Authenticity green coffee bean species and geographical origin using near-infrared spectroscopy combined with chemometrics

To prevent the adulteration of agricultural resources and provide a solution to enhance the green coffee bean supply chain, authentication using the near-infrared spectroscopy (NIRS) technique was investigated. Partial least square with discrimination analysis (PLS-DA) models combined with various preprocessing methods were built from NIR spectra of 153 Vietnamese green coffee samples. The model combined with the standard normal variate and the first order of derivative yielded excellent performance in predicting coffee species with the error cross-validation of 0.0261. PLS-DA model of mean centre and first-order derivative spectra also yielded good performance in verifying geographical indication of green coffee with the error of 0.0656. By contrast, the predicting abilities of post-harvest methods were poor. The overall results showed a high potential of the NIRS in online authentication practices.     

Controlling thickness to tune performance of high-mobility transparent conducting films deposited from Ga-doped ZnO ceramic target

Structure modification has been found to tune significantly the transparent-conducting performance, especially mobility and conductivity of hydrogenated Ga-doped ZnO (HGZO) films. The strong correlation between film thickness and mobility of the films is revealed. The mobility increases quickly with increasing the thickness from 350 to 900 nm, and then tends to be saturated at further thicknesses. A higher mobility than 50 cm²/Vs can be achieved, which is an extra-high value for polycrystalline ZnO films deposited by using the sputtering technique. The thickness-dependent mobility originates from scatterings on grain boundaries and dislocation-induced defects controlled by thin-film growth. Based on the Volmer-Weber model, an expansion model is built up to describe the thickness-dependent crystal growth of the HGZO films, especially at the thick films. As a result, the 800 nm-thick HGZO film obtains the highest performance with high mobility of 51.5 cm²/Vs, low resistivity of 5.3 × 10^?4 Ωcm, and good transmittance of 83.3 %.     

Physical Aging of Amorphous Fructose

ABSTRACT: Physical aging of amorphous anhydrous fructose at temperature 5 °C and at 22 °C was studied using differential scanning calorimetry (DSC). The dynamic glass transition temperature, T_g0 for unaged samples was 16 °C and 13.3 °C for heating rate of 10 °C/min and 1 °C/min, respectively. The fictive temperature, T_f0 for unaged samples calculated by Richardson and Savill method was 12 °C, which is close to the dynamic value obtained from the lower DSC heating rate. The fictive temperature T_f of the aged fructose glasses at temperatures both below and above the transition region was fitted well by a non-exponential decay function (Williams-Watts form). Aging above the transition region (22 °C) for 18 d increased both the dynamic glass transition temperature T_g and the fictive temperature T_f. However, aging below the transition region (5 °C) for 1 d increased the dynamic glass transition temperature T_g but decreased the fictive temperature T_f.     

Algebraic decoding of (103, 52, 19) and (113, 57, 15) quadratic residue codes

In this paper, two algebraic decoders for the (103, 52, 19) and (113, 57, 15) quadratic residue codes, which have lengths greater than 100, are presented. The results have been verified by software simulation that programs in C++ language have been executed to check possible error patterns of both quadratic residue codes.     

Study of lithium intercalation into tungsten oxide films prepared by different methods

The interaction of lithium atoms into amorphous tungsten oxide films deposited by thermal evaporation, sputtering and sol-gel synthesis is studied spectroscopically. The mechanism of insertion of lithium into the film depends on the amount and the bonding state of water to the tungsten oxide network. Thermally evaporated tungsten oxide film contains water bonded chemically in the form of a hydrogen tungsten bronze which facilitates the accommodation of a high number of lithium atoms. In the sputtered film, water is physisorbed and the lithiation is incomplete. Tungsten oxide films prepared by sol-gel synthesis have structural water molecules directly involved in the lithiation process. The formation of lithium tungstate independent of the preparation method is demonstrated.     

