Multichromic polymers based on pyrene clicked thienylpyrrole

In this study, the effect of pendant pyrene on the optical and electronic properties of poly(2,5‐dithienylpyrrole)s was studied. For this purpose a new pyrene coupled 2,5‐dithienylpyrrole derivative (SNS‐pyrene) was synthesized through click reaction. SNS‐pyrene was electrochemically polymerized and its electrochemical and optical properties were investigated by electrochemical and optical techniques. The polymer had a band gap of 3.36 eV and displayed light green to blue color variation upon oxidation in less than 2.48 s. Additionally, electrochemical copolymerization of SNS‐pyrene with 3,4‐ethylenedioxythiophene was achieved whilst a detailed investigation was performed on the effect of electrochemical polymerization conditions on the optoelectronic properties of the copolymers. Studies revealed that the copolymers exhibit multichromic reversible redox behavior with lower band gaps and shorter switching times than their parent polymer, P(SNS‐pyrene) © 2014 Society of Chemical Industry.     

Theoretical Investigation of Time Suboptimal Control of Industrial Manipulators Along Specified Paths

A method for the time suboptimal control of an industrial manipulator from an initial position and orientation to a final position and orientation as it moves along a specified path is proposed. Nonlinear system equations that describe the manipulator motion are linearized at each time step along the path. A method which gives the control inputs (joint angular velocities) for time suboptimal control of the manipulator is developed. In the formulation, joint angular velocity and acceleration limitations are also taken into consideration. A six degree of freedom elbow type manipulator is used in numerical examples to verify the method developed.     

Design of a Commercial Hybrid VTOL UAV System

For the last four decades Unmanned Air Vehicles (UAVs) have been extensively used for military operations that include tracking, surveillance, active engagement with weapons and airborne data acquisition. UAVs are also in demand commercially due to their advantages in comparison to manned vehicles. These advantages include lower manufacturing and operating costs, flexibility in configuration depending on customer request and not risking the pilot on demanding missions. Even though civilian UAVs currently constitute 3 % of the UAV market, it is estimated that their numbers will reach up to 10 % of the UAV market within the next 5 years. Most of the civilian UAV applications require UAVs that are capable of doing a wide range of different and complementary operations within a composite mission. These operations include taking off and landing from limited runway space, while traversing the operation region in considerable cruise speed for mobile tracking applications. This is in addition to being able traverse in low cruise speeds or being able to hover for stationary measurement and tracking. All of these complementary and but different operational capabilities point to a hybrid unmanned vehicle concept, namely the Vertical Take-Off and Landing (VTOL) UAVs. In addition, the desired UAV system needs to be cost-efficient while providing easy payload conversion for different civilian applications. In this paper, we review the preliminary design process of such a capable civilian UAV system, namely the TURAC VTOL UAV. TURAC UAV is aimed to have both vertical take-off and landing and Conventional Take-off and Landing (CTOL) capability. TURAC interchangeable payload pod and detachable wing (with potential different size variants) provides capability to perform different mission types, including long endurance and high cruise speed operations. In addition, the TURAC concept is to have two different variants. The TURAC A variant is an eco-friendly and low-noise fully electrical platform which includes 2 tilt electric motors in the front, and a fixed electric motor and ducted fan in the rear, where as the TURAC B variant is envisioned to use high energy density fuel cells for extended hovering time. In this paper, we provide the TURAC UAV’s iterative design and trade-off studies which also include detailed aerodynamic and structural configuration analysis. For the aerodynamic analysis, an in-house software including graphical user interface has been developed to calculate the aerodynamic forces and moments by using the Vortex Lattice Method (VLM). Computational Fluid Dynamics (CFD) studies are performed to determine the aerodynamic effects for various configurations For structural analysis, a Finite Element Model (FEM) of the TURAC has been prepared and its modal analysis is carried out. Maximum displacements and maximal principal stresses are calculated and used for streamlining a weight efficient fuselage design. Prototypes have been built to show success of the design at both hover and forward flight regime. In this paper, we also provide the flight management and autopilot architecture of the TURAC. The testing of the controller performance has been initiated with the prototype of TURAC. Current work focuses on the building of the full fight test prototype of the TURAC UAV and aerodynamic modeling of the transition flight.     

Fair referee assignments for professional football leagues

Assignment of referees to football games is an important problem faced in professional football leagues. Despite its importance, the problem has received limited academic attention. This paper presents a model and analysis of the problem for fair referee assignments, and develops a constructive heuristic and a local search procedure for its solution. Results from an extensive computational study show that the methods are effective in solving the problem in a second of computation time and yielding an excellent solution quality.     

