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1.
Removal of gaseous and vapor constituents of environmental tobacco smoke (ETS) by activated carbons in a packed bed arrangement was studied under dynamic conditions and was compared with that by silica gel and molecular sieve 13X. ETS is a mixture of sidestream smoke and exhaled mainstream smoke, and it consists of various organic and inorganic compounds, trace heavy metals, and particulate matters. Due to the complex nature of ETS-air mixture, its removal from indoors is a challenging task. For experimentation in a laboratory, the ETS was produced from a specially designed smoking apparatus that simulated the puffng of a cigarette by a person. Air containing ETS was passed through a bed containing about 25 grams of activated carbon at room temperature. The flow rate of air-ETS mixture through the bed was 4000 cm3/min. The relative humidity of the air was 50% and contained about 35 to 40 ppm of hydrocarbons as measured as methane-equivalent. The number of particles in the inlet air stream were in the range of 30,000 to 35,000 particles/cm3. About 60% of hydrocarbons present in ETS were removed at these operating conditions for a period of about 70 hours. Based on 15 adsorption and regeneration cycles, it was noted that the carbon bed did not loose its capacity for ETS significantly as indicated by the BET surface area and water adsorption data. At the beginning of an adsorption cycle, the carbon bed captured a significant number of particles. However, the bed rapidly lost its particle capture effciency as the experiment progressed. The number of particles in the outlet air stream was found to be the same as that of the inlet stream within five minutes. 相似文献
2.
Indranil Roy Manish Chauhan Farghalli A. Mohamed Enrique J. Lavernia 《Metallurgical and Materials Transactions A》2006,37(3):721-730
Thermal stability in bulk ultrafine-grained (UFG) 5083 Al that was processed by gas atomization followed by cryomilling, consolidation,
and extrusion, and that exhibited an average grain size of 305 nm, was investigated in the temperature range of 473 to 673
K (0.55 to 0.79 T
m
, where T
m
is the melting temperature of the material) for different annealing times. Appreciable grain growth was observed at temperatures
> 573 K, whereas there was limited grain growth at temperatures < 573 K even after long annealing times. The values of the
grain growth exponent, n, deduced from the grain growth data were higher than the value of 2 predicted from elementary grain growth theories. The
discrepancy was attributed to the operation of strong pinning forces on boundaries during the annealing treatment. An examination
of the microstructure of the alloy suggests that the origin of the pinning forces is most likely related to the presence of
dispersion particles, which are mostly introduced during cryomilling. Two-grain growth regimes were identified: the low-temperature
region (<573 K) and the high-temperature region (>573 K). For temperatures lower than 573 K, the activation energy of 25 ±
5 kJ/mol was determined. It is suggested that this low activation energy represents the energy for the reordering of grain
boundaries in the UFG material. For temperatures higher than 573 K, an activation energy of 124 ± 5 kJ/mol was measured. This
value of activation energy, 124 ± 5 kJ/mol, lies between that for grain boundary diffusion and lattice diffusion in analogous
aluminum polycrystalline systems. The results show that the strength and ductility of bulk UFG 5083 Al, as obtained from tensile
tests, correlate well with substructural changes introduced in the alloy by the annealing treatment. 相似文献
3.
4.
Yogesh Singh Chauhan Renaud Gillon Benoit Bakeroot Francois Krummenacher Michel Declercq Adrian Mihai Ionescu 《Solid-state electronics》2007,51(11-12):1581
An EKV-based high voltage MOSFET model is presented. The intrinsic channel model is derived based on the charge based EKV-formalism. An improved mobility model is used for the modeling of the intrinsic channel to improve the DC characteristics. The model uses second order dependence on the gate bias and an extra parameter for the smoothening of the saturation voltage of the intrinsic drain. An improved drift model [Chauhan YS, Anghel C, Krummenacher F, Ionescu AM, Declercq M, Gillon R, et al. A highly scalable high voltage MOSFET model. In: IEEE European solid-state device research conference (ESSDERC), September 2006. p. 270–3; Chauhan YS, Anghel C, Krummenacher F, Maier C, Gillon R, Bakeroot B, et al. Scalable general high voltage MOSFET model including quasi-saturation and self-heating effect. Solid State Electron 2006;50(11–12):1801–13] is used for the modeling of the drift region, which gives smoother transition on output characteristics and also models well the quasi-saturation region of high voltage MOSFETs. First, the model is validated on the numerical device simulation of the VDMOS transistor and then, on the measured characteristics of the SOI-LDMOS transistor. The accuracy of the model is better than our previous model [Chauhan YS, Anghel C, Krummenacher F, Maier C, Gillon R, Bakeroot B, et al. Scalable general high voltage MOSFET model including quasi-saturation and self-heating effect. Solid State Electron 2006;50(11–12):1801–13] especially in the quasi-saturation region of output characteristics. 相似文献
5.
