We investigated the effect of lead nitrate (0.5, 1.0, 2.0 or 5.0 microM) on the proliferation of cultured bovine aortic endothelial cells. After exposure to lead, the number of cells and the incorporation of [3H]thymidine into the acid-insoluble fraction of the cells were reduced in parallel in a concentration-dependent manner. Histologically, lead treatment resulted in a decrease in the cell number accompanied by a change in the cell shape from polygonal to spindle; however, no degenerative change was observed except in 5.0 microM lead-treated cells. Furthermore, stimulation of [3H]thymidine incorporation by either basic or acidic fibroblast growth factor was significantly reduced by lead. However, the leakage of lactate dehydrogenase into the medium from the cells, a marker of nonspecific cell damage, was not changed by lead. From these results, it was revealed that lead inhibits the proliferation of cultured vascular endothelial cells without nonspecific cell damage. Although lead does not destroy the monolayer of endothelial cells, the metal may exhibit its noxious effect in the repair process of the vascular endothelium. 相似文献
10.
Morihiko Nakamura Naoyuki Itoh Kenki Hashimoto Tokuzo Tsujimoto Toshiyuki Suzuki 《Metallurgical and Materials Transactions A》1994,25(2):321-330
Isothermally forged TiAl-base alloys (Al-rich, Mn-containing, and Cr-containing TiAl) were heat-treated in various conditions,
and equiaxed grain structures consisting of γ and α2 or Β phases were obtained. The heat-treated alloys were tensile tested in vacuum and air at room temperature, and the environmental
effect on tensile elongation was studied. The ductility of the alloys consisting of equiaxed γ grains and a large amount of
α2 grains was not largely affected by laboratory air, and a decrease in the amount of α2 grains resulted in a large reduction of ductility in air. The Β phase in the Cr-containing alloy improved the ductility in
vacuum, but it resulted in a large reduction of ductility in air.
Formerly with Kougakuin University, Shinjyuku-ku, Tokyo,
Formerly with National Research Institute for Metals, Meguro-ku, Tokyo, 相似文献