Maximization of buckling load of laminated composite plates with central circular holes using MFD method

This paper addresses optimal design of simply supported symmetrically laminated composite plates with central circular holes. The design objective is the maximization of the buckling load, and the design variable is considered as the fiber orientation. The first-order shear deformation theory is used for the finite element analysis. The study is complicated because the effects of bending–twisting coupling are also included for the buckling optimization. The modified feasible direction method is used to solve the optimization problems. Finally, the effect of different number of layers, boundary conditions, width-to-thickness ratio, plate aspect ratios, hole daimeter-to-width ratio, and load ratios on the results is investigated.     

Standardization problem of author affiliations in citation indexes

Academic effectiveness of universities is measured with the number of publications and citations. However, accessing all the publications of a university reveals a challenge related to the mistakes and standardization problems in citation indexes. The main aim of this study is to seek a solution for the unstandardized addresses and publication loss of universities with regard to this problem. To achieve this, all Turkey-addressed publications published between 1928 and 2009 were analyzed and evaluated deeply. The results show that the main mistakes are based on character or spelling, indexing and translation errors. Mentioned errors effect international visibility of universities negatively, make bibliometric studies based on affiliations unreliable and reveal incorrect university rankings. To inhibit these negative effects, an algorithm was created with finite state technique by using Nooj Transducer. Frequently used 47 different affiliation variations for Hacettepe University apart from “Hacettepe Univ” and “Univ Hacettepe” were determined by the help of finite state grammar graphs. In conclusion, this study presents some reasons of the inconsistencies for university rankings. It is suggested that, mistakes and standardization issues should be considered by librarians, authors, editors, policy makers and managers to be able to solve these problems.     

Are Propositional Attitudes Mental States?

Minds and Machines - I present an argument that propositional attitudes are not mental states. In a nutshell, the argument is that if propositional attitudes are mental states, then only minded...     

Martensitic phase transformations in Ni–Ti-based shape memory alloys: The Landau theory

We present a simple Landau free energy functional for cubic-to-orthorhombic and cubic-to-monoclinic martensitic phase transformations. The functional is derived following group–subgroup relations between different martensitic phases – tetragonal, trigonal, orthorhombic and monoclinic – in order to fully capture the symmetry properties of the free energy of the austenite and martensite phases. The derived free energy functional is fitted to the elastic and thermodynamic properties of NiTi and NiTiCu shape memory alloys which exhibit cubic-to-monoclinic and cubic-to-orthorhombic martensitic phase transformations, respectively.     

Characterization of nanocrystalline Ni–Cu thin films electrodeposited onto ITO coated glass substrates: effect of pretreatment current density

In this work, Ni–Cu films were grown onto indium tin oxide coated glass substrates without and with galvanostatic pretreatment process at different current densities. In all cases, Ni–Cu films were electrodeposited at a constant deposition potential of ?1,800 mV versus saturated calomel electrode. After that, the surface morphology and structural properties of electrodeposited Ni–Cu films in dependence of pretreatment current density were studied. X-ray diffraction analysis showed that all films have face-centered cubic structure and consist of segregated two Ni-rich and Cu-rich phases regardless of pretreatment current density. The compositional analysis carried out by energy dispersive X-ray spectroscopy revealed that all films contain almost 90 wt% Ni and 10 wt% Cu. The average crystallite size decreased with decreasing pretreatment current density towards more negative values without inducing significant changes in the composition of the films. It was found that the preferred orientation of all films is in the [111] direction regardless of pretreatment current density. The effect of galvanostatic pretreatment process on the surface morphology investigated using a scanning electron microscopy and an atomic force microcopy were also discussed by means of obtained results.     

Cooling slope casting to produce EN AW 6082 forging stock for manufacture of suspension components

The potential of cooling slope casting process to produce EN AW 6082 forging stock for the manufacture of EN AW 6082 suspension components was investigated. EN AW 6082 billets cast over a cooling plate offer a fine uniform structure that can be forged even without a separate homogenization treatment. This is made it possible by the limited superheat of the melt at the start of casting and the fractional solidification that occurs already on the cooling plate. Suspension parts forged from cast and homogenized billets with or without Cr all showed a uniform structure, and the hardness reached HV 110 after the standard artificial ageing treatment.