Tushar S. Deore Amid L. Sadgar Radha V. Jayaram 《Journal of surfactants and detergents》2021,24(1):185-190
Ionic liquids have been found to be suitable alternatives to volatile organic solvents in chemical transformation. Through a proper choice of cations and anions, the properties of an ionic liquid can be tuned so that it resembles an amphiphile. Such specially designed molecules are known as surface-active ionic liquids (SAIL). Like conventional surfactants, SAIL also form aggregates in an aqueous medium. Studies show that the mixing of SAIL with conventional surfactants leads to synergistic micellization. However, very few reports are available on the application of such systems as reaction media. Present study focuses on the application of mixed micelles of 1-tetradecyl-3-methylimidazol-1-ium bromide, ([C14mim]Br) with nonionic surfactant, Octylphenol ethoxylate with 10 moles of ethylene oxide (OPE-10). Enhanced solubilization and selective catalytic oxidation of toluene using hydrogen peroxide as an oxidant and tungstic acid as a catalyst have been studied in detail using this system. 相似文献
6.
Shamsher S. Kanwar Ghansham S. Chauhan Swapandeep S. Chimni Sandeep Chauhan Gajendra S. Rawat Rajeev K. Kaushal 《应用聚合物科学杂志》2006,100(2):1420-1426
An alkaline thermotolerant bacterial lipase of Bacillus coagulans MTCC‐6375 was purified and immobilized on a methacrylic acid and dodecyl methacrylate (MAc‐DMA) hydrogel. The lipase was optimally bound to the matrix after 20 min of incubation at 55°C and pH 9 under shaking conditions. The matrix‐bound lipase retained approximately 50% of its initial activity at 70–80°C after 3 h of incubation. The immobilized lipase was highly active on medium chain length p‐nitrophenyl acyl ester (C: 8, p‐nitrophenyl caprylate) than other p‐nitrophenyl acyl esters. The presence of Fe3+, NH4+, K+, and Zn2+ ions at 1 mM concentration in the reaction mixture resulted in a profound increase in the activity of immobilized lipase. Most of the detergents partially reduced the activity of the immobilized lipase. The immobilized lipase performed ~62% conversion in 12 h at temperature 55°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1420–1426, 2006 相似文献
7.
Shamsher Singh Kanwar Rajeev Kumar Kaushal Amit Aggarwal Sandeep Chauhan Swapandeep Singh Chimni Ghansham Singh Chauhan 《应用聚合物科学杂志》2007,105(3):1437-1443
A purified alkaline thermotolerant bacterial lipase of Bacillus coagulans MTCC‐6375 was efficiently immobilized onto poly(N‐AEAAm‐co‐AAc‐cl‐MBAm)‐hydrogel at pH 8.5 and at temperature 55°C in 16 h. The hydrogel‐bound matrix possessed 1.04 U/g (matrix) lipase activity with a specific activity of 1.8 U/mg of protein. The immobilized lipase resulted in formation of 52.5 mM of ethyl propionate (52% conversion) at 55°C in 9 h in n‐nonane. Ethanol and propionic acid when used in a ratio of 300 : 100 mM, respectively, in n‐nonane along with 10 mg of hydrogel‐bound lipase resulted in optimal synthesis of ethyl propionate (82.5 mM). Addition of molecular sieves (3 Å, 0.7 g/reaction volume) further enhanced the conversion rate to 82.4% resulting in 83.5 mM of ethyl propionate. Incubation temperature below or above 55°C had a marked effect on the synthesis of ethyl propionate. However, esterification performed in n‐heptane at 65°C resulted in 87.5 mM of ethyl propionate with a conversation rate of 89.3%. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
8.
K. N. Mehrotra M. Chauhan R. K. Shukla 《Journal of the American Oil Chemists' Society》1996,73(7):897-902
The ultrasonic velocity and density measurements of europium soaps in a mixture of benzene and methanol (3:2, vol/vol) were
used to evaluate various acoustic parameters and molar volume and to determine the critical micelle concentration. The results
showed that the ultrasonic velocity, specific acoustic impedance, molar sound velocity, and molar compressibility increase,
and intermolecular free length, adiabatic Compressibility, and relative association decrease with increasing concentration
and chainlength of the soap. The results were interpreted in terms of soap-solvent interaction. 相似文献
9.
Mahajan Nitish Chauhan Amita Kumar Harish Kaushal Sakshi Sangaiah Arun Kumar 《Mobile Networks and Applications》2022,27(4):1423-1443
Mobile Networks and Applications - In the era of Internet of Things (IoT) powered by 5G technologies, Automobile Industry is headed towards a revolution. In Intelligent Transport Systems (ITS),... 相似文献
10.
Lin Pei-Chun Yankson Benjamin Chauhan Vishal Tsukada Manabu 《The Journal of supercomputing》2022,78(13):15060-15088
The Journal of Supercomputing - Currently, many smart speakers, even social robots, appear on the market to help people's lives become more convenient. Usually, people use smart speakers to... 相似文献