Automated zebrafish chorion removal and single embryo placement: optimizing throughput of zebrafish developmental toxicity screens

The potential of the developing zebrafish model for toxicology and drug discovery is limited by inefficient approaches to manipulating and chemically exposing zebrafish embryos-namely, manual placement of embryos into 96- or 384-well plates and exposure of embryos while still in the chorion, a barrier of poorly characterized permeability enclosing the developing embryo. We report the automated dechorionation of 1600 embryos at once at 4 h postfertilization (hpf) and placement of the dechorionated embryos into 96-well plates for exposure by 6 hpf. The process removed ≥95% of the embryos from their chorions with 2% embryo mortality by 24 hpf, and 2% of the embryos malformed at 120 hpf. The robotic embryo placement allocated 6-hpf embryos to 94.7% ± 4.2% of the wells in multiple 96-well trials. The rate of embryo mortality was 2.8% (43 of 1536) from robotic handling, the rate of missed wells was 1.2% (18 of 1536), and the frequency of multipicks was <0.1%. Embryo malformations observed at 24 hpf occurred nearly twice as frequently from robotic handling (16 of 864; 1.9%) as from manual pipetting (9 of 864; 1%). There was no statistical difference between the success of performing the embryo placement robotically or manually.     

Investigation of long term drift of an intraocular pressure sensor

Microsystem Technologies - “Zero drift” behavior of an optical intraocular pressure sensor is studied using an analytical model based on the deflection of a circular membrane. Results...     

ANDES: efficient evaluation of NOT-twig queries in relational databases

Despite a large body of work on XPath query processing in relational environment, systematic study of queries containing not-predicates have received little attention in the literature. Particularly, several xml supports of industrial-strength commercial rdbms fail to efficiently evaluate such queries. In this paper, we present an efficient and novel strategy to evaluate not -twig queries in a tree-unaware relational environment. not -twig queries are XPath queries with ancestor–descendant and parent–child axis and contain one or more not-predicates. We propose a novel Dewey-based encoding scheme called Andes (ANcestor Dewey-based Encoding Scheme), which enables us to efficiently filter out elements satisfying a not-predicate by comparing their ancestor group identifiers. In this approach, a set of elements under the same common ancestor at a specific level in the xml tree is assigned same ancestor group identifier. Based on this scheme, we propose a novel sql translation algorithm for not-twig query evaluation. Experiments carried out confirm that our proposed approach built on top of an off-the-shelf commercial rdbms significantly outperforms state-of-the-art relational and native approaches. We also explore the query plans selected by a commercial relational optimizer to evaluate our translated queries in different input cardinality. Such exploration further validates the performance benefits of Andes.     

Enhanced Dynamic Authentication Scheme (EDAS)

With non-stop growth in network environments, communication security is necessary. A strong protocol guarantees that users and service providers are secure against many kinds of attacks, such as impersonation and replay attack. Sood et al. proposed an authentication scheme based on dynamic identity to prevent transactions from being intercepted by malicious users. Although they claimed that their scheme has advantages over previous schemes with the same approach, we prove that their scheme is vulnerable to impersonation attack and stolen verification attack, and can be affected by clock synchronization. Therefore we propose a novel authentication scheme to enhance security and overcome limitations existing in Sood’s scheme. Our security analysis shows that our proposed method can efficiently resist known types of attacks. Experimental results also show that the method can be implemented and processed in real-time thus applicable for not only regular computers but also mobile devices.     

Effect of physical aging on the fracture behavior of crosslinked epoxies

The effect of physical aging on the fracture behavior, crack opening displacement, and plastic deformation zone of unmodified and rubber-modified epoxies was determined at two aging temperatures and different displacement rates. The strain energy release rate decreases to between 40 and 50% (for rubber modified and unmodified samples, respectively) of the unaged values after 35 days aging. Systematic dependence of the decrease in fracture toughness by aging on the rubber content is not apparent. The increased yield stress after physical aging is the main factor contributing to the reduction in fracture toughness, crack opening displacement, and plastic deformation zone. Physical aging suppresses the crack blunting mechanisms in epoxies.