Functional polyamides. 3. Synthesis and chelating properties of a new poly(amide thioether)

Polymerization of β,β′-(ethylenedithio)dipropionitrile

1 IUPAC name: 4,7-dithiadecane dinitrile.

with formaldehyde in the presence of sulfuric acid was carried out in order to permit the synthesis of polymides containing thioether groups. The obtained poly(amide thioether)s were characterized; they coordinate mercury (II) with a high degree of selectivity.     

Group Study of Simulated Driving fMRI Data by Multiset Canonical Correlation Analysis

In this work, we apply a novel statistical method, multiset canonical correlation analysis (M-CCA), to study a group of functional magnetic resonance imaging (fMRI) datasets acquired during simulated driving task. The M-CCA method jointly decomposes fMRI datasets from different subjects/sessions into brain activation maps and their associated time courses, such that the correlation in each group of estimated activation maps across datasets is maximized. Therefore, the functional activations across all datasets are extracted in the order of consistency across different dataset. On the other hand, M-CCA preserves the uniqueness of the functional maps estimated from each dataset by avoiding concatenation of different datasets in the analysis. Hence, the cross-dataset variation of the functional activations can be used to test the hypothesis of functional-behavioral association. In this work, we study 120 simulated driving fMRI datasets and identify parietal-occipital regions and frontal lobe as the most consistently engaged areas across all the subjects and sessions during simulated driving. The functional-behavioral association study indicates that all the estimated brain activations are significantly correlated with the steering operation during the driving task. M-CCA thus provides a new approach to investigate the complex relationship between the brain functions and multiple behavioral variables, especially in naturalistic tasks as demonstrated by the simulated driving study.     

UV curable lens production using molecular weight controlled PEEK based acrylic oligomer (Ac-PEEK)

We produced UV curable lenses with properties blocking short wave UV light. In the UV-curable formulations, we used an oligomer (Ac-PEEK) with another urethan oligomer (Mw = 2000). Radically active, molecular weight controlled Ac-PEEK was obtained by reacting 2-hydroxyl ethyl methacrylate with molecular- weight- controlled and isocyanate terminated PEEK (Mn = 4500). We characterized all synthesized monomer, oligomer and optical materials with UV/Vis spectrophotometer with interferogram, elemental analyser, mass spectrophotometer, proton nuclear magnetic resonance, Fourier transform infrared spectroscopy, thermal gravimetric analyzer, differential scanning calorimeter, scanning electron microscopy and gas chromatography. Results suggested that newly synthesized oligomer with the structure of PEEK absorbs short wave UV-light. Ageing tests [ISO 11979-5, Ophthalmic implants—intraocular lenses (IOL)—Part 5: Biocompatibility] performed on the IOL materials were successful. High contact angle of the obtained lenses suggests that all lenses were hydrophobic and SEM results revealed that lenses are morphologically homogeneous. Based on all positive properties just mentioned, we safely conclude that the lenses produced in this study are very promising for IOL production.     

WCOT: A utility based lifetime metric for wireless sensor networks

Network lifetime is a novel performance metric which is derived in need to evaluate the networks that are composed of nodes with non-replenishable energy sources. Wireless Sensor Networks (WSNs) are the primary examples of such networks, in which elongating the network lifetime is the main concern. Optimal WSN design is highly dependent on the application scenario context. Correct quantification of the application specific network lifetime is a must to further optimize the design or to comparatively evaluate the proposed schemes – e.g. a legacy layered design vs. a cross-layer implementation. However, in practice, we observe that the focus is given on proposing sophisticated schemes to increase the energy efficiency, whereas only rudimentary lifetime metrics are employed to evaluate the outcome of this effort which compromises the correctness of the results. To realistically and correctly quantify the lifetime, we propose a utility based lifetime measurement framework called Weighted Cumulative Operational Time (WCOT). WCOT lets users incorporate the application dependence into the lifetime metric through its utility based interface. WCOT performs a weighted summation of time where utility values are the weights. With this mechanism, a more representative lifetime metric which maps the complete network behavior into a numeric value is obtained. This is in contrast with metrics which focus solely on certain milestones of the network functionality to quantify the lifetime which include the first node death, the last node death.     

Performance evaluation of a submerged membrane bioreactor for the treatment of brackish oil and natural gas field produced water

Produced water, which is co-produced during oil and gas manufacturing, represents one of the largest sources of oily wastewaters. Therefore, treatment of this produced water may improve the economic viability and lead to a new source of water for beneficial use. In this study a submerged hollow fiber membrane bioreactor (MBR) has been studied experimentally for the treatment of brackish oil and natural gas field produced water. This type of wastewater is also characterized with relatively moderate to high amount of salt, oil and total petroleum hydrocarbons (TPH). However, the bacteria which are growing in conventional activated sludge and MBR cannot survive at these strict conditions, therefore acclimation of the bacteria is of vital importance. The performance of the biological system, membrane permeability, the rate and extent of TPH biodegradability have been investigated under different sludge age and F/M ratios. The results obtained by gas chromatography analyses showed that the MBR system could be very effective in the removal of TPH from produced water and a significant improvement in the effluent quality was achieved.     

Investigation of the effects of geometrical parameters on heat transfer from buried finned pipes

Heat transfer from finned pipes buried in the soil has been investigated using experimental, analytical and numerical techniques. The experimental setup consists of a ground source heat pump system and two separate ground heat exchangers. Constant surface temperature approach based on Carslaw and Jaeger’s theory study was used for calculating the heat transfer from the pipes analytically. The problem was modeled and solved using a CFD program numerically. Effects of the fin number, fin length and simulation time on the heat transfer rate have been investigated and compared with bare tube. A modified analytical formula was also proposed for finned pipes in this study.