冠醚存在下氯代芳基化合物与碱金属氟化物的相互作用

本文研究了各种冠醚对多氯芳烃与碱金属氟化物（KF，RbF，CsF）反应的影响。指出冠醚的催化作用跟多氯芳烃的性质几乎无关，且只有在一个确定的反应速率范围内才最有效。     

复杂蒸馏的最小回流比

本文提出的直接计算方法不仅适用于多股进料的蒸馏塔,而且也适于有多股侧线抽出的情况。     

并流和逆流热交换器的流体出口温度算式

<正> 在近几年出版的一些化工原理教材有关“传热单元”的章节中,在提到确定热交换器流体出口温度时,都谈到用对数平均温差需试差求解,采用传热单元法可避免试差、比较简便的论点。在这一节的举例中,各教材或例题与习题集都以逆流或并流热交换     

侧流塔的最小回流比

蒸馏塔的设计需要估算最小回流比。本文指出如何计算有一股或多股侧流的蒸馏塔最小回流比。     

Activity clusters in dynamical model of the working memory system

A mathematical model of working memory is proposed in the form of a network of neuron-like units interacting via global inhibitory feedback. This network is capable of storing information items in the form of clusters of periodical spiking activity. Several sequentially excited clusters can coexist simultaneously, corresponding to several items stored in the memory. The capacity of the memory is studied as the function of the system parameters.     

A source of a reference spherical wave based on a single mode optical fiber with a narrowed exit aperture

A new type of a reference spherical wave source (SWS) based on a single mode optical fiber with a narrowed down up to the submicrometer size exit aperture is proposed. It is intended for the precision point diffraction interferometers as a source of a reference wave. Systematic experimental errors which influence the measurement accuracy of the quality of the wave fronts generated by the SWSs are considered. Experimental data on wave front deformations are given. The combined root-mean-square (rms) wave deformation for a couple of the SWSs measured in a numerical aperture of NA=0.27 reaches the value of rms=0.36 nm that corresponds to rms=0.25 nm of a single SWS or about lambda2500 for the red He-Ne laser.     

Reflection-transmission photoellipsometry: theory and experiments

We propose a method that uses reflection and transmission photoellipsometry to analyze samples consisting of thin films combined with semitransparent thick layers or substrates in the form of multilayer structures. Athick film or substrate is defined as a layer for which no interference effects can be observed for a given wavelength resolution, and contributions from multiple reflections in the substrate are taken into account in the theoretical treatment. An automatic reflection-transmission spectroscopic ellipsometer was built to test the theory, and satisfactory results have been obtained. Examples corresponding to a strongly absorbing film deposited on a glass substrate and a highly transmitting film also deposited on glass are shown. In both cases a good fit between theory and experiment is found. The photoellipsometric method presented is particularly suited to the analysis of actual samples of energy-efficient coatings for windows.     

Stable room-temperature LiF:F2 (+*) tunable color-center laser for the 830-1060-nm spectral range pumped by second-harmonic radiation from a neodymium laser

Simultaneous photostability and thermostability of a room-temperature LiF:F2(+*) tunable color-center laser, with an operating range over 830-1060 nm, pumped by second-harmonic radiation of a YAG:Nd(3+) laser with a 532-nm wavelength has been achieved. The main lasing characteristics of the obtained LiF:F2 (+*) laser have been measured. Twenty-five percent real efficiency in a nonselective resonator cavity and 15% real efficiency in a selective resonator cavity have been obtained. The stable LiF:F2 (+*) laser operates at a 1-100-Hz pulse-repetition rate with a 15-ns pulse duration, a 1-1.5-cm(-1) narrow-band oscillation bandwidth, and divergency of better than 6 × 10(-4). Doubling the fundamental frequencies of F2(+*) oscillation made it possible to obtain stable blue-green tunable radiation over the 415-530-nm range.